Phosphorus (P) supply (concentration and flux) is an important driver for biological activity in flowing waters and needs to be managed to avoid eutrophication impacts associated with urbanisation ...and agricultural intensification. This paper examines the role of in-stream retention and cycling in regulating river P concentrations in order to better understand the links between P sources and their ecological impacts. In terms of their composition (solubility and concentration), patterns of delivery (mode and timing) and therefore ecological relevance, P sources entering rivers are best grouped into wastewater discharges > runoff from impervious surfaces (roads, farmyards) > runoff from pervious surfaces (forestry, cultivated land and pasture). The localized impacts of soluble P discharges during ecologically sensitive periods can be distinguished from the downstream impacts associated with particulate P discharges under high flows due to the different processes by which these sources are retained, transformed and assimilated within the river channel. The range of physico-chemical processes involved in P cycling and the variable importance of these processes in different river environments according to stream size, stream geomorphology and anthropogenic pressures are summarised. It is concluded that the capacity to retain (process) P within the river channel, and hence regulate the downstream delivery of P without stressing the aquatic communities present, is considerable, especially in headwaters. To help achieve good water quality, there is scope to better manage this ecosystem service through regulation of P supply whilst optimising in-stream P retention according to subsidy-stress theory. Further research is needed to develop in-stream management options for maximising P subsidies and to demonstrate that regulation of downstream P delivery will reduce the incidence of eutrophication in connected waterbodies.
Phosphorus losses from land to water will be impacted by climate change and land management for food production, with detrimental impacts on aquatic ecosystems. Here we use a unique combination of ...methods to evaluate the impact of projected climate change on future phosphorus transfers, and to assess what scale of agricultural change would be needed to mitigate these transfers. We combine novel high-frequency phosphorus flux data from three representative catchments across the UK, a new high-spatial resolution climate model, uncertainty estimates from an ensemble of future climate simulations, two phosphorus transfer models of contrasting complexity and a simplified representation of the potential intensification of agriculture based on expert elicitation from land managers. We show that the effect of climate change on average winter phosphorus loads (predicted increase up to 30% by 2050s) will be limited only by large-scale agricultural changes (e.g., 20-80% reduction in phosphorus inputs).The impact of climate change on phosphorus (P) loss from land to water is unclear. Here, the authors use P flux data, climate simulations and P transfer models to show that only large scale agricultural change will limit the effect of climate change on average winter P loads in three catchments across the UK.
The series of papers in this issue of AMBIO represent technical presentations made at the 7th International Phosphorus Workshop (IPW7), held in September, 2013 in Uppsala, Sweden. At that meeting, ...the 150 delegates were involved in round table discussions on major, predetermined themes facing the management of agricultural phosphorus (P) for optimum production goals with minimal water quality impairment. The six themes were (1) P management in a changing world; (2) transport pathways of P from soil to water; (3) monitoring, modeling, and communication; (4) importance of manure and agricultural production systems for P management; (5) identification of appropriate mitigation measures for reduction of P loss; and (6) implementation of mitigation strategies to reduce P loss. This paper details the major challenges and research needs that were identified for each theme and identifies a future roadmap for catchment management that cost-effectively minimizes P loss from agricultural activities.
Septic tank systems (STS) are a potential source of nutrient emissions to surface waters but few data exist in the UK to quantify their significance for eutrophication. We monitored the impact of STS ...on nutrient concentrations in a stream network around a typical English village over a 1-year period. Septic tank effluent discharging via a pipe directly into one stream was highly concentrated in soluble N (8–63mgL−1) and P (<1–14mgL−1) and other nutrients (Na, K, Cl, B and Mn) typical of detergent and household inputs. Ammonium-N (NH4N) and soluble reactive P (SRP) fractions were dominant (70–85% of total) and average concentrations of nitrite-N (NO2N) were above levels considered harmful to fish (0.1mgL−1). Lower nutrient concentrations were recorded at a ditch and a stream site, but range and average values downstream of rural habitation were still 4 to 10-fold greater than those in upstream sections. At the ditch site, where flow volumes were low, annual flow-weighted concentrations of NH4N and SRP increased from 0.04 and 0.07mgL−1, respectively upstream to 0.55 and 0.21mgL−1 downstream. At the stream site, flow volumes were twice as large and flow-weighted concentrations increased much less; from 0.04 to 0.21mgL−1 for NH4N and from 0.06 to 0.08mgL−1 for SRP. At all sites, largest nutrient concentrations were recorded under low flow and stream discharge was the most important factor determining the eutrophication impact of septic tank systems. The very high concentrations, intercorrelation and dilution patterns of SRP, NH4-N and the effluent markers Na and B suggested that soakaways in the heavy clay catchment soils were not retaining and treating the septic tank effluents efficiently, with profound implications for stream biodiversity. Water companies, water regulators and rural communities therefore need to be made more aware of the potential impacts of STS on water quality so that their management can be optimised to reduce the risk of potential eutrophication and toxicity to aquatic ecosystems during summer low flow periods.
