Nowadays, hyperbranched polymers (HBP) are obtained by different polycondensation and polyaddition reactions 1. Almost interest is the reaction of 1,3-dipolar cycloaddition of azides to alkynes ...(1,3-DCA) 2, 3. There is a series of papers dedicated to the preparation of triazine-triazole HBPs 4, 5, 6. These polymers were obtained by the reaction of azido-acetylene AB2 monomers polyaddition: 2-azido-4,6-bis (propyne-2-yloxy) -1,3,5-triazine (ABPOT) and 2,4-diazido-6- (propine-2-yloxy) -1,3,5-triazine (DAPOT) (Fig. 1).