Perovskite solar cells (PSCs) with an inverted structure (often referred to as the p-i-n architecture) are attractive for future commercialization owing to their easily scalable fabrication, reliable ...operation and compatibility with a wide range of perovskite-based tandem device architectures
. However, the power conversion efficiency (PCE) of p-i-n PSCs falls behind that of n-i-p (or normal) structure counterparts
. This large performance gap could undermine efforts to adopt p-i-n architectures, despite their other advantages. Given the remarkable advances in perovskite bulk materials optimization over the past decade, interface engineering has become the most important strategy to push PSC performance to its limit
. Here we report a reactive surface engineering approach based on a simple post-growth treatment of 3-(aminomethyl)pyridine (3-APy) on top of a perovskite thin film. First, the 3-APy molecule selectively reacts with surface formamidinium ions, reducing perovskite surface roughness and surface potential fluctuations associated with surface steps and terraces. Second, the reaction product on the perovskite surface decreases the formation energy of charged iodine vacancies, leading to effective n-type doping with a reduced work function in the surface region. With this reactive surface engineering, the resulting p-i-n PSCs obtained a PCE of over 25 per cent, along with retaining 87 per cent of the initial PCE after over 2,400 hours of 1-sun operation at about 55 degrees Celsius in air.
The role of the alkali metal cations in halide perovskite solar cells is not well understood. Using synchrotron-based nano-x-ray fluorescence and complementary measurements, we found that the halide ...distribution becomes homogenized upon addition of cesium iodide, either alone or with rubidium iodide, for substoichiometric, stoichiometric, and overstoichiometric preparations, where the lead halide is varied with respect to organic halide precursors. Halide homogenization coincides with long-lived charge carrier decays, spatially homogeneous carrier dynamics (as visualized by ultrafast microscopy), and improved photovoltaic device performance. We found that rubidium and potassium phase-segregate in highly concentrated clusters. Alkali metals are beneficial at low concentrations, where they homogenize the halide distribution, but at higher concentrations, they form recombination-active second-phase clusters.
Surface trap-mediated nonradiative charge recombination is a major limit to achieving high-efficiency metal-halide perovskite photovoltaics. The ionic character of perovskite lattice has enabled ...molecular defect passivation approaches through interaction between functional groups and defects. However, a lack of in-depth understanding of how the molecular configuration influences the passivation effectiveness is a challenge to rational molecule design. Here, the chemical environment of a functional group that is activated for defect passivation was systematically investigated with theophylline, caffeine, and theobromine. When N-H and C=O were in an optimal configuration in the molecule, hydrogen-bond formation between N-H and I (iodine) assisted the primary C=O binding with the antisite Pb (lead) defect to maximize surface-defect binding. A stabilized power conversion efficiency of 22.6% of photovoltaic device was demonstrated with theophylline treatment.
Organic-inorganic hybrid perovskites have electronic and optoelectronic properties that make them appealing in many device applications
. Although many approaches focus on polycrystalline materials
, ...single-crystal hybrid perovskites show improved carrier transport and enhanced stability over their polycrystalline counterparts, due to their orientation-dependent transport behaviour
and lower defect concentrations
. However, the fabrication of single-crystal hybrid perovskites, and controlling their morphology and composition, are challenging
. Here we report a solution-based lithography-assisted epitaxial-growth-and-transfer method for fabricating single-crystal hybrid perovskites on arbitrary substrates, with precise control of their thickness (from about 600 nanometres to about 100 micrometres), area (continuous thin films up to about 5.5 centimetres by 5.5 centimetres), and composition gradient in the thickness direction (for example, from methylammonium lead iodide, MAPbI
, to MAPb
Sn
I
). The transferred single-crystal hybrid perovskites are of comparable quality to those directly grown on epitaxial substrates, and are mechanically flexible depending on the thickness. Lead-tin gradient alloying allows the formation of a graded electronic bandgap, which increases the carrier mobility and impedes carrier recombination. Devices based on these single-crystal hybrid perovskites show not only high stability against various degradation factors but also good performance (for example, solar cells based on lead-tin-gradient structures with an average efficiency of 18.77 per cent).
Using scanning X-ray diffraction microscopy, we investigate the relationship between residual strains from crystal growth in CsPbBr3 thin-film crystals, their stability, and local photoluminescence ...(PL). We find that out-of-plane compressive strain that arises from cooldown from crystallization is detrimental to material stability under X-ray irradiation. We also find that the optical PL red-shifts as a result of the out-of-plane compressive strain. The sensitivity of the PL peak position to strain suggests possible applications such as stress-sensitive sensors. Mosaicity, the formation of small misorientations in neighboring crystalline domains we observe in some CsPbBr3 single crystals, indicates the significant variations in the crystal quality that can occur even in single-crystal halide perovskites. The nanodiffraction results suggest that reducing local strains is a necessary path to enhance the stability of perovskite optoelectronic materials and devices from light-emitting diodes to high-energy detectors.
