E-resources
-
Negreiros, F. R; Obermüller, Th; Blatnik, M; Mohammadi, M; Fortunelli, A; Netzer, F. P; Surnev, S
Journal of physical chemistry. C, 11/2019, Volume: 123, Issue: 45Journal Article
Two-dimensional (2D) WO3 nanosheets exhibit a range of novel properties and functionalities that render them attractive for advanced nanotechnologies. However, at the ultimate 2D limit of single-layer thickness, the structural properties of WO3 are unclear. Here, we fabricated, using molecular beam epitaxy techniques, a crystalline 2D WO3 overlayer on a Ag(100) surface and unveiled its geometric, electronic, and vibrational structure via a combination of state-of-the-art experimental (microscopic and spectroscopic) and computational techniques. The 2D WO3 phase forms a bilayer with a staggered arrangement of WO6 octahedra, linked together by corner- and edge-sharing, which is significantly different from the cubic and monoclinic WO3 bulk structures, but resembles a bilayer of the α-MoO3 layered bulk lattice. Such a 2D WO3 bilayer on Ag(100) is a robust nonpolar structure, which is incommensurate in various rotational orientations, weakly coupled to the metal substrate, and, according to the density functional theory calculations, should survive as a stable freestanding layer, that is, as a nanosheet.
Author
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.