Context. Dynamical masses of young planets aged between 10 and 200 Myr detected in imaging play a crucial role in shaping models of giant planet formation. Regrettably, only a few such objects ...possess these characteristics. Furthermore, the evolutionary pattern of young sub-stellar companions in near-infrared colour-magnitude diagrams might diverge from free-floating objects, possibly due to differing formation processes. Aims. The recent identification of a giant planet around AF Lep, part of the β Pic moving group (BPMG), encouraged us to re-examine these points. Methods. We considered updated dynamical masses and luminosities for the sub-stellar objects in the BPMG. In addition, we compared the properties of sub-stellar companions and free-floating objects in the BPMG and other young associations remapping the positions of the objects in the colour-magnitude diagram into a dustiness-temperature plane. Results. We found that cold-start evolutionary models do not reproduce the mass-luminosity relation for sub-stellar companions in the BPMG. This aligns rather closely with predictions from “hot start” scenarios and is consistent with recent planet formation models. We obtain rather good agreement with masses from photometry and the remapping approach compared to actual dynamical masses. We also found a strong suggestion that the near-infrared colour-magnitude diagram for young companions is different from that of free-floating objects belonging to the same young associations. Conclusions. If confirmed by further data, this last result would imply that cloud settling – which likely causes the transition between L and T spectral type – occurs at a lower effective temperature in young companions than in free-floating objects. This might tentatively be explained with a different chemical composition.
Summary 565 I. LMA in perspective 566 II. LMA in the field 567 III. Inherent differences 568 IV. Relation with anatomy and chemical composition 570 V. Environmental effects 572 VI. Differences in ...space and time 577 VII. Molecular regulation and physiology 579 VIII. Ecological consequences 580 IX. Conclusions and perspectives 582 Acknowledgements 582 References 582 Appendices 587
Over the last several years, inorganic-organic hybrid perovskites have shown dramatic achievements in photovoltaic performance and device stability. Despite the significant progress in photovoltaic ...application, an in-depth understanding of the fundamentals of precursor solution chemistry is still lacking. In this review, the fundamental background knowledge of nucleation and crystal growth processes in solution including the LaMer model and Ostwald ripening process is described. This review article also highlights the recent progress in precursor-coordinating molecule interaction in solution along with the role of anti-solvent in the solvent engineering process to control nucleation and crystal growth. Moreover, chemical pathways from precursor solution to perovskite film formation are given. This represents identification of the intermediate phase induced by precursor-coordinating molecule interaction and responsible intermediate species for uniform and dense perovskite film formation. Further to the description of chemical phenomena in solution, the contemporary progress in chemical precursor composition is also provided to comprehend the current research approaches to further enhance photovoltaic performance and device stability. On the basis of the critical and comprehensive review, we provide some perspectives to further achieve high-performance perovskite solar cells with long-term device stability through precisely controlled nucleation and crystal growth in precursor solution.
The perovskite precursor solution chemistry is of paramount importance for well-controlled nucleation/crystal growth in solution-processed perovskite solar cells.
In recent years, the concept of entropy stabilization of crystal structures in oxide systems has led to an increased research activity in the field of "high entropy oxides". These compounds comprise ...the incorporation of multiple metal cations into single-phase crystal structures and interactions among the various metal cations leading to interesting novel and unexpected properties. Here, we report on the reversible lithium storage properties of the high entropy oxides, the underlying mechanisms governing these properties, and the influence of entropy stabilization on the electrochemical behavior. It is found that the stabilization effect of entropy brings significant benefits for the storage capacity retention of high entropy oxides and greatly improves the cycling stability. Additionally, it is observed that the electrochemical behavior of the high entropy oxides depends on each of the metal cations present, thus providing the opportunity to tailor the electrochemical properties by simply changing the elemental composition.
An extended study on the oxidative potential (OP) of PM10 particles collected from December 2014 to October 2015 at a peninsular site of the Central Mediterranean basin has been performed. PM10 ...particles have been selected to better account for all different aged/fresh particle types. Two acellular assays, i.e., the dithiothreitol (DTT) and ascorbic acid (AA) methods, were used to measure the OP of PM10 particles chemically speciated by more than 40 species.
DTT and AA assays provide close mean values of volume normalized OPV responses, with similar variability range, i.e., mean OPDTTV = 0.24 ± 0.12 nmolDTT min−1 m−3 and mean OPAAV = 0.29 ± 0.18 nmolAA min−1 m−3. Also mass normalized OPm responses are similar for both assays, with mean value close to 0.008 nmol min−1 μg−1.
