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Lu, Shichao; Gong, Yaling; Zhou, Demin
Journal of organic chemistry, 09/2015, Volume: 80, Issue: 18Journal Article
A radical cascade decarboxylation/cyclization of 2-isocyanobiphenyls with aliphatic carboxylic acids as well as aromatic carboxylic acids under the transition metal-free conditions was reported. This process, which included formation of two new C–C bonds and cleavage of C–COOH bonds, afforded a novel and environmentally friendly approach to producing 6-alkyl/aryl phenanthridines with moderate to good yields.
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