► First direct UK evidence that nutrient emissions from septic tank systems affect water quality in rural areas. ► Septic tank soakaways on impermeable soils failed to adeqautely treat the septic tank effluent. ► The downstream eutrophication impact of septic tank systems largely depends on stream discharge volumes. ► Septic tank systems act as mini-point sources and need to better managed in catchment management planning.
We hypothesise that climate change, together with intensive agricultural systems, will increase the transfer of pollutants from land to water and impact on stream health. This study builds, for the ...first time, an integrated assessment of nutrient transfers, bringing together a) high-frequency data from the outlets of two surface water-dominated, headwater (~10km2) agricultural catchments, b) event-by-event analysis of nutrient transfers, c) concentration duration curves for comparison with EU Water Framework Directive water quality targets, d) event analysis of location-specific, sub-daily rainfall projections (UKCP, 2009), and e) a linear model relating storm rainfall to phosphorus load. These components, in combination, bring innovation and new insight into the estimation of future phosphorus transfers, which was not available from individual components. The data demonstrated two features of particular concern for climate change impacts. Firstly, the bulk of the suspended sediment and total phosphorus (TP) load (greater than 90% and 80% respectively) was transferred during the highest discharge events. The linear model of rainfall-driven TP transfers estimated that, with the projected increase in winter rainfall (+8% to +17% in the catchments by 2050s), annual event loads might increase by around 9% on average, if agricultural practices remain unchanged. Secondly, events following dry periods of several weeks, particularly in summer, were responsible for high concentrations of phosphorus, but relatively low loads. The high concentrations, associated with low flow, could become more frequent or last longer in the future, with a corresponding increase in the length of time that threshold concentrations (e.g. for water quality status) are exceeded. The results suggest that in order to build resilience in stream health and help mitigate potential increases in diffuse agricultural water pollution due to climate change, land management practices should target controllable risk factors, such as soil nutrient status, soil condition and crop cover.
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•Climate change may increase pollutant transfers from agricultural land.•High temporal resolution data enabled present day nutrient dynamics to be analysed.•High flow events (>Q10) transported >90% of sediment, >80% of phosphorus•Longer periods of low flow and high concentration will increase ecological risk.•Average phosphorus loads may increase by 9% with higher rainfall volume and intensity.
Reactive nitrogen (N) and phosphorus (P) inputs to surface waters modify aquatic environments, affect public health and recreation. Source controls dominate eutrophication management, whilst ...biological regulation of nutrients is largely neglected, although aquatic microbial organisms have huge potential to process nutrients. The stoichiometric ratio of organic carbon (OC) to N to P atoms should modulate heterotrophic pathways of aquatic nutrient processing, as high OC availability favours aquatic microbial processing. Heterotrophic microbial processing removes N by denitrification and captures N and P as organically-complexed, less eutrophying forms. With a global data synthesis, we show that the atomic ratios of bioavailable dissolved OC to either N or P in rivers with urban and agricultural land use are often distant from a “microbial optimum”. This OC-deficiency relative to high availabilities of N and P likely overwhelms within-river heterotrophic processing. We propose that the capability of streams and rivers to retain N and P may be improved by active stoichiometric rebalancing. Although autotrophic OC production contributes to heterotrophic rates substantial control on nutrient processing from allochthonous OC is documented for N and an emerging field for P. Hence, rebalancing should be done by reconnecting appropriate OC sources such as wetlands and riparian forests that have become disconnected from rivers concurrent with agriculture and urbanisation. However, key knowledge gaps require research prior to the safe implementation of this approach in management: (i) to evaluate system responses to catchment inputs of dissolved OC forms and amounts relative to internal production of autotrophic dissolved OC and aquatic and terrestrial particulate OC and (ii) evaluate risk factors in anoxia-mediated P desorption with elevated OC scenarios. Still, we find stoichiometric rebalancing through reconnecting landscape beneficial OC sources has considerable potential for river management to alleviate eutrophication, improve water quality and aquatic ecosystem health, if augmenting nutrient source control.
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•Eutrophication assessment should examine balances of the macronutrients C, N and P.•C:N and C:P stoichiometry was assessed in global catchment sources and river waters.•Excesses of NP relative to organic C was associated with agriculture and urbanisation.•Restoration of catchment C sources (e.g. wetlands) may drive microbial NP sequestration.
