ABSTRACT There are many open questions about prebiotic chemistry in both planetary and exoplanetary environments. The increasing number of known exoplanets and other ultra-cool, substellar objects ...has propelled the desire to detect life and prebiotic chemistry outside the solar system. We present an ion-neutral chemical network constructed from scratch, Stand2015, that treats hydrogen, nitrogen, carbon, and oxygen chemistry accurately within a temperature range between 100 and 30,000 K. Formation pathways for glycine and other organic molecules are included. The network is complete up to H6C2N2O3. Stand2015 is successfully tested against atmospheric chemistry models for HD 209458b, Jupiter, and the present-day Earth using a simple one-dimensional photochemistry/diffusion code. Our results for the early Earth agree with those of Kasting for CO2, H2, CO, and O2, but do not agree for water and atomic oxygen. We use the network to simulate an experiment where varied chemical initial conditions are irradiated by UV light. The result from our simulation is that more glycine is produced when more ammonia and methane is present. Very little glycine is produced in the absence of any molecular nitrogen and oxygen. This suggests that the production of glycine is inhibited if a gas is too strongly reducing. Possible applications and limitations of the chemical kinetics network are also discussed.
Context. WASP-18b is an ultra-hot Jupiter with a temperature difference of up to 2500 K between day and night. Such giant planets begin to emerge as a planetary laboratory for understanding cloud ...formation and gas chemistry in well-tested parameter regimes in order to better understand planetary mass loss and for linking observed element ratios to planet formation and evolution. Aims. We aim to understand where clouds form, their interaction with the gas-phase chemistry through depletion and enrichment, the ionisation of the atmospheric gas, and the possible emergence of an ionosphere on ultra-hot Jupiters. Methods. We used 1D profiles from a 3D atmosphere simulation for WASP-18b as input for kinetic cloud formation and gas-phase chemical equilibrium calculations. We solved our kinetic cloud formation model for these 1D profiles, which sample the atmosphere of WASP-18b at 16 different locations along the equator and in the mid-latitudes. We derived the gas-phase composition consistently. Results. The dayside of WASP-18b emerges as completely cloud-free as a result of the very high atmospheric temperatures. In contrast, the nightside is covered in geometrically extended and chemically heterogeneous clouds with dispersed particle size distributions. The atmospheric C/O ratio increases to >0.7 and the enrichment of the atmospheric gas with cloud particles is ρd/ρgas > 10−3. The clouds that form at the limbs appear located farther inside the atmosphere, and they are the least extended. Not all day- to nightside terminator regions form clouds. The gas phase is dominated by H2, CO, SiO, H2O, H2S, CH4, and SiS. In addition, the dayside has a substantial degree of ionisation that is due to ions such as Na+, K+, Ca+, and Fe+. Al+ and Ti+ are the most abundant of their element classes. We find that WASP-18b, as one example for ultra-hot Jupiters, develops an ionosphere on the dayside.
Abstract
Clouds form in the atmospheres of planets where they can determine the observable spectra, the albedo and phase curves. Cloud properties are determined by the local thermodynamical and ...chemical conditions of an atmospheric gas. A retrieval of gas abundances requires a comprehension of the cloud formation mechanisms under varying chemical conditions. With the aim of studying cloud formation in metal-rich atmospheres, we explore the possibility of clouds in evaporating exoplanets like CoRoT-7b and 55 Cancri e (55 Cnc e) in comparison to a generic set of solar abundances and the metal-rich gas giant HD 149026b. We assess the impact of metal-rich, non-solar element abundances on the gas-phase chemistry, and apply our kinetic, non-equilibrium cloud formation model to study cloud structures and their details. We provide an overview of global cloud properties in terms of material compositions, maximum particle formation rates and average cloud particle sizes for various sets of rocky element abundances. Our results suggest that the conditions on 55 Cnc e and HD 149026b should allow the formation of mineral clouds in their atmosphere. The high temperatures on some hot rocky super-Earths (e.g. the day side of CoRoT-7b) result in an ionized atmospheric gas, and they prevent gas condensation, making cloud formation unlikely on its day side.
Context.
Ultra-hot Jupiters are the hottest exoplanets that have been discovered so far. Observations begin to provide insight into the composition of their extended atmospheres and their chemical ...day/night asymmetries. Both are strongly affected by cloud formation.
Aims.
We explore trends in cloud properties for a sample of five giant gas planets: the hot gas giant WASP-43b and the four ultra-hot Jupiters (UHJs) WASP-18b, HAT-P-7b, WASP-103b, and WASP-121b. This provides a reference frame for cloud properties for the JWST targets WASP-43b and WASP-121b. We further explore chemically inert tracers to observe geometrical asymmetries of UHJs and if the location of the inner boundary of a 3D global circulation model (3D GCM) matters for the clouds that form.
Methods.
A homogeneous set of 3D GCM results was used as input for a kinetic cloud formation code to evaluate the cloud opacity and gas parameters such as C/O, mean molecular weight, and degree of ionisation. We cast our results in terms of integrated quantities to enable a global comparison between the sample planets.
