ALMA observations of the long wavelength dust continuum are used to estimate the interstellar medium (ISM) masses in a sample of 708 galaxies at z = 0.3 to 4.5 in the COSMOS field. The galaxy sample ...has known far-infrared luminosities and, hence, star formation rates (SFRs) and stellar masses ( ) from the optical-infrared spectrum fitting. The galaxies sample SFRs from the main sequence (MS) to 50 times above the MS. The derived ISM masses are used to determine the dependence of gas mass on redshift, , and specific SFR (sSFR) relative to the MS. The ISM masses increase approximately with the 0.63 power of the rate of increase in SFRs with redshift and the 0.32 power of the sSFR/sSFRMS. The SF efficiencies also increase as the 0.36 power of the SFR redshift evolution and the 0.7 power of the elevation above the MS; thus the increased activities at early epochs are driven by both increased ISM masses and SF efficiency. Using the derived ISM mass function, we estimate the accretion rates of gas required to maintain continuity of the MS evolution ( yr−1 at z > 2.5). Simple power-law dependencies are similarly derived for the gas accretion rates. We argue that the overall evolution of galaxies is driven by the rates of gas accretion. The cosmic evolution of total ISM mass is estimated and linked to the evolution of SF and active galactic nucleus activity at early epochs.
This paper presents a new perspective on modeling of CO2 and miscible gas injection into shale oil plays for potential enhanced oil recovery (EOR) and CO2 storage. Our major points are the conceptual ...understandings of the dominant trapping and the oil recovery mechanisms behind miscible gas injection. This paper investigates the efficiency of miscible gas (solvent) injection into shale oil reservoirs with a wide range of permeability (from 1 to 100 µD). We set up a large-scale numerical model to simulate and capture the important mechanisms behind various miscible gas injection and geological storage scenarios. This numerical study demonstrates that injecting miscible gas such as CO2 and recycled gas rich in ethane substantially increases oil recovery in shale oil reservoirs. Numerical simulation models reveal that miscibility and CO2 adsorption, along with gas diffusion, are important physical mechanisms. However, recycled-enriched gas injection demonstrated a larger oil recovery rate compared to miscible CO2 injection. On the other hand, CO2 trapping is considerable, because of adsorption and other traditional trapping mechanisms in shale plays. The amount of CO2 trapped in unconventional reservoirs can be a significant fraction of the total injected amount (∼25 to50% including the important and dominant trapping mechanisms, e.g. CO2 dissolution in oil and water, adsorption, residual, and mobile gas saturations). Results show that molecular diffusion can speed CO2 flux delivery to larger matrix area and thus contribute to oil recovery, and become trapped and adsorbed on minerals or organic contents.
The fascinating biological activity of gold coordination compounds has led to the development of a wide range of complexes. The precise biological action of such species is often poorly understood ...and the ability to map gold distribution in cellular environments is key. This article discusses the recent progress in luminescent Au(
i
) complexes whilst considering their utility in bioimaging and therapeutics.
This article discusses the recent progress in luminescent Au(
i
) complexes whilst considering their utility in bioimaging and therapeutics.
Submillimeter/millimeter observations of dusty star-forming galaxies with the Atacama Large Millimeter/submillimeter Array (ALMA) have shown that dust continuum emission generally occurs in compact ...regions smaller than the stellar distribution. However, it remains to be understood how systematic these findings are. Studies often lack homogeneity in the sample selection, target discontinuous areas with inhomogeneous sensitivities, and suffer from modest
u
v
coverage coming from single array configurations. GOODS-ALMA is a 1.1 mm galaxy survey over a continuous area of 72.42 arcmin
2
at a homogeneous sensitivity. In this version 2.0, we present a new low resolution dataset and its combination with the previous high resolution dataset from the survey, improving the
u
v
coverage and sensitivity reaching an average of
σ
= 68.4 μJy beam
−1
. A total of 88 galaxies are detected in a blind search (compared to 35 in the high resolution dataset alone), 50% at
S
/
N
peak
≥ 5 and 50% at 3.5 ≤
S
/
N
peak
≤ 5 aided by priors. Among them, 13 out of the 88 are optically dark or faint sources (
H
- or
K
-band dropouts). The sample dust continuum sizes at 1.1 mm are generally compact, with a median effective radius of
R
e
= 0
.
″
10 ± 0
.
