DIKUL - logo
E-resources
Full text
Peer reviewed Open access
  • Front Cover Picture: Rhodiu...
    Kliemann, Max N.; Teeuwen, Simon; Weike, Christopher; Franciò, Giancarlo; Leitner, Walter

    Advanced synthesis & catalysis, December 8, 2022, 2022-12-08, Volume: 364, Issue: 23
    Journal Article

    The front cover picture illustrates the variety of products accessible through the newly developed asymmetric hydrohydrazonemethylation (HHM). The devised hydroformylation/condensation sequence leads to stable and versatile γ‐chiral N’‐substituted aceto‐hydrazones. They can be reduced in one‐pot to the corresponding γ‐chiral N’‐substituted acetohydrazides, and after deprotection, to β‐chiral hydrazines. They can be also reduced and hydrogenolysed to the β‐chiral primary amines or serve as substrates for diastereoselective C−C coupling. The high enantioselectivity reached for all product types makes the molecular peacock proud of its pluridecorated tail. Details can be found in the communication by Franciò and co‐workers (M. N. Kliemann, S. Teeuwen, C. Weike, G. Franciò, W. Leitner, Adv. Synth. Catal. 2022, 364, 4006–4012; DOI: 10.1002/adsc.202200804).