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Wei, Yong-Sheng; Hu, Xiao-Peng; Han, Zhen; Dong, Xi-Yan; Zang, Shuang-Quan; Mak, Thomas C. W
Journal of the American Chemical Society, 03/2017, Volume: 139, Issue: 9Journal Article
Recently, research on metal–organic frameworks (MOFs) serving as a new type of proton conductive material has resulted in many exciting achievements. However, direct observation of a well-established proton-transfer mechanism still remains challenging in MOFs and other crystalline compounds, let alone other conductive materials. Herein we report the solvothermal synthesis of a new proton-conducting MOF, (Me2NH2)Eu(L) (H4L = 5-(phosphonomethyl)isophthalic acid). The compound consists of a layered anionic framework Eu(L)− and interlayer-embedded counter cations (Me2NH2)+, which interact with adjacent uncoordinated O atoms of phosphonate groups to form strongly (N–H···O) hydrogen-bonded chains aligned parallel to the c-axis. Facile proton transfer along these chains endows the compound with single-crystal anhydrous conductivity of 1.25 × 10–3 S·cm–1 at 150 °C, and water-assisted proton conductivity for a compacted pellet of microcrystalline crystals attains 3.76 × 10–3 S·cm–1 at 100 °C and 98% relative humidity (RH). Proton dynamics (vibrating and transfer) within N–H···O chains of the compound are directly observed using a combination of anisotropic conductivity measurements and control experiments using large single-crystals and pelletized samples, in situ variable-temperature characterization techniques including powder X-ray diffraction (PXRD), single-crystal X-ray diffraction (SCXRD), diffuse reflectance infrared Fourier transform spectrum (DRIFTS), and variable-temperature photoluminescence. In particular, a scarce single-crystal to single-crystal (SCSC) transformation accompanied by proton transfer between an anionic structure (Me2NH 2)Eu(L) and an identical neutral framework Eu(HL) has been identified.
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