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Zhang, Xiao-Wen; Huang, Chun-Hua; Yang, Mingxue; Chen, Xu-Lin; Lu, Can-Zhong
Dalton transactions : an international journal of inorganic chemistry, 07/2023, Volume: 52, Issue: 29Journal Article
A novel binuclear Cu( i ) halide complex, Cu 2 I 2 (DPPCz) 2 , which emits efficient thermally activated delayed fluorescence (TADF), is reported. The crystal of this complex spontaneously undergoes ligand rotation and coordination-configuration transformation, converting to its isomer without any external stimulation. A new binuclear Cu( i ) halide complex, Cu 2 I 2 (DPPCz) 2 , demonstrates spontaneous ligand rotation and coordination configuration transformation, resulting in its conversion to an isomer, without the need for any external stimulation.
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