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Wang, Jian; Fan, Shiguang; Xu, Xuan; Yun, Huiru; Liu, He; Wang, Zongxian
E3S web of conferences, 01/2020, Volume: 194Journal Article
Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h -1 at 180 ℃ for 150 minutes.
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