Recent advances in three-dimensional (3D) printing technology has enabled to shape food in unique and complex 3D shapes. To showcase the capability of 3D food printing, chocolates have been commonly ...used as printing inks, and 3D printing based on hot-melt extrusion have been demonstrated to model 3D chocolate products. Although hot-melt extrusion of chocolates is simple, the printing requires precise control over the operating temperature in a narrow range. In this work, for the first time, we directly printed chocolate-based inks in its liquid phase using direct ink writing (DIW) 3D printer to model complex 3D shapes without temperature control. We termed this method as chocolate-based ink 3D printing (Ci3DP). The printing inks were prepared by mixing readily available chocolate syrup and paste with cocoa powders at 5 to 25 w/w% to achieve desired rheological properties. High concentrations of cocoa powders in the chocolate-based inks exhibited shear-thinning properties with viscosities ranging from 10
to 10
Pa.s; the inks also possessed finite yield stresses at rest. Rheology of the inks was analyzed by quantifying the degree of shear-thinning by fitting the experimental data of shear stress as a function of shear rate to Herschel-Bulkley model. We demonstrated fabrication of 3D models consisting of chocolate syrups and pastes mixed with the concentration of cocoa powders at 10 to 25 w/w%. The same method was extended to fabricate chocolate-based models consisting of multiple type of chocolate-based inks (e.g. semi-solid enclosure and liquid filling). The simplicity and flexibility of Ci3DP offer great potentials in fabricating complex chocolate-based products without temperature control.
Three-dimensional food printing (3DFP) leads to advances in digital gastronomy by targeting consumers’ specific requirements for nutrition customization and visual appeal. Dysphagia, or difficulty ...swallowing, is prevalent in elderly people and patients suffering from debilitating illnesses. Dysphagic diets require textural modifications to render them soft and safe to swallow. Diets must be visually pleasing to enable a greater food uptake to prevent malnutrition in patients. 3DFP so far has mainly utilized freeze-dried vegetable powders for shaping 3D designs. Our work focuses on fresh and frozen vegetables having better nutritional profile and low costs. Three different categories of vegetables are identified based on the number of hydrocolloids required to render them printable. Garden pea, carrot and bok choy are chosen as representatives in each category, which requires no HC, one type of HC and two types of HCs, respectively. Food inks are prepared by the addition of HCs i.e. xanthan gum (XG), kappa carrageenan (KC) and locust bean gum (LBG) for texture modification. Rheological, textural, microstructural and syneresis properties of the inks are examined. International dysphagia diet standardisation initiative (IDDSI) tests are done to assess the potential of the inks for dysphagic diets. Optimized ink formulations display excellent 3D printability, minimal water seepage, and dense microstructures with minimal amount of HCs. Using fresh vegetables instead of freeze-dried foods serves the purpose of preserving flavour and nutrition like real food. This in turn may bring 3DFP closer to the hospital and nursing home kitchens.
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•Three-dimensional food printing of fresh vegetables for dysphagic patients.•Three vegetable categories defined according to the number of hydrocolloids required to prepare food inks.•Extensive characterization of food ink properties and its suitability for dysphagic patients.•3D-Printable food inks with no more than 2% hydrocolloids.•A method of quantifying syneresis in food inks.
Emulsification using electric fields is an easy alternative to flow-induced drop breakup, and the former is reported to be more effective and economical than the latter, especially when the medium ...phase is poorly conducting and highly viscous. The emulsification of a coarse water-in-oil emulsion in a uniform electric field is studied. We perform a detailed experimental analysis of the effect of applied electric field strength and the duration of applied electric field on the drop size distribution. The average diameter as well as the time for emulsification decreases with an increase in the intensity of the electric field. Moreover, a narrow size distribution is observed. An average size of a few microns of the dispersed phase could be achieved. New breakup mechanisms at play in the emulsification process are discussed. Identified mechanisms involve charged lobe disintegration, charged drop breakup, chain formation in which several water droplets are interconnected by thin water bridges, electrospraying and charge transfer, and coalescence. The study shows that charged drop disintegration could be the key mechanism of fine emulsification of an initially electrically neutral coarse emulsion.
We present an extracellular matrix (ECM)-based gradient generator that provides a culture surface with continuous chemical concentration gradients created by interstitial flow. The gelatin-based ...microchannels harboring gradient generators and in-channel micromixers were rapidly fabricated by sacrificial molding of a 3D-printed water-soluble sacrificial mold. When fluorescent dye solutions were introduced into the channel, the micromixers enhanced mixing of two solutions joined at the junction. Moreover, the concentration gradients generated in the channel diffused to the culture surface of the device through the interstitial space facilitated by the porous nature of the ECM. To check the functionality of the gradient generator for investigating cellular responses to chemical factors, we demonstrated that human umbilical vein endothelial cells cultured on the surface shrunk in response to the concentration gradient of histamine generated by interstitial flow from the microchannel. We believe that our device could be useful for the basic biological study of the cellular response to chemical stimuli and for the in vitro platform in drug testing.
