Chapatti
is a flattened circular flatbread also known as
roti, poli, safari,
and
phulka,
usually baked on a hot iron griddle. It is a staple diet of India and hence the quality of
chapatti
plays a ...major role in its acceptance. The overall quality of
chapatti
is dependent on various attributes such as pliability, handfeel,
chapatti
eating quality, and taste. These attributes are influenced by numerous factors, including wheat genotypes, wheat varieties, the molecular weight distribution of proteins, and processing techniques
.
This staple food has been extensively studied for various aspects, including processing, mechanism, fractionation, and reconstitution, quality improver, shelf life extension and also the mechanization of processing. This review focus on all the above-mentioned aspects and innovations carried out in this area.
Display omitted
•PUAE an emerging and non-destructive, cost and energy effective extraction method.•Power and duty cycle had most significant effects for influencing PUAE efficacy.•The optimum ...conditions were 2.17 S/S ratio at 116 W power; 80% duty cycle for 6 min.•Significant correlation among responses were established during PUAE.•At optimal conditions, the extract showed remarkable antioxidant activity.
Pomegranate peel (PP) is one of the interesting agri-food by-products because of its abundant bioactive phytochemicals. However, the bioactivity of valuable compounds is affected due to the extraction method used. A pulsed ultrasound-assisted extraction (PUAE) was carried out to intensify the extraction efficacy with reduced power and time. Influence of several process variables viz. peel solids/ solvent ratio, sonication power, duty cycle, and extraction time was studied using empirical quadratic models followed by multicriterial numerical optimization with respect to face-centered composite design. Power-duty cycle combination was found to be most significant (p < 0.05) for process intensification. The optimal process conditions of 2.17 g/100 mL S/S ratio at 116 W power with 80% duty cycle for 6 min resulted into 0.48 g/g yield, 177.54 mg GAE/g total phenolics content, 35.71 mg QE/g total flavonoids, 160.54 mg GAE/g antioxidant capacity, 21.65 mg cyn-3-glc/100 g anthocyanin content with 54.92 browning index in dry pomegranate peel. Significant Pearson correlation analysis was established in all responses with potent phenols and flavonoid relation with highest coefficient (r) 0.931. All response models were significantly validated with regression coefficient (R2) above 0.965. Remarkable antioxidant bioactivities were recorded for the resultant peel extract. Hence, it is strongly recommended that PUAE could be successfully applied for the intensification of the extraction process of bioactive from any peel and or plant systems with minimal process time and power consumption with a green label.
Urban Modification of Thunderstorms Niyogi, Dev; Pyle, Patrick; Lei, Ming ...
Journal of applied meteorology and climatology,
05/2011, Letnik:
50, Številka:
5
Journal Article
Recenzirano
Odprti dostop
A radar-based climatology of 91 unique summertime (May 2000–August 2009) thunderstorm cases was examined over the Indianapolis, Indiana, urban area. The study hypothesis is that urban regions alter ...the intensity and composition/structure of approaching thunderstorms because of land surface heterogeneity. Storm characteristics were studied over the Indianapolis region and four peripheral rural counties approximately 120 km away from the urban center. Using radar imagery, the time of event, changes in storm structure (splitting, initiation, intensification, and dissipation), synoptic setting, orientation, and motion were studied. It was found thatmore than 60% of storms changed structure over the Indianapolis area as compared with only 25% over the rural regions. Furthermore, daytime convection was most likely to be affected, with 71% of storms changing structure as compared with only 42% at night. Analysis of radar imagery indicated that storms split closer to the upwind urban region and merge again downwind. Thus, a larger portion of small storms (50–200 km²) and large storms (>1500 km²) were found downwind of the urban region, whereas midsized storms (200–1500 km) dominated the upwind region. A case study of a typical storm on 13 June 2005 was examined using available observations and the fifth-generation Pennsylvania State University–NCAR Mesoscale Model (MM5), version 3.7.2. Two simulations were performed with and without the urban land use/Indianapolis region in the fourth domain (1.33-km resolution). The storm of interest could not be simulated without the urban area. Results indicate that removing the Indianapolis urban region caused distinct differences in the regional convergence and convection as well as in simulated base reflectivity, surface energy balance (through sensible heat flux, latent heat flux, and virtual potential temperature changes), and boundary layer structure. Study results indicate that the urban area has a strong climatological influence on regional thunderstorms.
