Petroleum-based plastics are useful but they pose a great threat to the environment and human health. It is highly desirable yet challenging to develop sustainable structural materials with excellent ...mechanical and thermal properties for plastic replacement. Here, inspired by nacre's multiscale architecture, we report a simple and efficient so called "directional deforming assembly" method to manufacture high-performance structural materials with a unique combination of high strength (281 MPa), high toughness (11.5 MPa m
), high stiffness (20 GPa), low coefficient of thermal expansion (7 × 10
K
) and good thermal stability. Based on all-natural raw materials (cellulose nanofiber and mica microplatelet), the bioinspired structural material possesses better mechanical and thermal properties than petroleum-based plastics, making it a high-performance and eco-friendly alternative structural material to substitute plastics.
As an abundant natural resource, wood has gained great attention for thousands of years, spanning from the primitive construction materials to the modern high‐added‐value engineering materials. The ...unique delicate microstructures and the wonderful properties (e.g., low‐density, high strength and stiffness, good toughness, and environmental sustainability) have made wood a natural source of inspiration that guides researchers to invent various wood‐inspired materials. Herein, as an emerging material system, bioinspired artificial wood, with similar cellular structures and comparable mechanical properties, is discussed in the view of the design concept, fabrication strategy, properties, and possible applications. The present challenges and further research opportunities are also presented for artificial woods to thrive. To achieve the final eco‐friendly artificial wood, more endeavors should be made in biomaterials and biodegradable or recyclable engineering of polymers to gain high mechanical properties and environmental sustainability simultaneously.
Artificial woods have emerged as a novel kind of wood‐inspired engineering material with almost exactly the same channel microstructures and similar wall components. The performances of artificial woods depend on both the oriented channel and wall designs. The rational combination of other engineering polymers and channel‐making techniques hold promise to develop more useful artificial woods.
The widespread use of disposable plastic straws cause serious environmental problems and poses potential threats to human health, while paper straws, their most used alternatives, are not so ...satisfactory due to poor mechanical performance and unpleasant user experience. Here, a new kind of edible and microplastic‐free straw made from bacterial cellulose (BC) by biosynthesis is reported. Through the alginate coating, this BC‐based straw achieves better mechanical performance than paper straws and avoids additional adhesives. Owing to the 3D nanofiber network and strong interlayer connection, the comprehensive performance of this BC‐based straw surpasses that of commercially available counterparts, satisfying the requirements for practical use. Of particular note, the edible character provides a better user experience and a new end‐of‐life option for the straws, making the BC‐based straw a healthier and more eco‐friendly substitute for plastic straws.
A sustainable, microplastic‐free, ultrastrong, and edible straw is fabricated through biosynthesis. This bacterial cellulose‐based straw demonstrates great sustainability and excellent mechanical performance, representing an ideal substitute for plastic straws and a powerful competitor for paper straws. The 3D network of bacterial cellulose endows the straw with the ability to carry functional substances like flavor molecules, providing a better user experience.
Widely used disposable plastic tableware is usually buried or directly discharged into the natural environment after using, which poses potential threats to the natural environment and human health. ...To solve this problem, nondegradable plastic tableware needs to be replaced by tableware composed of biodegradable structural materials with both food safety and the excellent mechanical and thermal properties. Here, a food‐safe sargassum cellulose nanofiber (SCNF) is extracted from common seaweed in an efficient and low energy consuming way under mild reaction conditions. Then, by assembling the SCNF into a dense bulk material, a strong sargassum cellulose nanofiber structural material (SCNSM) with high strength (283 MPa) and high thermal stability (>160 °C) can be prepared. The SCNSM also possesses good machinability, which can be processed into tableware with different shapes, e.g., knives and forks. The overall performance of the SCNSM‐based tableware is better than commercial plastic, wood‐based, and poly(lactic acid) tableware, which shows great application potential in the tableware field.
A food‐safe sargassum cellulose nanofiber (SCNF) is extracted through an efficient and low energy consuming way. Then, by assembling the SCNF into a dense bulk material, a strong structural material can be prepared. It possesses good machinability, which can be processed into tableware with better overall performance than that of commercial tableware, showing great application potential in the tableware field.
