Co-substitution in a Prussian blue analog with a hollow heterostructure for ultrahigh capacity and rate capability aqueous Zn2+ batteries

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Co-substitution in a Prussian blue analog with a hollow heterostructure for ultrahigh capacity and rate capability aqueous Zn2+ batteries

Su, Zhihao; Huang, Jionghao; Wang, Runhao; Zhang, Yufei; Liu, Zili; Fan, Haosen

Chemical communications (Cambridge, England), 07/2022, Volume: 58, Issue: 58

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Nickel and manganese co-substitution into hollow Prussian blue nanocubes (H-PBMN) has been successfully carried out via utilizing a high-concentration polymer template to grow manganese-Prussian blue (PBM) and nickel-Prussian blue (PBN) through a slow nucleation process. Due to the hollow structure and double metal co-substitution, the properties of the electrode material have been optimized, and it presents an ultrahigh capacity of 138.4 mA h g−1 at 0.05 A g−1.

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