Transformations of methyl L-(-)-thiazolidine-4-carboxylate, 2-amino-2-thiazoline and 2-aminothiazole into thiazoloazines and azolothiazoles
Malešič, Mateja ; Krbavčič, Aleš ; Stanovnik, Branko
In the search for potential immunomodulators methyl L-(-)-thiazolidine-4-carboxylate, (2), 2-amino-2-thiazoline (12), and 2-aminothiazole (19) were transformed into derivatives of various bicyclic ...systems. Thus, from compound 2 derivatives of perhydrothiazolo [4,3-c]-[1,4]oxazine 7, and perhydroimidazo[1,5-c]thiazole 9a,b, from compound12 derivatives of 2,3-dihydro-thiazolo[2,3-b]pyrimidine 13a,b, and from compound 19 derivatives of imidazo[2,1-b]thiazole 21,22,24, and 25 were prepared. 6-(p-sulfamoylphenyl)-7-oxoperhydroimidazo[1,5-c]thiazole-5-thione (9a) was found to exhibit immunorestoration activity.
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