Understanding reactions at the electrode/electrolyte interface (EEI) is essential to developing strategies to enhance cycle life and safety of lithium batteries. Despite research in the past four ...decades, there is still limited understanding by what means different components are formed at the EEI and how they influence EEI layer properties. We review findings used to establish the well-known mosaic structure model for the EEI (often referred to as solid electrolyte interphase or SEI) on negative electrodes including lithium, graphite, tin, and silicon. Much less understanding exists for EEI layers for positive electrodes. High-capacity Li-rich layered oxides yLi2–x MnO3·(1–y)Li1–x MO2, which can generate highly reactive species toward the electrolyte via oxygen anion redox, highlight the critical need to understand reactions with the electrolyte and EEI layers for advanced positive electrodes. Recent advances in in situ characterization of well-defined electrode surfaces can provide mechanistic insights and strategies to tailor EEI layer composition and properties.
Optoelectronic devices based on hybrid perovskites have demonstrated outstanding performance within a few years of intense study. However, commercialization of these devices requires barriers to ...their development to be overcome, such as their chemical instability under operating conditions. To investigate this instability and its consequences, the electric field applied to single crystals of methylammonium lead bromide (CH3NH3PbBr3) is varied, and changes are mapped in both their elemental composition and photoluminescence. Synchrotron‐based nanoprobe X‐ray fluorescence (nano‐XRF) with 250 nm resolution reveals quasi‐reversible field‐assisted halide migration, with corresponding changes in photoluminescence. It is observed that higher local bromide concentration is correlated to superior optoelectronic performance in CH3NH3PbBr3. A lower limit on the electromigration rate is calculated from these experiments and the motion is interpreted as vacancy‐mediated migration based on nudged elastic band density functional theory (DFT) simulations. The XRF mapping data provide direct evidence of field‐assisted ionic migration in a model hybrid‐perovskite thin single crystal, while the link with photoluminescence proves that the halide stoichiometry plays a key role in the optoelectronic properties of the perovskite.
Bromide‐ion migration is directly observed in a methylammonium lead bromide perovskite single crystal under bias using a synchrotron‐based X‐ray fluorescence nanoprobe. Photoluminescence mapping indicates that bromide‐rich regions exhibit enhanced photoluminescence. The close correspondence between the local bromide concentration and photoluminescence in response to bias reveals the importance of non‐stoichiometry in determining optoelectronic performance in halide perovskites.
Understanding the role of ferroelectric polarization in modulating the electronic and structural properties of crystals is critical for advancing these materials for overcoming various technological ...and scientific challenges. However, due to difficulties in performing experimental methods with the required resolution, or in interpreting the results of methods therein, the nanoscale morphology and response of these surfaces to external electric fields has not been properly elaborated. In this work we investigate the effect of ferroelectric polarization and local distortions in a BaTiO
3
perovskite, using two widely used computational approaches which treat the many-body nature of X-ray excitations using different philosophies, namely the many-body, delta-self-consistent-field determinant (mb-ΔSCF) and the Bethe-Salpeter equation (BSE) approaches. We show that in agreement with our experiments, both approaches consistently predict higher excitations of the main peak in the O-K edge for the surface with upward polarization. However, the mb-ΔSCF approach mostly fails to capture the L
2,3
separations at the Ti-L edge, due to the absence of spin-orbit coupling in Kohn-Sham density functional theory (KS-DFT) at the generalized gradient approximation level. On the other hand, and most promising, we show that application of the GW/BSE approach successfully reproduces the experimental XAS, both the relative peak intensities as well as the L
2,3
separations at the Ti-L edges upon ferroelectric switching. Thus simulated XAS is shown to be a powerful method for capturing the nanoscale structure of complex materials, and we underscore the need for many-body perturbation approaches, with explicit consideration of core-hole and multiplet effects, for capturing the essential physics in these systems.
We investigate ferroelectric local distortion in BaTiO
3
with two widely used computational approaches with different treatments of many-body excitation effects.
Increasing the stability of lead halide perovskites (LHPs) is critical for their practical application in solar cells and other technologies. Halide ion migration is one of the main contributors to ...instability and hysteresis in LHP solar cells. Here, we employ a series of Gedankenexperiments to quantitatively establish the correlated effects of the A site cation motion, H bonding strength, and octahedral rotation on halide ion migration in APbBr3 (A = Cs or methylammonium/MA) LHPs. We find that in cubic CsPbBr3, the increase of PbBr6 octahedra rotation/tilting during ion migration lowers the halide ion migration barrier by at least 100 meV compared to the orthorhombic phase. In MAPbBr3, we show that halide ion migration is also assisted by MA cation rotation to re-establish H bonding, resulting in lower halide migration barriers. These results suggest that “locking” the organic cation via chemical and processing means can help mitigate halide migration-induced instability and reduced hysteresis in LHP solar cells.
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