Diffuse nutrient loss from agriculture is degrading surface and groundwater quality throughout Europe, leaving water bodies at risk of not reaching targets set by the Water Framework Directive (WFD). ...Mitigation methods to reduce diffuse agricultural nutrient loss need to be implemented where water bodies have been identified as at risk of not reaching good status by 2015. Though the effectiveness of individual mitigation methods has usually been assessed in controlled experiments, it is necessary to quantify impact under a wider range of environmental and agricultural conditions and at the catchment scale to ensure that action taken now will be sufficient to meet WFD targets. Due to catchment buffering and long transit times (>
50 years), it is unlikely that responses to intervention will be observed by 2015 in many water bodies. In this review, we compare the attributes and usefulness of different approaches (direct measurement, nutrient budgeting, risk assessment and modelling) to assess the efficacy of actions to mitigate sources and transport of nitrogen (N) and phosphorus (P) from agricultural land to water. Modelling and ‘measured changes in farm activity’ through budgeting avoid the time lags associated with direct measurement and enable rapid evaluations of different options before implementation. Budgeting approaches using on-farm data also provide a simpler, more communicable means of assessment but currently fail to consider the timing and transport aspects of mitigation and assume a direct causal relationship between potential and actual nutrient loss. Risk assessment and modelling applications are potentially more comprehensive and able to better reflect choice of mitigation at a range of scales, but assessments demand increased availability of data, and there is a large degree of uncertainty associated with their spatial and temporal dimensions which is difficult to validate adequately. The failings of individual approaches suggest that these assessment methods should be integrated to maximise their potential usefulness and positive attributes. This will enable nutrient inputs to be utilised most efficiently at broad scales and site specific actions to reduce nutrient transport and delivery can be targeted most cost-effectively at smaller scales. Such an integrated approach will also more effectively engage and involve the farmer in what must be an iterative process.
The eutrophication of surface waters has become an endemic global problem. Nutrient loadings from agriculture are a major driver, but it remains very unclear what level of on-farm controls are ...necessary or can be justified to achieve water quality improvements. In this review article, we use the UK as an example of societies' multiple stressors on water quality to explore the uncertainties and challenges in achieving a sustainable balance between useable water resources, diverse aquatic ecosystems and a viable agriculture. Our analysis shows that nutrient loss from agriculture is a challenging issue if farm productivity and profitability is to be maintained and increased. Legacy stores of nitrogen (N) and phosphorus (P) in catchments may be sufficient to sustain algal blooms and murky waters for decades to come and more innovation is needed to drawdown and recover these nutrients. Agriculture's impact on eutrophication risk may also be overestimated in many catchments, and more accurate accounting of sources, their bioavailabilities and lag times is needed to direct proportioned mitigation efforts more effectively. Best practice farms may still be leaky and incompatible with good water quality in high-risk areas requiring some prioritization of society goals. All sectors of society must clearly use N and P more efficiently to develop long-term sustainable solutions to this complex issue and nutrient reduction strategies should take account of the whole catchment-to-coast continuum. However, the right balance of local interventions (including additional biophysical controls) will need to be highly site specific and better informed by research that unravels the linkages between sustainable farming practices, patterns of nutrient delivery, biological response and recovery trajectories in different types of waterbodies.
This commentary examines an “inconvenient truth” that phosphorus (P)‐based nutrient mitigation, long regarded as the key tool in eutrophication management, in many cases has not yet yielded the ...desired reductions in water quality and nuisance algal growth in rivers and their associated downstream ecosystems. We examine why the water quality and aquatic ecology have not recovered, in some case after two decades or more of reduced P inputs, including (i) legacies of past land‐use management, (ii) decoupling of algal growth responses to river P loading in eutrophically impaired rivers; and (iii) recovery trajectories, which may be nonlinear and characterized by thresholds and alternative stable states. It is possible that baselines have shifted and that some disturbed river environments may never return to predisturbance conditions or may require P reductions below those that originally triggered ecological degradation. We discuss the practical implications of setting P‐based nutrient criteria to protect and improve river water quality and ecology, drawing on a case study from the Red River Basin in the United States. We conclude that the challenges facing nutrient management and eutrophication control bear the hallmarks of “postnormal” science, where uncertainties are large, management intervention is urgently required, and decision stakes are high. We argue a case for a more holistic approach to eutrophication management that includes more sophisticated regime‐based nutrient criteria and considers other nutrient and pollutant controls and river restoration (e.g., physical habitat and functional food web interactions) to promote more resilient water quality and ecosystem functioning along the land–freshwater continuum.
Friction stir welding of aluminium alloys Threadgill, P L; Leonard, A J; Shercliff, H R ...
International materials reviews,
03/2009, Volume:
54, Issue:
2
Journal Article
Peer reviewed
The comprehensive body of knowledge that has built up with respect to the friction stir welding (FSW) of aluminium alloys since the technique was invented in 1991 is reviewed. The basic principles of ...FSW are described, including thermal history and metal flow, before discussing how process parameters affect the weld microstructure and the likelihood of entraining defects. After introducing the characteristic macroscopic features, the microstructural development and related distribution of hardness are reviewed in some detail for the two classes of wrought aluminium alloy (non-heat-treatable and heat-treatable). Finally, the range of mechanical properties that can be achieved is discussed, including consideration of residual stress, fracture, fatigue and corrosion. It is demonstrated that FSW of aluminium is becoming an increasingly mature technology with numerous commercial applications. In spite of this, much remains to be learned about the process and opportunities for further research and development are identified.
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