Nowadays, GIS and remote sensing techniques are effectively used to find groundwater prospect zones in various troublesome landscapes throughout the world. In the present work, groundwater potential ...zonation mapping was carried out for the Vattamalaikarai River basin in South India by overlaying ten thematic maps such as soil, drainage density, lineament density, geology, slope, land use/land cover, geomorphology, topographic position index, rainfall and groundwater level by giving appropriate weightages to each significant parameter with respect to its influence on groundwater. As the basin mainly depends on the groundwater resources, it is necessary to assess the groundwater prospect for the better management of aquifer system. Groundwater potential zonation map illustrates that more than 50% of the basin region falls under moderate to low groundwater potential category. Highly influential thematic layers were integrated to generate groundwater recharge zonation map. Based on this output, artificial recharge sites were selected to replenish the groundwater resources in the basin. Three check dam sites were suggested across the third- and fourth-order streams. Four suitable sites for the construction of percolation ponds and ten locations for the construction of recharge pits were also identified. Four injection well sites were recommended to augment groundwater in the aquifer present under the black cotton soil regions in the western part of the basin.
Since the inception of cobalt phthalocyanine for oxygen reduction reaction (ORR), non-platinum group metals have been the central focus in the area of fuel-cell electrocatalysts. Besides Fe–N x ...active sites, a large variety of species are formed during the pyrolysis, but studies related to their ORR activity have been given less importance in the literature. Fe2O3 is one among them, and this study describes the role of Fe2O3 in the ORR. The Fe2O3 is carefully synthesized on various carbon supports and characterized using X-ray photoelectron spectroscopy (XPS) spectra, high-resolution transmission electron microscopy (HRTEM) images, and surface area analysis. The characterization techniques reveal that the Fe2O3 nanoparticles are present in the pores of the carbon supports, having a particle size ranging from 4 to 15 nm. The current density of the ORR on Fe2O3/C catalysts is increased compared with bare carbon supports, as discerned from the rotating ring-disk electrode (RRDE) voltammetry experiments, demonstrating the role of size-confined Fe2O3 nanoparticles. The overall number of electrons in the ORR is increased by the introduction of Fe2O3 on the carbon support. Based on the kinetic analysis, the ORR on Fe2O3/C follows a pseudo-4-electron or 2+2-electron ORR, where the first 2-electron ORR to H2O2 and second 2-electron H2O2 reduction reaction (HPRR) to H2O are assigned to the graphitic carbon (carbon defects) and Fe2O3 active sites, respectively. Theoretical studies indicate that the role of Fe2O3 is to decrease the free energy of O2 adsorption and reduce the energy barrier for the reduction of *OOH to OH–. The onset potential estimated from the free energy diagram is 0.42 V, matching with the HPRR activity demonstrated using the potential-dependent rate constants plot. Fe2O3/C shows higher stability by retaining 95% of the initial activity even after 20 000 cycles.
In the present study, the effect of variable vanadium oxidation states on the structural, optical, and dielectric properties of vanadium oxide containing lithium borate glasses has been investigated. ...Electron paramagnetic resonance studies indicate that vanadium in these glasses is mostly in the V4+ state, having a tetragonal symmetry. As the glass composition of V2O5 increases, tetragonality also increases at the cost of octahedral symmetry. The photoluminescence (PL) spectra of these glasses are dominated by zinc oxide transition, whereas the peaks pertaining to the vanadyl group are not visible in the PL spectra. The optical absorption spectra show a single wide absorption band, which is attributed to V4+ ions in these glasses. The ac conductivity of the glasses increases with an increase in vanadium content. The highest electrical conductivity observed is ∼10–5 S cm–1 at 250 °C for the glass with 2.5 mol % V2O5. Electrical conductivity is dominated by electron conduction, as indicated by the activation energy calculation.
Vascular endothelial growth factor-A (VEGF-A) is essential for endothelial cell functions associated with angiogenesis. Signal transduction networks initiated by VEGFA/VEGFR2, the most prominent ...ligand-receptor complex in the VEGF system, leads to endothelial cell proliferation, migration, survival and new vessel formation involved in angiogenesis. Considering its biomedical importance, we have developed the first comprehensive map of endothelial cell-specific signaling events of VEGFA/VEGFR2 system pertaining to angiogenesis. Screening over 20,000 published research articles and following the post-translational modification (PTM) and site specificity of VEGFR2, we have documented 240 proteins and their diverse PTM-dependent reactions involved in VEGFA/VEGFR2 signal transduction. From the ligand-receptor complex, this map has been extended to the level of major transcriptionally regulated genes for which the signaling cascades leading to their transcription factors are reported. We believe that this map would serve as a novel platform for reference, integration, and representation and more significantly, the progressive analysis of dynamic features of VEGF signaling in endothelial cells including their cross-talks with other ligand-receptor systems involved in angiogenesis.