″
05 (a physical size of
R
e
= 0.73 ± 0.29 kpc at the redshift of each source). Dust continuum sizes evolve with redshift and stellar mass resembling the trends of the stellar sizes measured at optical wavelengths, albeit a lower normalization compared to those of late-type galaxies. We conclude that for sources with flux densities
S
1.1 mm
> 1 mJy, compact dust continuum emission at 1.1 mm prevails, and sizes as extended as typical star-forming stellar disks are rare. The
S
1.1 mm
< 1 mJy sources appear slightly more extended at 1.1 mm, although they are still generally compact below the sizes of typical star-forming stellar disks.
Abstract
We present the results of a new study of the relationship between infrared excess (IRX ≡ LIR/LUV), ultraviolet (UV) spectral slope (β) and stellar mass at redshifts 2 < z < 3, based on a ...deep Atacama Large Millimeter Array (ALMA) 1.3-mm continuum mosaic of the Hubble Ultra Deep Field. Excluding the most heavily obscured sources, we use a stacking analysis to show that z ≃ 2.5 star-forming galaxies in the mass range $9.25\le \log (M_{\ast }/\rm M_{{\odot }}) \le 10.75$ are fully consistent with the IRX–β relation expected for a relatively grey attenuation curve, similar to the commonly adopted Calzetti law. Based on a large, mass-complete sample of 2 ≤ z ≤ 3 star-forming galaxies drawn from multiple surveys, we proceed to derive a new empirical relationship between β and stellar mass, making it possible to predict UV attenuation (A1600) and IRX as a function of stellar mass, for any assumed attenuation law. Once again, we find that z ≃ 2.5 star-forming galaxies follow A1600–M* and IRX–M* relations consistent with a relatively grey attenuation law, and find no compelling evidence that star-forming galaxies at this epoch follow a reddening law as steep as the Small Magellanic Cloud (SMC) extinction curve. In fact, we use a simple simulation to demonstrate that previous determinations of the IRX–β relation may have been biased towards low values of IRX at red values of β, mimicking the signature expected for an SMC-like dust law. We show that this provides a plausible mechanism for reconciling apparently contradictory results in the literature and that, based on typical measurement uncertainties, stellar mass provides a cleaner prediction of UV attenuation than β. Although the situation at lower stellar masses remains uncertain, we conclude that for 2 < z < 3 star-forming galaxies with $\log (M_{\ast }/\rm M_{{\odot }}) \ge 9.75$, both the IRX–β and IRX–M* relations are well described by a Calzetti-like attenuation law.
ABSTRACT We present 0 4 resolution extinction-independent distributions of star formation and dust in 11 star-forming galaxies (SFGs) at z = 1.3-3.0. These galaxies are selected from sensitive ...blank-field surveys of the 2′ × 2′ Hubble Ultra-Deep Field at λ = 5 cm and 1.3 mm using the Karl G. Jansky Very Large Array and Atacama Large Millimeter/submillimeter Array. They have star formation rates (SFRs), stellar masses, and dust properties representative of massive main-sequence SFGs at z ∼ 2. Morphological classification performed on spatially resolved stellar mass maps indicates a mixture of disk and morphologically disturbed systems; half of the sample harbor X-ray active galactic nuclei (AGNs), thereby representing a diversity of z ∼ 2 SFGs undergoing vigorous mass assembly. We find that their intense star formation most frequently occurs at the location of stellar-mass concentration and extends over an area comparable to their stellar-mass distribution, with a median diameter of 4.2 1.8 kpc. This provides direct evidence of galaxy-wide star formation in distant blank-field-selected main-sequence SFGs. The typical galactic-average SFR surface density is 2.5 M yr−1 kpc−2, sufficiently high to drive outflows. In X-ray-selected AGN where radio emission is enhanced over the level associated with star formation, the radio excess pinpoints the AGNs, which are found to be cospatial with star formation. The median extinction-independent size of main-sequence SFGs is two times larger than those of bright submillimeter galaxies, whose SFRs are 3-8 times larger, providing a constraint on the characteristic SFR (∼300 M yr−1) above which a significant population of more compact SFGs appears to emerge.
