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Zhang, Yunqin; Wang, Leilei; Zhou, Qingli; Li, Zuoshan; Li, Dan; Yin, Caixia; Wang, Xiufang; Xiao, Guozhi
Angewandte Chemie, May 22, 2023, 2023-05-22, Volume: 62, Issue: 22Journal Article
Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the treatment of inflammatory bowel diseases. In their Research Article (e202301351), Guozhi Xiao and co‐workers accomplished the first synthesis of a tridecasaccharide motif from Bacteroides vulgatus lipopolysaccharides by a strategy involving orthogonal one‐pot glycosylation reactions based on glycosyl ortho‐(1‐phenylvinyl)benzoates, which avoided issues such as aglycone transfer and the unpleasant odor of thioglycoside‐based orthogonal one‐pot glycosylation.
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