We review theories of dark matter (DM) beyond the collisionless paradigm, known as self-interacting dark matter (SIDM), and their observable implications for astrophysical structure in the Universe. ...Self-interactions are motivated, in part, due to the potential to explain long-standing (and more recent) small scale structure observations that are in tension with collisionless cold DM (CDM) predictions. Simple particle physics models for SIDM can provide a universal explanation for these observations across a wide range of mass scales spanning dwarf galaxies, low and high surface brightness spiral galaxies, and clusters of galaxies. At the same time, SIDM leaves intact the success of ΛCDM cosmology on large scales. This report covers the following topics: (1) small scale structure issues, including the core–cusp problem, the diversity problem for rotation curves, the missing satellites problem, and the too-big-to-fail problem, as well as recent progress in hydrodynamical simulations of galaxy formation; (2) N-body simulations for SIDM, including implications for density profiles, halo shapes, substructure, and the interplay between baryons and self-interactions; (3) semi-analytic Jeans-based methods that provide a complementary approach for connecting particle models with observations; (4) merging systems, such as cluster mergers (e.g., the Bullet Cluster) and minor infalls, along with recent simulation results for mergers; (5) particle physics models, including light mediator models and composite DM models; and (6) complementary probes for SIDM, including indirect and direct detection experiments, particle collider searches, and cosmological observations. We provide a summary and critical look for all current constraints on DM self-interactions and an outline for future directions.
The emergence of plastic electronics satisfies the increasing demand for flexible electronics. However, it has caused severe ecological problems. Flexible electronics based on natural materials are ...increasing to hopefully realize the “green” and eco‐friendly concept. Herein, recent advances in the design and fabrication of green flexible electronics are reviewed. First, this review comprehensively introduces various natural materials and derivatives, focusing particularly on fibroin and silk, wood and paper, plants, and biomass. Second, fabrication techniques for modifying natural materials, including physical and chemical methods, are presented, after which their merits and demerits are thoroughly discussed. Green flexible electronics based on natural materials, comprising electrical wires/electrodes, antennas, thermal management devices, transistors, memristors, sensors, energy‐harvesting devices, energy‐storage devices, displays, actuators, electromagnetic shielding, and integration systems, are described in detail. Finally, perspectives on the existing challenges and opportunities to employ natural materials in green flexible electronics are presented.
The recent advances in the elaborate design and fabrication of functional natural materials and natural‐materials‐based green flexible electronics are reviewed. Natural materials and derivatives, functionalization techniques of natural materials, and applications to green flexible electronics are presented in detail in sequence. Last, the perspectives on current challenges and opportunities of green flexible electronics based on natural materials are provided.
Flexible electronics is an emerging field of research involving multiple disciplines, which include but not limited to physics, chemistry, materials science, electronic engineering, and biology. ...However, the broad applications of flexible electronics are still restricted due to several limitations, including high Young's modulus, poor biocompatibility, and poor responsiveness. Innovative materials aiming for overcoming these drawbacks and boost its practical application is highly desirable. Hydrogel is a class of 3D crosslinked hydrated polymer networks, and its exceptional material properties render it as a promising candidate for the next generation of flexible electronics. Here, the latest methods of synthesizing advanced functional hydrogels and the state‐of‐art applications of hydrogel‐based flexible electronics in various fields are reviewed. More importantly, the correlation between properties of the hydrogel and device performance is discussed here, to have better understanding of the development of flexible electronics by using environmentally responsive hydrogels. Last, perspectives on the current challenges and future directions in the development of hydrogel‐based multifunctional flexible electronics are provided.
The latest methods of synthesizing advanced functional hydrogels and the state‐of‐art applications of hydrogel‐based flexible electronics in various fields are reviewed. More importantly, the correlation between properties of the hydrogel and device performance, to have better understanding of the development of flexible electronics by using environmentally responsive hydrogels are discussed. Last, perspectives on the current challenges and future directions in the development of hydrogel‐based multifunctional flexible electronics are provided.