Results.
The large day/night temperature differences of UHJs cause the following chemical asymmetries: cloud-free days but cloudy nights, atomic versus molecular gases and their different mean molecular weights, deep thermal ionospheres versus low-ionised atmospheres, and undepleted versus enhanced C/O. WASP-18b, as the heaviest planet in the sample, has the lowest global C/O.
Conclusions.
The global climate may be considered as similar amongst UHJs, but different to that of hot gas giants. The local weather, however, is individual for each planet since the local thermodynamic conditions, and hence the local cloud and gas properties, differ. The morning and the evening terminator of UHJs will carry signatures of their strong chemical asymmetry such that ingress and egress asymmetries can be expected. An increased C/O ratio is a clear sign of cloud formation, making cloud modelling a necessity when utilising C/O (or other mineral ratios) as a tracer for planet formation. The changing geometrical extension of the atmosphere from the day to the nightside may be probed through chemically inert species such as helium. Ultra-hot Jupiters are likely to develop deep atmospheric ionospheres which may impact the atmosphere dynamics through magneto-hydrodynamic processes.
Context . Recent observations suggest the presence of clouds in exoplanet atmospheres, but they have also shown that certain chemical species in the upper atmosphere might not be in chemical ...equilibrium. Present and future interpretation of data from, for example, CHEOPS, JWST, PLATO, and Ariel require a combined understanding of the gas-phase and the cloud chemistry. Aims . The goal of this work is to calculate the two main cloud formation processes, nucleation, and bulk growth consistently from a non-equilibrium gas phase. The aim is also to explore the interaction between a kinetic gas-phase and cloud microphysics. Methods . The cloud formation is modelled using the moment method and kinetic nucleation, which are coupled to a gas-phase kinetic rate network. Specifically, the formation of cloud condensation nuclei is derived from cluster rates that include the thermochemical data of (TiO 2 ) N from N = 1 to 15. The surface growth of nine bulk Al, Fe, Mg, O, Si, S, and Ti binding materials considers the respective gas-phase species through condensation and surface reactions as derived from kinetic disequilibrium. The effect of the completeness of rate networks and the time evolution of the cloud particle formation is studied for an example exoplanet, HD 209458 b. Results . A consistent, fully time-dependent cloud formation model in chemical disequilibrium with respect to nucleation, bulk growth, and the gas-phase is presented and first test cases are studied. This model shows that cloud formation in exoplanet atmospheres is a fast process. This confirms previous findings that the formation of cloud particles is a local process. Tests on selected locations within the atmosphere of the gas-giant HD 209458 b show that the cloud particle number density and volume reach constant values within 1 s. The complex kinetic polymer nucleation of TiO 2 confirms results from classical nucleation models. The surface reactions of SiOs and SiO 2 s can create a catalytic cycle that dissociates H 2 to 2 H, resulting in a reduction of the CH 4 number densities.
Context.
Having a short orbital period and being tidally locked makes WASP-43b an ideal candidate for the
James Webb
Space Telescope (JWST) phase curve measurements. Phase curve observations of an ...entire orbit will enable the mapping of the atmospheric structure across the planet, with different wavelengths of observation allowing different atmospheric depths to be seen.
Aims.
We provide insight into the details of the clouds that may form on WASP-43b and their impact on the remaining gas phase, in order to prepare the forthcoming interpretation of the JWST and follow-up data.
Methods.
We follow a hierarchical modelling strategy. We utilise 3D GCM results as input for a kinetic, non-equilibrium model for mineral cloud particles and for a kinetic model to study a photochemically-driven hydrocarbon haze component.
Results.
Mineral condensation seeds form throughout the atmosphere of WASP-43b. This is in stark contrast to the ultra-hot Jupiters, such as WASP-18b and HAT-P-7b. The dayside is not cloud free but it is loaded with few yet large mineral cloud particles in addition to hydrocarbon haze particles of a comparable abundance. Photochemically driven hydrocarbon haze appears on the dayside, but it does not contribute to the cloud formation on the nightside. The geometrical cloud extension differs across the globe due to the changing thermodynamic conditions. Day and night differ by 6000 km in pressure scale height. As reported for other planets, the C/O is not constant throughout the atmosphere and varies between 0.74 and 0.3. The mean molecular weight is approximately constant in a H
2
-dominated WASP-43b atmosphere because of the moderate day/night-temperature differences compared to the super-hot Jupiters.
Conclusions.
WASP-43b is expected to be fully covered in clouds which are not homogeneously distributed throughout the atmosphere. The dayside and the terminator clouds are a combination of mineral particles of locally varying size and composition as well as of hydrocarbon hazes. The optical depth of hydrocarbon hazes is considerably lower than that of mineral cloud particles such that a wavelength-dependent radius measurement of WASP-43b would be determined by the mineral cloud particles but not by hazes.