ABSTRACT ALMA Cycle 2 observations of long-wavelength dust emission in 145 star-forming galaxies are used to probe the evolution of the star-forming interstellar medium (ISM). We also develop a ...physical basis and empirical calibration (with 72 low-z and z ∼ 2 galaxies) for using the dust continuum as a quantitative probe of ISM masses. The galaxies with the highest star formation rates (SFRs) at = 2.2 and 4.4 have gas masses up to 100 times that of the Milky Way and gas mass fractions reaching 50%-80%, i.e., gas masses 1-4× their stellar masses. We find a single high-z star formation law: yr−1-an approximately linear dependence on the ISM mass and an increased star formation efficiency per unit gas mass at higher redshift. Galaxies above the main sequence (MS) have larger gas masses but are converting their ISM into stars on a timescale only slightly shorter than those on the MS; thus, these "starbursts" are largely the result of having greatly increased gas masses rather than an increased efficiency of converting gas to stars. At z > 1, the entire population of star-forming galaxies has ∼2-5 times shorter gas depletion times than low-z galaxies. These shorter depletion times indicate a different mode of star formation in the early universe-most likely dynamically driven by compressive, high-dispersion gas motions-a natural consequence of the high gas accretion rates.
We previously speculated that depression of cerebellar excitability using cathodal transcranial direct current stimulation (tDCS) might release extra cognitive resources via the disinhibition of ...activity in prefrontal cortex. The objective of the present study was to investigate whether anodal tDCS over the prefrontal cortex could similarly improve performance when cognitive demands are high. Sixty-three right-handed participants in 3 separate groups performed the Paced Auditory Serial Addition Task (PASAT) and the more difficult Paced Auditory Serial Subtraction Task (PASST), before and after 20 min of anodal, cathodal, or sham stimulation over the left dorsolateral prefrontal cortex (DLPFC). Performance was assessed in terms of the accuracy, latency, and variability of correct verbal responses. All behavioral measures significantly improved for the PASST after anodal DLPFC stimulation, but not the PASAT. There were smaller practice effects after cathodal and sham stimulation. Subjective ratings of attention and mental fatigue were unchanged by tDCS over time. We conclude that anodal stimulation over the left DLPFC can selectively improve performance on a difficult cognitive task involving arithmetic processing, verbal working memory, and attention. This result might be achieved by focally improving executive functions and/or cognitive capacity when tasks are difficult, rather than by improving levels of arousal/alertness.
Surfactant or polymer directed self-assembly has been widely investigated to prepare nanostructured metal oxides, semiconductors, and polymers, but this approach is mostly limited to two-phase ...materials, organic/inorganic hybrids, and nanoparticle or polymer-based nanocomposites. Self-assembled nanostructures from more complex, multiscale, and multiphase building blocks have been investigated with limited success. Here, we demonstrate a ternary self-assembly approach using graphene as fundamental building blocks to construct ordered metal oxide−graphene nanocomposites. A new class of layered nanocomposites is formed containing stable, ordered alternating layers of nanocrystalline metal oxides with graphene or graphene stacks. Alternatively, the graphene or graphene stacks can be incorporated into liquid-crystal-templated nanoporous structures to form high surface area, conductive networks. The self-assembly method can also be used to fabricate free-standing, flexible metal oxide−graphene nanocomposite films and electrodes. We have investigated the Li-ion insertion properties of the self-assembled electrodes for energy storage and show that the SnO2−graphene nanocomposite films can achieve near theoretical specific energy density without significant charge/discharge degradation.
We investigate the properties of a sample of 35 galaxies, detected with the Atacama Large Millimeter/Submillimeter Array (ALMA) at 1.1 mm in the GOODS-ALMA field (area of 69 arcmin
2
, resolution = ...0.60″, rms ≃ 0.18 mJy beam
−1
). Using the ultraviolet-to-radio deep multiwavelength coverage of the GOODS–South field, we fit the spectral energy distributions of these galaxies to derive their key physical properties. The galaxies detected by ALMA are among the most massive at
z
= 2−4 (
M
⋆, med
= 8.5 × 10
10
M
⊙
) and they are either starburst or located in the upper part of the galaxy star-forming main sequence. A significant portion of our galaxy population (∼40%), located at
z
∼ 2.5 − 3, exhibits abnormally low gas fractions. The sizes of these galaxies, measured with ALMA, are compatible with the trend between the rest-frame 5000 Å size and stellar mass observed for
z
∼ 2 elliptical galaxies, suggesting that they are building compact bulges. We show that there is a strong link between star formation surface density (at 1.1 mm) and gas depletion time: The more compact a galaxy’s star-forming region is, the shorter its lifetime will be (without gas replenishment). The identified compact sources associated with relatively short depletion timescales (∼100 Myr) are the ideal candidates to be the progenitors of compact elliptical galaxies at
z
∼ 2.