Delta y-Octamolybdate [MoV4MoVI4O24]4-: An Unusual Small Polyoxometalate in Partially Reduced Form from Nonaqueous Solvent Reduction

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Delta y-Octamolybdate [MoV4MoVI4O24]4-: An Unusual Small Polyoxometalate in Partially Reduced Form from Nonaqueous Solvent Reduction

Wang, Longsheng; Yin, Panchao; Zhang, Jin; Hao, Jian; Lv, Chunlin; Xiao, Fengping; Wei, Yongge

Chemistry : a European journal, 04/2011, Volume: 17, Issue: 17

Journal Article

The first mixed-valent octamolybdate anion MoV4MoVI4O244-, termed Delta *y-octamolybdate due to its shape, was obtained by partial reduction of -(Bu4N)4Mo8O26 in dry acetonitrile. Single-crystal X-ray structure analysis revealed that the anion includes an unusual MoV4O8 cubane-like cluster core, whose four side faces are capped by four MoO4 units to form a crosslike cluster. X-ray photoelectron spectroscopy (XPS) and bond valence sum (BVS) calculations were carried out to validate the presence of mixed-valent Mo centers.

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