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Fantoni, R; Maestre, M A G; Santos, A
arXiv.org, 10/2021Paper, Journal Article
The equilibrium properties of a Janus fluid made of two-face particles confined to a one-dimensional channel are revisited. The exact Gibbs free energy for a finite number of particles \(N\) is exactly derived for both quenched and annealed realizations. It is proved that the results for both classes of systems tend in the thermodynamic limit (\(N\to\infty\)) to a common expression recently derived (Maestre M A G and Santos A 2020 J Stat Mech 063217). The theoretical finite-size results are particularized to the Kern--Frenkel model and confirmed by Monte Carlo simulations for quenched and (both biased and unbiased) annealed systems.
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