Herein we report the development of a turn‐on lanthanide luminescent probe for time‐gated detection of nitroreductases (NTRs) in live bacteria. The probe is activated through NTR‐induced formation of ...the sensitizing carbostyril antenna and resulting energy transfer to the lanthanide center. This novel NTR‐responsive trigger is virtually non‐fluorescent in its inactivated form and features a large signal increase upon activation. We show that the probe is capable of selectively sensing NTR in lysates as well as in live bacteria of the ESKAPE family which are clinically highly relevant multiresistant pathogens responsible for the majority of hospital infections. The results suggest that our probe could be used to develop diagnostic tools for bacterial infections.
Illuminating pathogens: A terbium‐based luminescent turn‐on probe was developed capable of tracing nitroreductase in live bacteria using fluorescence lifetime imaging. The probe thus could be used as a new tool for the imaging of bacterial infections.
Too big to fail in light of Gaia Kaplinghat, Manoj; Valli, Mauro; Yu, Hai-Bo
Monthly notices of the Royal Astronomical Society,
11/2019, Volume:
490, Issue:
1
Journal Article
Peer reviewed
Open access
ABSTRACT
We point out an anticorrelation between the central dark matter (DM) densities of the bright Milky Way dwarf spheroidal galaxies (dSphs) and their orbital pericenter distances inferred from ...Gaia data. The dSphs that have not come close to the Milky Way centre (like Fornax, Carina and Sextans) are less dense in DM than those that have come closer (like Draco and Ursa Minor). The same anticorrelation cannot be inferred for the ultrafaint dSphs due to large scatter, while a trend that dSphs with more extended stellar distributions tend to have lower DM densities emerges with ultrafaints. We discuss how these inferences constrain proposed solutions to the Milky Way’s too-big-to-fail problem and provide new clues to decipher the nature of DM.
The exploring of catalysts with high‐efficiency and low‐cost for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is one of the key issues for many renewable energy systems ...including fuel cells, metal–air batteries, and water splitting. Despite several decades pursuing, bifunctional oxygen catalysts with high catalytic performance at low‐cost, especially the one that could be easily scaled up for mass production are still missing and highly desired. Herein, a hybrid catalyst with NiCo alloy nanoparticles decorated on N‐doped carbon nanofibers is synthesized by a facile electrospinning method and postcalcination treatment. The hybrid catalyst NiCo@N‐C 2 exhibits outstanding ORR and OER catalytic performances, which is even surprisingly superior to the commercial Pt/C and RuO2 catalysts, respectively. The synergetic effects between alloy nanoparticles and the N‐doped carbon fiber are considered as the main contributions for the excellent catalytic activities, which include decreasing the intrinsic and charge transfer resistances, increasing CC, graphitic‐N/pyridinic‐N contents in the hybrid catalyst. This work opens up a new way to fabricate high‐efficient, low‐cost oxygen catalysts with high production.
NiCo alloy nanoparticles decorated on N‐doped carbon nanofibers as a highly active and durable oxygen electrocatalyst at low‐cost are synthesized and reported. The hybrid catalyst with suitable amount of NiCo alloy nanoparticles loading (NiCo@N‐C 2) gives the most outstanding oxygen reduction reaction and oxygen evolution reaction electrocatalytic performances, which is even surprisingly superior to the commercial Pt/C and RuO2 catalysts, respectively.
Aerogels, a type of fascinating material with very low density and high surface area, show many unique properties and unlimited applications. To boost their practical applications, it is necessary to ...develop efficient, controllable, and low‐cost methods to produce high‐performance aerogels on a large‐scale, preferably in a sustainable way. Here, a general strategy is reported for controllable fabrication of a family of carbonaceous nanofiber aerogels (CNFAs) by biomass‐derived nanofibers template‐directed hydrothermal carbonization method. Abundant functional groups are exposed on the surface of the prepared carbonaceous nanofibers. Importantly, in contrast to traditional nature biopolymer‐based aerogels, a superior combination of good recoverability and high strength is achieved for the CNFAs by adjusting the synthetic parameters. The successful synthesis of such fascinating materials provides an excellent platform for design and construction of devices for fast water treatment. The synthetic strategy and sustainable concept presented in this work will open a new way to prepare advanced aerogels with unique properties for wide applications.
Biomass‐derived nanofibers, including amyloid nanofibrils, aminated cellulose nanofibers, and deacetylated chitin nanofibers, are used as templates to direct the hydrothermal carbonization of glucose. The obtained carbonaceous nanofiber aerogels with rigid 3D cross‐linked structures provide an excellent platform for design and construction of powerful devices for fast water purification.