This paper presents the differences in the color changes of unsteamed and steamed beech wood (
L.) caused by long-term exposure to sunlight on the surface of wood in interiors for 36 months. The ...light white-gray color of the yellow tinge of native beech wood darkened under the influence of sunlight, and the wood took on a pale brown color of yellow tinge. The degree of darkening and browning is quantified by the value of the total color difference ∆
= 13.0. The deep brown-red color of steamed beech under the influence of sunlight during the exposure brightened, and the surface of the wood took on a pale brown hue. The degree of lightening of the color of steamed beech wood in the color space CIE
is quantified by the value of the total color difference ∆
= 7.1. A comparison of the color changes of unsteamed and steamed beech wood through the total color difference ∆
due to daylight shows that the surface of steamed beech wood shows 52.2% smaller changes than unsteamed beech wood. The lower value of the total color difference of steamed beech wood indicates the fact that steaming of beech wood with saturated water steam has a positive effect on the color stability and partial resistance of steamed beech wood to the initiation of photochemical reactions induced by UV-VIS wavelengths of solar radiation. Spectra ATR-FTIR analyses declare the influence of UV-VIS components of solar radiation on unsteamed and steamed beech wood and confirm the higher color stability of steamed beech wood.
The article presents the differences in some physical and chemical properties of wood with false heartwood, mature wood, and sapwood of Fagus sylvatica L.: density of wood in the dry state, color in ...the color space CIE L*a*b* on the tangential surface and the planed surface at w = 10 ± 0.5%, as well as moisture and acidity of wet wood. As part of chemical analyses, the relative proportion of cellulose, hemicelluloses, lignin, and extractive substances in individual zones of beechwood in trunks with false heartwood was determined. From the carried out analyses, it follows that the biggest difference between the wood of false heartwood, mature wood, and sapwood is the color of the wood. The red-brown color of the wood with false heartwood in the color space CIE L*a*b* is described by the following coordinate values: L* = 64.9 ± 4.9; a* = 12.9 ± 1.4; b* = 19.6 ± 1.7. The most significant differences between the values of the color space are on the lightness coordinate, where the light ochre-white of mature wood shows a decrease of ∆L* = −14.0 compared with the color of false heartwood, and the white—pale grey color of sapwood shows a decrease of ∆L* = −17.5. The density of dry beechwood with false heartwood is higher by ∆ρ0 = 4.7% than the density of mature wood, and the density of sapwood is ∆ρ0 = 12.3% lower than the density of wood with false heartwood. The exact opposite applies to the acidity of wet beechwood. The results of wet wood acidity measurements also point to certain differences. While the acidity of the wet wood of false heartwood is pH = 5.32 ± 0.13, the acidity of the sapwood is 5.1% lower. The higher acidity of beech heartwood is attributed to the presence of organic acids in polyphenols during heartwood formation. From the comparison of the representation of cellulose, hemicellulose, lignin, and extractive substances, it follows that the relative content of lignin and hemicelluloses is higher in false heartwood than in mature wood and sapwood. On the contrary, the content of holocellulose and cellulose is highest in sapwood. The presented divisions in the physical and chemical properties of beechwood with false heartwood do not limit the use of beechwood in industrial applications, except for a change in color; the definition of color boundaries in the color space CIE L*a*b* creates space for sorting beechwood according to color and can be used to increase the color variety of compositions of construction-carpentry products.
There is a global need to increase the production of alternative sources of energy due to many issues related to conventional sources, such as environmental degradation or energy security. In this ...paper, decentralized liquefied natural gas production is analyzed. Liquefied natural gas, according to the analysis, can be considered a viable alternative even for decentralized applications Design and economic analysis of a small-scale biogas LNG plan together with the necessary technology and economic evaluation are presented in the paper. The results show that a project of the proposed size (EUR 3 million) offers a relatively good profitability level. Specifically, the net present value of the project is mostly positive (around EUR 0.1 million up to EUR 0.8 million). Therefore, based on the research, small LNG plants operating across the continent can be recommended for the processing of local sources of biogas.
The visual inspection of fresh cut spruce wood (
, L. Karst.) showed the variability of its colour. Wood visual inspection is a part of wood quality assessment, for example, prior to or after its ...processing. The detail spruce wood colour analysis was performed using spectrophotometric data. The colour was measured by the bench-top spectrophotometer CM-5 Konica Minolta. The spectrophotometer was calibrated with a built-in white standard and on air. The whole analysis was performed in an xy chromaticity diagram supplemented with coordinate
and CIE L*a*b* colour spaces. The ratio of the white chromophore amount to the amount of all achromatic chromophores is related to the
coordinate. The ratio of the chromatic chromophore amount to all chromophores amount is saturation. The constructed model of the spruce wood colour is composed of four chromophores. The white chromophore belongs to holocellulose. The black chromophore belongs to lignin. The saturation is influenced by two chromophores. One of them belongs to extractives, another to lignin. The amounts of chromophores correlated with the spruce wood chemical composition. The chemical composition was measured using the procedures of Seifert, Wise, Sluiter, and ASTM. Moreover, the wood colour is affected by the moisture content.
Chemical composition and morphological properties of Norway spruce wood and bark were evaluated. The extractives, cellulose, hemicelluloses, and lignin contents were determined by wet chemistry ...methods. The dimensional characteristics of the fibers (length and width) were measured by Fiber Tester. The results of the chemical analysis of wood and bark show the differences between the trunk and top part, as well as in the different heights of the trunk and in the cross section of the trunk. The biggest changes were noticed between bark trunk and bark top. The bark top contains 10% more of extractives and 9.5% less of lignin. Fiber length and width depends on the part of the tree, while the average of these properties are larger depending on height. Both wood and bark from the trunk contains a higher content of fines (fibers <0.3 mm) and less content of longer fibers (>0.5 mm) compared to the top. During storage, it reached a decrease of extractives mainly in bark. Wood from the trunk retained very good durability in terms of chemical composition during the storage. In view of the morphological characteristics, it occurred to decrease both average fibers length and width in wood and bark.