The measured OPDTTV and OPAAV are correlated with several inorganic species, namely ions and metals, and with organic/elemental carbon. The discrimination of the data according seasonality, i.e., Autumn-Winter (AW, October–March) and Spring-Summer (SS, April–September) days, shows a clear seasonal trend of correlation coefficients. In AW, OPDTTV is strongly correlated with nss-K+ and nss-Ca2+, in addition to Ba, Cd, Ce, Cr, Cu, Fe, and Mn (traffic-related metals) and with EC, OC, and POC associated with the traffic exhaust source and/or with the combustion including biomass-burning source. Otherwise, OPDTTV of SS samples is correlated only with NH4+, Cu, EC, OC, and POC.
The OPAAV of AW samples is well correlated with Ba, Ce, Cr, Cu, Fe, Mn, nss-K+, EC, OC, and POC, which are related with traffic and/or combustion emissions. Conversely, in SS, OPAAV is mainly correlated with NH4+, nss-K+, nss-Mg2+, nss-Ca2+, nss-SO42−, Cu, Mn, P, Pb, and oxalate, that are species related to secondary aerosols and resuspended soil from vehicular traffic and/or transported Saharan dust.
These findings point the importance of both organic components and transition metals to PM oxidative properties, and also suggest that synergistic/antagonistic interactions and cross-correlations between the PM redox-active components are likely responsible for the seasonal variation of the AA and DTT assay response. The inter-correlation among all analysed species has been investigated to explain contrasting results and the negative correlations between OP values and some chemical species.
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•Oxidative potential is assessed for PM10 collected at a Central Mediterranean Site.•Two cell-free assays yield similar OPDTT and OPAA responses.•Association of OPAAV and OPDTTV with PM chemical components varies with seasons.•Metals and primary organic carbon are the main responsible for PM-induced OP.
Cell-free methods assessed the oxidative potential of particulate matter collected at a Central Mediterranean Site and the results were correlated with PM10 chemical composition.
The ever-increasing energy demand motivates the pursuit of inexpensive, safe, scalable, and high-performance rechargeable batteries. Carbon materials have been intensively investigated as electrode ...materials for various batteries on account of their resource abundance, low cost, nontoxicity, and diverse electrochemistry. Taking use of the reversible donor-type cation intercalation/de-intercalation (including Li
+
, Na
+
, and K
+
) at low redox potentials, carbon materials can serve as ideal anodes for 'Rocking-Chair' alkali metal-ion batteries. Meanwhile, acceptor-type intercalation of anions into graphitic carbon materials has also been revealed to be a facile, reversible process at high redox potentials. Based on anion-intercalation graphitic carbon materials, a number of dual-ion battery and Al-ion battery technologies are experiencing booming development. In this review, we summarize the significant advances of carbon materials in terms of the porous structure, chemical composition, and interlayer spacing control. Fundamental mechanisms of carbon materials as the cation host and anion host are further revisited by elaborating the electrochemistry, intercalant effect, and intercalation form. Subsequently, the recent progress in the development of novel carbon nanostructures and carbon-derived energy storage devices is presented with particular emphasis on correlating the structures with electrochemical properties as well as assessing the device configuration, electrochemical reaction, and performance metric. Finally, perspectives on the remaining challenges are provided, which will accelerate the development of new carbon material concepts and carbon-derived battery technologies towards commercial implementation.
The development of carbon electrode materials for rechargeable batteries is reviewed from the perspective of structural features, electrochemistry, and devices.
PM2.5 and its major chemical compositions were sampled and analyzed in January, April, July and October of 2014 at Beijing (BJ), Tianjin (TJ), Langfang (LF) and Baoding (BD) in order to probe the ...temporal and spatial characteristics as well as source apportionment of PM2.5 in the Beijing-Tianjin-Hebei (BTH) region. The results showed that PM2.5 pollution was severe in the BTH region. The average annual concentrations of PM2.5 at four sampling sites were in the range of 126–180 μg/m3, with more than 95% of sampling days exceeding 35 μg/m3, the limit ceiling of average annual concentration of PM2.5 regulated in the Chinese National Ambient Air Quality Standards (GB3095-2012). Additionally, concentrations of PM2.5 and its major chemical species were seasonally dependent and demonstrated spatially similar variation characteristics in the BTH region. Concentration of toxic heavy metals, such as As, Cd, Cr, Cu, Mn, Ni, Pb, Sb, Se, and Zn, were higher in winter and autumn. Secondary inorganic ions (SO42−, NO3−, and NH4+) were the three-major water-soluble inorganic ions (WSIIs) of PM2.5 and their mass ratios to PM2.5 were higher in summer and autumn. The organic carbon (OC) and elemental carbon (EC) concentrations were lower in spring and summer than in autumn and winter. Five factors were selected in Positive Matrix Factorization (PMF) model analysis, and the results showed that PM2.5 pollution was dominated by vehicle emissions in Beijing, combustion emissions including coal burning and biomass combustion in Langfang and Baoding, and soil and construction dust emissions in Tianjin, respectively. The air mass that were derived from the south and southeast local areas around BTH regions reflected the features of short-distant and small-scale air transport. Shandong, Henan, and Hebei were identified the major potential sources-areas of secondary aerosol emissions to PM2.5.
