Spekter jedrske magnetne resonance skoraj linearnega sistema petih jeder s spinom 1/2 : magistrsko delo
Trontelj, Zvonko, 1937-2024
Vdelu je najprej podan pregled interakcij med magnetnimi dipoli. Sledi uporaba teh sodelovanj za izračun spektra magnetne resonance togege skoraj linearnega pet spinskega sistema tipa ▫$A-B-A-B-A$▫ s ...posameznim spinom ▫$\frac{1}{2}$▫. Pri tem upoštevamo interakcije med prvimi in drugimi najbližjimi sosedi. Obdelan je primer popolnoma linearne in nelinearne strukture petih jeder. Pokažemo, da dobimo različno strukturo spektra. Rezultate uporabimo za izračun spektra protonske in fluorove jedrske magnetne resonance ▫$H_2F_3^-$▫ iona v ▫$KH_2F_3$▫ in ▫$NaH_2F_3$▫. Oba spektra tudi pomerimo in ju primerjamo z izračunanimi spektri za ▫$^{1}H$▫ in ▫$^{19}F$▫. Ugotovimo, da v ▫$KH_2F_3$▫ vodikova atoma ne ležita v sredini vodikove vezi kot npr. pri ▫$KHF_2$▫, ampak sta pomaknjena iz središča vezi za približno 0,01nm proti zunanjima atomoma.
Type of material - master's thesis
Publication and manufacture - Ljubljana : [Z.Trontelj], 1968
FMF, Physical, Astronomical and Meteorological Library, Ljubljana
Skladišče-Jadranska 21 Magisteriji 9
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