In this article, the transition metals effect on different properties of lithium borate glasses is reviewed. These glasses are useful for medical and energy storage, nonlinear optics and conversion ...devices. In the first part of this article, the basic properties of glasses are summarized, followed by variations in different lithium borate glass composition having various transition metal oxide and their effects on the characteristics of glass formed. In the last part, the conclusion and future perspectives are given and discussed the role of lithium oxide in glass compositions. The presence of higher valence levels of transition metals in glass decreases the overall conductivity of the glasses because of localized effects because of their higher charges and masses. On the other hand, mechanical properties are improved with transition metal oxides in the glass composition. Lower levels of lithium oxide in borate glass cause structural units to change from triangular to tetrahedral units without producing non-bridging oxygens in the glasses that enhance thermal and mechanical stability of the glasses. It could be related to the glass network connectivity and localized higher interaction among different charge carriers.
The motive of this work is to synthesis aromatic polyimides by a two-step poly condensation process and the prepared aromatic polyamides (APIs) is been used as an effective functionalized adsorbent ...for the removal of carcinogenic crystal violet (CV) from aqueous medium. The adsorption efficiency of the APIs was enhanced by incorporation different functional moieties (varying aromatic dianhydrides with -O-, –(CF3)2–, –(CH3)2–) in the polymer structure. The initial and final concentration of CV was measured using UV–Vis spectrometer. The adsorption process was optimized by varying the parameters such as the effect of solution pH, contact time, initial dye concentration, and adsorbent dosage. Kinetics and isotherms of the adsorption system were appraised using data obtained from effect of contact time and initial dye concentration with corresponding empirical modelling techniques respectively. The evaluated results of the adsorption kinetic studies confirmed that the adsorption of API onto CV is followed a pseudo-second-order kinetic model. The adsorption behaviour and their interactions between APIs and CV are well established. The experimental results of this research output could be confirmed that APIs is a very effective adsorbent for the removal of cationic dye from aqueous.
Display omitted
•Aromatic polyimides are an effective adsorbent which is been produced by two-step polycondenzation technique.•APIs are employed to adsorb of CV dye from polluted water sources.•The CV adsorption onto APIs follows pseudo-Second-order kinetics, which is justified by kinetic data.•This research revealed that the highest adsorption capacity of APIs-1-CV is 287.71 mg/g and that of APIs-2-CV is 303.03 mg/g.•APIs proved to be a superior adsorbent for cationic dye removal.
Preliminary investigation reveals that fluorosis is reported due to the continuous intake of fluoride-rich groundwater in Vattamalikarai River basin, Tamil Nadu, India. A detailed study was attempted ...for evaluating the health risks associated with the intake of fluoride-rich groundwater supplied to the rural community. Groundwater samples were collected from 60 and 58 dug and tube wells during winter and southwest (SW) monsoon seasons respectively. The samples were analyzed for the determination of fluoride and other chemical parameters to examine the fitness for drinking water. Spatio-temporal variation maps reveal that fluoride concentration is high during SW monsoon season when compared with the winter season in this region. The fluoride bearing minerals present in hornblende-biotite gneiss and charnockite rock formations leached into the groundwater during rock–water interaction. To understand the subsurface hydrogeochemical reactions, inverse mass balance model was developed using NETPATH code. The model output indicates that calcite dilution, silicate (hornblende and biotite) weathering, ion exchange (Ca/Na and Mg/Na) and illite precipitation are the dominant processes controlling the groundwater chemistry along the flow paths. Non-carcinogenic risks to children and adults (women and men) were evaluated by working out intake exposure of groundwater. Hazard quotient (HQ) based on fluoride intake was calculated for children and adults. It varied from 0.08 to 2.21 with an average of 1.07 for adults. For children, it varied from 0.01 to 2.99 with the mean of 1.44. About 78%, 69% and 61% of the samples fall under the risk category for children, women and men during winter season. However, more number of samples possessed health risks (83% of samples for children, 73% of samples for women and 64% of samples for men) during SW monsoon season.
PDF