European silver fir (Abies alba L.) wood was heat-treated in an oven for 60 min at seven different temperatures of 100 °C, 150 °C, 200 °C, 220 °C, 240 °C, 260 °C, and 280 °C under atmospheric ...pressure in the presence of air. The effect of thermal treatment on the chemical composition, mechanical, and color properties of the wood was studied, and the mutual correlations between the investigated properties were evaluated. The bending strength/modulus of rupture (MOR) and the modulus of elasticity (MOE) were positively correlated with the total saccharides, glucose, mannose, and xylose content, where R ranged from 0.942 to 0.984. For changes in the wood color, very strong positive correlations between the total color difference and the contents of lignin and extractives were determined, where R = 0.968 and 0.945 respectively. Additionally, the total color difference was negatively correlated with the total saccharides, mannose, and xylose content, where R ranged from 0.876 to 0.938. The obtained data were evaluated by principal component analysis (PCA), where the components explained 93.1% of the total variance.
Wood stock in a warehouse is a necessary precondition for reliable manufacturing. However, wood can degrade and lose the matter during storage. “Dry-matter loss (DML)” is used to quantify the ...degradation following the changes in mass of a wood substance. The proposed calculation of DML is based on using parallel figures. The calculated loss of spruce wood substance harvested in winter during a six-month period was 4.5%. The estimated annual loss of wood substance was 5.7%. The loss was caused by a factor with a gradually eliminated effect. The changes in the chemical composition of wood substance were not proportional to the original amount of the isolated chemical substances. Hemicelluloses and lignin suffered from the loss faster than there was a change in the DML of spruce wood. Hemicelluloses were the most unstable isolated compound, with an increased rate of change during the first four months. The number of extractives significantly decreased during two months of storage. However, there was an increase in the number of extractives after six months of storage. The loss of cellulose was similar to the DML of spruce wood during the whole time of storage. The FTIR analysis confirmed a decrease in the total crystalline index (TCI) and lateral order index (LOI) of cellulose due to the storage of roundwood.
Research in historical timber assessment is hindered by the limited availability of samples, yet understanding the fire resistance of historic wood is crucial for preservation efforts. There is an ...opinion that historic wood behaves similarly to contemporary wood in terms of fire resistance. The aim of this paper is to observe the rate of charring of historical pine wood during the experiment, the color changes in the sample that occurred due to thermal loading, and the changes in the chemical composition of pine wood. Test samples made from historic pine wood were loaded with a 50 kW∙m−2 radiation panel for 60 min. The charring process was faster at the beginning of the charred layer formation. The charring rate at the beginning of the test at a depth of 10 mm from the exposed side reached values from 1.28 mm∙min−1 to 3.16 mm∙min−1. At a depth of 30 mm from the exposed side, the individual charring rates approached a value of 1 mm∙min−1 (0.99 mm∙min−1 to 1.08 mm∙min−1). Observations during medium-scale testing revealed distinct layers forming on the exposed side: a charred layer, charring base, pyrolysis layer, and intact wood. The chemical composition of the wood changed under the influence of the thermal load. The relative contents of extractives and holocellulose decreased with the increasing temperature while the lignin content increased. The highest value of combustion heat was measured in the charred layer of the sample. Correlation analysis demonstrated a negative relationship between the combustion heat and holocellulose, while a positive correlation was found with the lignin content. Chemical changes were also monitored using the FTIR method. These findings provide valuable insights into the behavior of historic pine wood under thermal loading, which is essential for understanding and preserving historical structures.
This study aimed to determine the influence of increased temperature on the mass loss, chemical composition, and colour of pine wood because of the lack of such information. The colour was measured ...on samples of wood, extracted sawdust, holocellulose, and lignin isolated from the extracted sawdust of pine heartwood and sapwood. A wood sample labelled 20 °C was considered as wood with the original composition. Subsequently, we verified the measured values with the proposed mixing colour model. Pine heartwood and sapwood samples were thermally treated at temperatures of 100, 150, 200, 220, 240, and 260 °C for 1, 3, and 5 h. It was found that sapwood degraded faster than heartwood. The thermal treatment of wood increases lignin content and decreases holocellulose content, especially at 260 °C. The maximum extractive content of 3.60% was at 1 h and a temperature of 260 °C for both parts of the wood. Lightness values decreased with increasing temperature and time of treatment. The coordinate a* of heartwood showed a positive slope until one hour of treatment duration and a temperature of 240 °C. Then, it decreased for the subsequent duration of treatment. The same course was shown for the coordinate b* of sapwood at a temperature of 200 °C. The proposed model of mixing colours proved that changes in both parts of a wood-extracted substance, holocellulose, and lignin content, were responsible for the changing colour of extracted wood.
Biobutanol is a renewable, less polluting, and potentially viable alternative fuel to conventional gasoline. Biobutanol can be produced from same sources as bioethanol, and it has many advantages ...over the widespread bioethanol. This paper systematically analyzes biobutanol fuel as an alternative to bioethanol in alcohol-gasoline mixtures and the physicochemical properties. Based on the conducted analyses, it was found that biobutanol mixtures have a more suitable behavior of vapor pressure without the occurrence of azeotrope, do not form a separate phase in lower temperature, it has higher energy density, but slightly reduce the octane number and a have higher viscosity. However, in general, biobutanol has many advantageous properties that could allow its use in gasoline engines instead of the commonly used bioethanol.
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