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  • Enhanced electrocaloric str...
    Lu, Sheng-Guo; Lin, Xiongwei; Li, Jiang; Li, Dandan; Yao, Yingbang; Tao, Tao; Liang, Bo

    Journal of alloys and compounds, 08/2021, Volume: 871
    Journal Article

    •Electrocaloric effects in (SrBa)(SnTi)O3 ceramics were investigated using direct and indirect approaches.•The largest electrocaloric strength obtained is 0.52 × 10−6 K m/V at T = 56 °C and E = 2 MV/m.•An analytic formula of electrocaloric strength (dT/dE) was firstly deduced via a thermodynamic theory.•The electrocaloric strength mainly depends on the large permittivity peak, phenomenological coefficient and polarization. The electrocaloric effect (ECE) in lead-free (Ba1−xSrx)(Sn0.05Ti0.95)O3 (BSSnT) (x = 0.05, 0.10, 0.15, 0.20) ceramics were investigated around room temperature using direct and indirect approaches. Results indicate that the maximum ECE occurs near the Curie temperature and slightly shifts towards high temperatures with the increasing applied electric field. The directly measured ECE is larger than that calculated using the Maxwell relation. The maximum electrocaloric strength ΔT/ΔE = 0.52 × 10−6 K m/V was obtained at T = 36 °C, with an adiabatic ΔT of 1.05 °C at 2 MV m−1. An analytic formula of electrocaloric strength (dT/dE) was deduced, via which the maximum dT/dE was estimated. The factors affecting the electrocaloric strength were discussed, and the experimental results were compared with those derived from the formula.