We present a lattice-QCD-based determination of the chiral phase transition temperature in QCD with two degenerate, massless quarks and a physical strange quark mass using lattice QCD calculations ...with the highly improved staggered quarks action. We propose and calculate two novel estimators for the chiral transition temperature for several values of the light quark masses, corresponding to Goldstone pion masses in the range of 58 MeV≲m_{π}≲163 MeV. The chiral phase transition temperature is determined by extrapolating to vanishing pion mass using universal scaling analysis. Finite-volume effects are controlled by extrapolating to the thermodynamic limit using spatial lattice extents in the range of 2.8-4.5 times the inverse of the pion mass. Continuum extrapolations are carried out by using three different values of the lattice cutoff, corresponding to lattices with temporal extents N_{τ}=6, 8, and 12. After thermodynamic, continuum, and chiral extrapolations, we find the chiral phase transition temperature T_{c}^{0}=132_{-6}^{+3} MeV.
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We present results for pseudo-critical temperatures of QCD chiral crossovers at zero and non-zero values of baryon (B), strangeness (S), electric charge (Q), and isospin (I) chemical potentials ...μX=B,Q,S,I. The results were obtained using lattice QCD calculations carried out with two degenerate up and down dynamical quarks and a dynamical strange quark, with quark masses corresponding to physical values of pion and kaon masses in the continuum limit. By parameterizing pseudo-critical temperatures as Tc(μX)=Tc(0)1−κ2X(μX/Tc(0))2−κ4X(μX/Tc(0))4, we determined κ2X and κ4X from Taylor expansions of chiral observables in μX. We obtained a precise result for Tc(0)=(156.5±1.5) MeV. For analogous thermal conditions at the chemical freeze-out of relativistic heavy-ion collisions, i.e., μS(T,μB) and μQ(T,μB) fixed from strangeness-neutrality and isospin-imbalance, we found κ2B=0.012(4) and κ4B=0.000(4). For μB≲300 MeV, the chemical freeze-out takes place in the vicinity of the QCD phase boundary, which coincides with the lines of constant energy density of 0.42(6)GeV/fm3 and constant entropy density of 3.7(5)fm−3.