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Pribylov, A. A.; Murdmaa, K. O.; Solovtsova, O. V.; Knyazeva, M. K.
Russian chemical bulletin, 10/2018, Volume: 67, Issue: 10Journal Article
Adsorption of methane on three samples of metal-organic framework structures (MOF), which contain copper, aluminum or zinc atoms, was measured at temperatures ranging from 303 to 333 K and pressures up to 40 MPa using a precise volumetric-gravimetric unit. The determined values of adsorption volumes and characteristic energies served to evaluate the average heats of adsorption, which were compared to the average isosteric heats of adsorption.
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