A new method for studying the effect of pH on the polysiloxane network formation using electric fields is presented. The kinetic data obtained using these experiments indicates that the two-step ...interfacial polycondensation of silanes is strongly dependent on the pH, and the mechanism is essentially different at low and neutral to high values of pH. Very rapid hydrolysis followed by moderate rates of condensation are observed at neutral and high pH. The rate of hydrolysis is drastically reduced, while that of condensation is slightly lowered at low pH as compared to that at high values of pH. The slow hydrolysis reaction at low pH is then exploited to synthesize nonspherical microcapsules. Nonspherical polysiloxane microcapsules with varying aspect ratios from 1.05to 1.97 are synthesized by controlling the applied electric field.
Abstract
Surface wetting is a multiscale phenomenon where properties at the macroscale are determined by features at much smaller length scales, such as nanoscale surface topographies. Traditionally, ...the wetting of surfaces is quantified by the macroscopic contact angle that a liquid droplet makes, but this approach suffers from various limitations. In recent years, several techniques have been developed to address these shortcomings, ranging from direct measurements of pinning forces using cantilever-based force probes to atomic force microscopy methods. In this review, we will discuss how these new techniques allow for the probing of surface wetting properties in far greater detail. Advances in surface characterization techniques will improve our understanding of surface wetting and facilitate the design of functional surfaces and materials, including for antifogging and antifouling applications.
Abstract
Scanning of a high-power laser beam on the surface of martensitic stainless steel (SS420) has been studied, addressing the effect of scanning rate V on integrity modifications in the ...near-surface regions. Structural, compositional, and crystallographic characterizations revealed the presence of ablations, surface melting/resolidification, surface oxidations, and austenite (
γ
-phase) precipitations when V ≤ 20 mm s
−1
. Melt pool (MP), heat affected zone (HAZ), and base material have been clearly distinguished at the cross-section of the slow-scanned samples. Adjacent MPs partially overlapped when V = 5 mm s
−1
. The
γ
-phase precipitations solely occurred in the MPs, i.e., of ∼ 400
μ
m deep for V = 5 mm s
−1
, while oxidations dominantly occurred in the surface regions of shallower than ∼30
μ
m within the MPs. Compositional analysis revealed increased Cr-, Mn-, and Si-to-Fe ratios at the laser-scanned surface but without variations along the surface normal direction. The enhanced surface hardness has been achieved up to 805 HV, and the hardness monotonically decreased when moving deeper (i.e., ∼1000
μ
m) into the base material. These observations shed new light on surface engineering of metallic alloys via laser-based direct energy treatments.
Polysiloxane is a desirable material for the fabrication of devices in microfluidics, lab-on-a-chip, and microelectromechanical systems, but direct patterning of microstructures using liquid ...polysiloxane resins would require adequate rheological and chemical properties of the resins. In this work, we developed a simple method to fabricate planar microstructures consisting of polysiloxane using commercially available liquid polysiloxane resins without changing their properties. We used a direct ink writing (DIW) printer to dispense curable liquid polysiloxane (with the viscosity in the range of 1–100 Pa·s) in a liquid immiscible with the resins (such as methanol, ethanol, and isopropanol). The contact angle (θ) of the dispensed polysiloxane on the Petri dish increased from 20° in air to 100° in methanol, ethanol, and isopropanol. The increase in the contact angles allowed maintaining the structures of patterned polysiloxane until curing, and the embedding liquid was readily removed by evaporation. We termed this method as embedded ink writing (EIW). The effects of curing time (τ) and nozzle speed (v) on the width of the printed filament (w) were evaluated. EIW achieved the minimum width of the printed filament of 65 μm. EIW enabled direct writing of polysiloxane resins and should find applications in fabricating microfluidic devices, flexible wearables, and soft actuators.
Flexible core–shell 3D structures are essential for the development of soft sensors and actuators. Despite recent advancements in 3D printing, the fabrication of flexible 3D objects with internal ...architectures (such as channels and void spaces) remains challenging with liquid precursors due to the difficulty to maintain the printed structures. The difficulty of such fabrication is prominent especially when low-viscosity polysiloxane resins are used. This study presents a unique approach to applying direct ink writing (DIW) 3D printing in a three-phase system to overcome this limitation. We performed core–shell 3D printing using a low-viscosity commercial polysiloxane resin (Ecoflex 10) as shell inks combined with a coaxially extruded core liquid (Pluronic F127) in Bingham plastic microparticulate gels (ethanol gel). In the process termed embedded core–shell 3D printing (eCS3DP), we highlighted the dependence of the rheological characteristics of the three fluids on the stability of the printed core–shell filament. With the core liquid with a sufficiently high concentration of Pluronic F127 (30 w/w%; σy = 158.5 Pa), the interfacial instability between the shell liquid and core liquid was suppressed; the removal of the core liquid permitted the fabrication of perfusable channels. We identified the printing conditions to ensure lateral attachments of printed core–shell filaments. Interestingly, judicious selection of the rheological properties and flow rates of three phases allowed the formation of droplets consisting of core liquids distributed along the printed filaments. eCS3DP offers a simple route to fabricate 3D structures of a soft elastomeric matrix with embedded channels and should serve as a useful tool for DIW-based fabrication of flexible wearable devices and soft robotic components.