An All‐Natural Wood‐Inspired Aerogel Han, Zi‐Meng; Sun, Wen‐Bin; Yang, Kun‐Peng ...
Angewandte Chemie International Edition,
February 1, 2023, 2023-Feb-01, 2023-02-00, 20230201, Volume:
62, Issue:
6
Journal Article
Peer reviewed
The oriented pore structure of wood endows it with a variety of outstanding properties, among which the low thermal conductivity has attracted researchers to develop wood‐like aerogels as excellent ...thermal insulation materials. However, the increasing demands of environmental protection have put forward new and strict requirements for the sustainability of aerogels. Here, we report an all‐natural wood‐inspired aerogel consisting of all‐natural ingredients and develop a method to activate the surface‐inert wood particles to construct the aerogel. The obtained wood‐inspired aerogel has channel structure similar to that of natural wood, endowing it with superior thermal insulation properties to most existing commercial sponges. In addition, remarkable fire retardancy and complete biodegradability are integrated. With the above outstanding performances, this sustainable wood‐inspired aerogel will be an ideal substitute for the existing commercial thermal insulation materials.
An interesting surface nanocrystallization method was developed to make the surface‐inert and weakly interacting wood particles better assemble to construct the aerogel. This bottom‐up method allows the preparation of large‐size composite aerogels. The wood‐inspired oriented channel structure endows the obtained aerogel with superior thermal insulation properties to natural wood and most existing commercial sponges.
Undoubtedly humidity is a non-negligible and sensitive problem for cellulose, which is usually regarded as one disadvantage to cellulose-based materials because of the uncontrolled deformation and ...mechanical decline. But the lack of an in-depth understanding of the interfacial behavior of nanocellulose in particular makes it challenging to maintain anticipated performance for cellulose-based materials under varied relative humidity (RH). Starting from multiscale mechanics, we herein carry out first-principles calculations and large-scale molecular dynamics simulations to demonstrate the humidity-mediated interface in hierarchical cellulose nanocrystals (CNCs) and associated deformation modes. More intriguingly, the simulations and subsequent experiments reveal that water molecules (moisture) as the interfacial media can strengthen and toughen nanocellulose simultaneously within a suitable range of RH. From the perspective of interfacial design in materials, the anomalous mechanical behavior of nanocellulose with humidity-mediated interfaces indicates that flexible hydrogen bonds (HBs) play a pivotal role in the interfacial sliding. The difference between CNC–CNC HBs and CNC–water–CNC HBs triggers the humidity-mediated interfacial slipping in nanocellulose, resulting in the arising of a pronounced strain hardening stage and the suppression of strain localization during uniaxial tension. This inelastic deformation of nanocellulose with humidity-mediated interfaces is similar to the Velcro-like behavior of a wet wood cell wall. Our investigations give evidence that the humidity-mediated interface can promote the mechanical enhancement of nanocellulose, which would provide a promising strategy for the bottom-up design of cellulose-based materials with tailored mechanical properties.
Flexible supercapacitors represent an attractive technology for the next generation of wearable consumer electronics as power sources but usually suffer from relatively low energy density. It is ...highly desired to construct high‐performance electrodes for the practical applications of supercapacitors. Here, inspired by the natural structure of the spider web, an elaborate design of binder is reported through a biosynthesis process to construct flexible electrodes with both excellent mechanical properties and electrochemical performance. Through this strategy, a spider‐web‐inspired 3D structural binder enables large ion‐accessible surface area and high packing density of active electrode material as well as efficient ion transport pathways. As a result, a high areal capacitance of 4.62 F cm‐2 and a high areal energy density of 0.18 mW h cm‐2 is achieved in the composite electrodes and symmetric supercapacitors, respectively, demonstrating a promising potential to construct flexible energy storage devices for diverse practical applications.