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•We present the temp-spatial PM2.5 variations at four cities in BTH region of China.•PM2.5 concentrations and its species show spatially similar variation in BTH region.•PMF results indicate PM2.5 pollution is dominated by vehicle emissions in Beijing.•Coal combustion plays a significant contribution on PM2.5 in LangFang and Baoding.•Soil and construction dust constitute most important components of PM2.5 in TianJin.
PM2.5 mass and its major chemical composition in the BTH region were seasonally dependent and demonstrated spatially similar variation characteristics. PMF results indicated that PM2.5 was dominated by vehicle emissions in Beijing, coal and biomass combustion emissions in Langfang and Baoding, and soil and construction dust emissions in Tianjin, respectively.
Mixed plastics waste represents an abundant and largely untapped feedstock for the production of valuable products. The chemical diversity and complexity of these materials, however, present major ...barriers to realizing this opportunity. In this work, we show that metal-catalyzed autoxidation depolymerizes comingled polymers into a mixture of oxygenated small molecules that are advantaged substrates for biological conversion. We engineer a robust soil bacterium,
Pseudomonas putida
, to funnel these oxygenated compounds into a single exemplary chemical product, either β-ketoadipate or polyhydroxyalkanoates. This hybrid process establishes a strategy for the selective conversion of mixed plastics waste into useful chemical products.
Funneling mixed waste with microbes
Current plastic recycling methods require sorting by chemical composition, a method that is expensive and results in products that are of lower quality and value than the starting plastic. If plastic waste could instead be converted to valuable chemical intermediates, then economical use of mixed waste as a feedstock might be feasible. Sullivan
et al
. developed a two-stage oxidation and biological funneling approach that can break down and reform mixtures of common consumer plastics (see the Perspective by Yan). The end products can be adjusted by metabolic engineering of the microbes in the second step, which should enable tailored conversion into various platform or specialty chemicals. —MAF
Autoxidation and biological funneling converts mixed plastics to a single product.
Metabolic syndrome (MetS) has emerged as a significant global public health concern. While environmental factors, including PM2.5, have been identified as important risk factors for MetS in the ...general population, limited studies have investigated their impact on individuals with essential hypertension. Therefore, our study aims to explore the relationship between PM2.5 composition, green space, and their combined effects on MetS among a Chinese essential hypertensive population.
A total of 20,131 participants diagnosed with essential hypertension from 10 provinces in China were included in this study. Individual level exposure to various environmental factors (including PM2.5, PM2.5 composition, green space and temperature) were evaluated using spatiotemporal models based on satellites data. Participants were defined as MetS according to the definition issued by the International Diabetes Federation. Generalized additive mixed models were used to analyze the individual air pollutants, green space and their interaction on MetS.
The prevalence of MetS in this population was 44.33%. The adjusted odd ratio (OR) of MetS, with each one unit increase in SO42−, BC and NO3− were 1.077 (1.049, 1.106), 1.126 (1.077, 1.177) and 0.977 (0.958, 0.996) respectively. Additionally, each unit increase of the Normalized Difference Vegetation Index (NDVI) was associated with a decreased risk of MetS (OR: 0.988, 95% CI: 0.984–0.993). In particular, green space was found to mitigate the adverse impacts of PM2.5 on MetS (OR: 0.988, 95% CI: 0.984–0.993).
Our results suggested that there was a positive association between PM2.5 and its composition (SO42−, BC) with MetS in the essential hypertensive population, while green space might play a protective role. Moreover, green space could effectively weaken the positive relationship between air pollutants and MetS, especially in males and participants younger than 60 years old.
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•Essential hypertension patients are at high risk for MetS.•Exposure to most PM increases the risk of MetS.•Green space could reduce the impact of PM exposure on MetS.
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