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Sokolov, Maxim N; Adonin, Sergey A; Sinkevich, Pavel L; Vicent, Cristian; Mainichev, Dmitry A; Fedin, Vladimir P
Dalton transactions : an international journal of inorganic chemistry, 09/2012, Volume: 41, Issue: 33Journal Article
ESI-MS based methodology for the rapid reactivity screening of PW(11)O(39)RhCl(5-) and PW(11)O(39)Ir(H(2)O)(4-) toward various metalation-intended substrates (reagents with an activated C-H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh-R (R = malonate, phenylacetate, CH(3), Ph, ferrocenyl) and Ir-R (R = CH(3)) bonds is reported.
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