3D atmosphere model results are used to comparatively study the kinetic, non-equilibrium cloud formation in the atmospheres of two example planets guided by the giant gas planets HD 209458b and ...HD 189733b. Rather independently of hydrodynamic model differences, our cloud modelling suggest that both planets are covered in mineral clouds throughout the entire modelling domain. Both planets harbour chemically complex clouds that are made of mineral particles that have a height-dependent material composition and size. The remaining gas-phase element abundances strongly affect the molecular abundances of the atmosphere in the cloud-forming regions. Hydrocarbon and cyanopolyyne molecules can be rather abundant in the inner, dense part of the atmospheres of HD 189733b and HD 209458b. No one value for metallicity and the C/O ratio can be used to describe an extrasolar planet. Our results concerning the presence and location of water in relation to the clouds explain some of the observed difference between the two planets. In HD 189733b, strong water features have been reported while such features appear less strong for HD 209458b. By considering the location of the clouds in the two atmospheres, we see that obscuring clouds exist high in the atmosphere of HD 209458b, but much deeper in HD 189733b. We further conclude that the (self-imposed) degeneracy of cloud parameters in retrieval methods can only be lifted if the cloud formation processes are accurately modelled in contrast to prescribing them by independent parameters.
We propose a classification of exoplanet atmospheres based on their H, C, O, and N element abundances below about 600 K. Chemical equilibrium models were run for all combinations of H, C, O, and N ...abundances, and three types of solutions were found, which are robust against variations of temperature, pressure, and nitrogen abundance. Type A atmospheres contain H2O, CH4, NH3, and either H2 or N2, but only traces of CO2 and O2. Type B atmospheres contain O2, H2O, CO2, and N2, but only traces of CH4, NH3, and H2. Type C atmospheres contain H2O, CO2, CH4, and N2, but only traces of NH3, H2, and O2. Other molecules are only present in ppb or ppm concentrations in chemical equilibrium, depending on temperature. Type C atmospheres are not found in the Solar System, where atmospheres are generally cold enough for water to condense, but exoplanets may well host such atmospheres. Our models show that graphite (soot) clouds can occur in type C atmospheres in addition to water clouds, which can occur in all types of atmospheres. Full-equilibrium condensation models show that the outgassing from warm rock can naturally provide type C atmospheres. We conclude that type C atmospheres, if they exist, would lead to false positive detections of biosignatures in exoplanets when considering the coexistence of CH4 and CO2, and suggest other, more robust non-equilibrium markers.
Recently, Fossati et al. observed that the UV transit of WASP-12b showed an early ingress compared with the optical transit. We suggest that the resulting early ingress is caused by a bow shock ahead ...of the planetary orbital motion. In this Letter, we investigate the conditions that might lead to the formation of such a bow shock. We consider two scenarios: (1) the stellar magnetic field is strong enough to confine the hot coronal plasma out to the planetary orbit and (2) the stellar magnetic field is unable to confine the plasma, which escapes in a wind. In both cases, a shock capable of compressing plasma to the observed densities will form around the planet for plasma temperatures T (4-5) X 106 K. In the confined case, the shock always forms directly ahead of the planet, but in the wind case the shock orientation depends on the wind speed and hence on the plasma temperature. For higher wind temperatures, the shock forms closer to the line of centers between the planet and the star. We conclude that shock formation leading to an observable early UV ingress is likely to be a common feature of transiting systems and may prove to be a useful tool in setting limits on planetary magnetic field strengths Bp . In the case of WASP-12b, we derive an upper limit of about Bp = 24 G.
Clouds form on extrasolar planets and brown dwarfs where lightning could occur. Lightning is a tracer of atmospheric convection, cloud formation and ionization processes as known from the Solar ...system, and may be significant for the formation of prebiotic molecules. We study lightning climatology for the different atmospheric environments of Earth, Venus, Jupiter and Saturn. We present lightning distribution maps for Earth, Jupiter and Saturn, and flash densities for these planets and Venus, based on optical and/or radio measurements from the World Wide Lightning Location Network and Sferics Timing and Ranging Network radio networks, the Lightning Imaging Sensor/Optical Transient Detector satellite instruments, the Galileo, Cassini, New Horizons and Venus Express spacecraft. We also present flash densities calculated for several phases of two volcano eruptions, Eyjafjallajökull's (2010) and Mt Redoubt's (2009). We estimate lightning rates for sample, transiting and directly imaged extrasolar planets and brown dwarfs. Based on the large variety of exoplanets, six categories are suggested for which we use the lightning occurrence information from the Solar system. We examine lightning energy distributions for Earth, Jupiter and Saturn. We discuss how strong stellar activity may support lightning activity. We provide a lower limit of the total number of flashes that might occur on transiting planets during their full transit as input for future studies. We find that volcanically very active planets might show the largest lightning flash densities. When applying flash densities of the large Saturnian storm from 2010/11, we find that the exoplanet HD 189733b would produce high lightning occurrence even during its short transit.
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