A spider‐web‐inspired composite electrode is developed by biosynthesis process. With the 3D structural binder, electrode material particles are tightly entangled in the bacterial cellulose 3D framework, endowing electrodes with excellent mechanical performance and facilitated ion diffusion. Thereby, spider‐web‐inspired composite electrodes exhibit high areal capacitance and demonstrate excellent rate capability, making them promising wearable and portable electronic applications.
The exploration of extreme environments has become necessary for understanding and changing nature. However, the development of functional materials suitable for extreme conditions is still ...insufficient. Herein, a kind of nacre‐inspired bacterial cellulose (BC)/synthetic mica (S‐Mica) nanopaper with excellent mechanical and electrical insulating properties that has excellent tolerance to extreme conditions is reported. Benefited from the nacre‐inspired structure and the 3D network of BC, the nanopaper exhibits excellent mechanical properties, including high tensile strength (375 MPa), outstanding foldability, and bending fatigue resistance. In addition, S‐Mica arranged in layers endows the nanopaper with remarkable dielectric strength (145.7 kV mm−1) and ultralong corona resistance life. Moreover, the nanopaper is highly resistant to alternating high and low temperatures, UV light, and atomic oxygen, making it an ideal candidate for extreme environment‐resistant materials.
A nacre‐inspired nanopaper is fabricated through an aerosol‐assisted biosynthesis (AABS) strategy. Based on the AABS strategy and biomimetic structure design, the nanopaper has excellent mechanical properties, high dielectric strength, and ultralong corona resistance time. The dielectric‐mechanical comprehensive performance of the nanopaper is far beyond that of various commercial mica papers.
All‐natural materials derived from cellulose nanofibers (CNFs) are expected to be used to replace engineering plastics and have attracted much attention. However, the lack of crack extension ...resistance and 3D formability of nanofiber‐based structural materials hinders their practical applications. Here, a multiscale interface engineering strategy is reported to construct high‐performance cellulose‐based materials. The sisal microfibers are surface treated to expose abundant active CNFs with positive charges, thereby enhancing their interfacial combination with the negatively charged CNFs. The robust multiscale dual network enables easy molding of multiscale cellulose‐based structural materials into complex 3D special‐shaped structures, resulting in nearly twofold and fivefold improvements in toughness and impact resistance compared with those of CNFs‐based materials. Moreover, this multiscale interface engineering strategy endows cellulose‐based structural materials with better comprehensive performance than petrochemical‐based plastics and broadens cellulose's potential for lightweight applications as structural materials with lower environmental effects.
A high‐performance multiscale cellulose‐based structural material is constructed through a multiscale interface engineering strategy. The positive and negative charges treatment of microfibers and nanofibers effectively solves the interface bonding problem in multiscale design, and allows them to be easily shaped into complex three‐dimensional special‐shaped structures. This sustainable material offers superior mechanical and thermal properties compared to petrochemical‐based plastics.
Plastic packaging materials are widely used because of their advantages of light weight, low cost, and convenience, especially as victuals packaging materials. Approximately 146 million metric tons ...of plastics were used for packaging in 2015, but most of these plastics had already been discarded and followed by serious white pollution. What's worse, the victuals packaging materials, especially polystyrene (PS) foam containers, can release microplastics (MPs) during daily usage. Through the combination of various appropriate chemical (eg, spectroscopy) and physical (eg, microscopy) characterization and analysis, the existence of MPs is proved and MPs can be intuitively observed. Although the impacts of MPs on ecosystems and human health are still under discussion, existing studies have shown that MPs can be integrated into habitats through soil transportation, affecting the health of various terrestrial invertebrates. Faced with this shocking reality, reducing the use of PS foam containers at high temperatures and developing healthy materials to substitute these plastics are promising solutions.
Based on the various appropriate chemical (e.g., spectroscopy) and physical (e.g., microscope) characterization and analysis, this paper provides sufficient evidence for the fact that the victuals packaging materials, especially polystyrene foam containers, can release microplastics (MPs) during daily usage. MPs have various sizes and irregularly shapes, which have potential threats to the ecosystems and human health.