We investigate the relation between gas and star formation in sub-galactic regions, ~360 pc to ~1.5 kpc in size, within the nearby starburst dwarf NGC4449, in order to separate the underlying ...relation from the effects of sampling at varying spatial scales. Dust and gas mass surface densities are derived by combining new observations at 1.1 mm, obtained with the AzTEC instrument on the Large Millimeter Telescope, with archival infrared images in the range 8-500 micron from the Spitzer Space Telescope and the Herschel Space Observatory. We extend the dynamic range of our mm (and dust) maps at the faint end, using a correlation between the far-infrared/millimeter colors F(70)/F(1100) and F(160)/F(1100) and the mid-infrared color F(8)/F(24) that we establish for the first time for this and other galaxies. Supplementing our data with maps of the extinction-corrected star formation rate (SFR) surface density, we measure both the SFR-molecular gas and the SFR-total gas relations in NGC4449. We find that the SFR-molecular gas relation is described by a power law with exponent that decreases from ~1.5 to ~1.2 for increasing region size, while the exponent of the SFR-total gas relation remains constant with value ~1.5 independent of region size. We attribute the molecular law behavior to the increasingly better sampling of the molecular cloud mass function at larger region sizes; conversely, the total gas law behavior likely results from the balance between the atomic and molecular gas phases achieved in regions of active star formation. Our results indicate a non-linear relation between SFR and gas surface density in NGC4449, similar to what is observed for galaxy samples.
We present the first public data release of the CALIFA survey. It consists of science-grade optical datacubes for the first 100 of eventually 600 nearby (0.005<z<0.03) galaxies, obtained with the ...integral-field spectrograph PMAS/PPak mounted on the 3.5m telescope at the Calar Alto observatory. The galaxies in DR1 already cover a wide range of properties in color-magnitude space, morphological type, stellar mass, and gas ionization conditions. This offers the potential to tackle a variety of open questions in galaxy evolution using spatially resolved spectroscopy. Two different spectral setups are available for each galaxy, (i) a low-resolution V500 setup covering the nominal wavelength range 3745-7500A with a spectral resolution of 6.0A (FWHM), and (ii) a medium-resolution V1200 setup covering the nominal wavelength range 3650-4840A with a spectral resolution of 2.3A (FWHM). We present the characteristics and data structure of the CALIFA datasets that should be taken into account for scientific exploitation of the data, in particular the effects of vignetting, bad pixels and spatially correlated noise. The data quality test for all 100 galaxies showed that we reach a median limiting continuum sensitivity of 1.0x10^-18erg/s/cm^2/A/arcsec^2 at 5635A and 2.2x10^-18erg/s/cm^2/A/arcsec^2 at 4500A for the V500 and V1200 setup respectively, which corresponds to limiting r and g band surface brightnesses of 23.6mag/arcsec^2 and 23.4mag/arcsec^2, or an unresolved emission-line flux detection limit of roughly 1x10^-17erg/s/cm^2/arcsec^2 and 0.6x10^-17erg/s/cm^2/arcsec^2, respectively. The median spatial resolution is 3.7", and the absolute spectrophotometric calibration is better than 15% (1sigma). We also describe the available interfaces and tools that allow easy access to this first public CALIFA data.
We investigate the relation between gas and star formation in subgalactic regions, similar to 360. pc to similar to 1.5. kpc in size, within the nearby starburst dwarf NGC 4449, in order to separate ...the underlying relation from the effects of sampling at varying spatial scales. Dust and gas mass surface densities are derived by combining new observations at 1.1. mm, obtained with the AzTEC instrument on the Large Millimeter Telescope, with archival infrared images in the range 8-500 mu m from the Spitzer Space Telescope and the Herschel Space Observatory. We extend the dynamic range of our millimeter (and dust) maps at the faint end, using a correlation between the far-infrared/millimeter colors F(70)/F(1100) (and F(160)/F(1100)) and the mid-infrared color F(8)/F(24) that we establish for the first time for this and other galaxies. Supplementing our data with maps of the extinction-corrected star formation rate (SFR) surface density, we measure both the SFR-molecular gas and the SFR-total. gas relations in NGC 4449. We find that the SFR-molecular. gas relation is described by a power law with an exponent that decreases from similar to 1.5 to similar to 1.2 for increasing region size, while the exponent of the SFR-total. gas relation remains constant with a value of similar to 1.5 independent of region size. We attribute the molecular law behavior to the increasingly better sampling of the molecular cloud mass function at larger region sizes; conversely, the total gas law behavior likely results from the balance between the atomic and molecular gas phases achieved in regions of active star formation. Our results indicate a nonlinear relation between SFR and gas surface density in NGC 4449, similar to what is observed for galaxy samples.
Frontier orbitals determine fundamental molecular properties such as chemical reactivities. Although electron distributions of occupied orbitals can be imaged in momentum space by photoemission ...tomography, it has so far been impossible to follow the momentum-space dynamics of a molecular orbital in time, for example, through an excitation or a chemical reaction. Here, we combined time-resolved photoemission using high laser harmonics and a momentum microscope to establish a tomographic, femtosecond pump-probe experiment of unoccupied molecular orbitals. We measured the full momentum-space distribution of transiently excited electrons, connecting their excited-state dynamics to real-space excitation pathways. Because in molecules this distribution is closely linked to orbital shapes, our experiment may, in the future, offer the possibility of observing ultrafast electron motion in time and space.
As a result of the variability survey in Chi Persei and NGC6910, the number of Beta Cep stars that are members of these two open clusters is increased to twenty stars, nine in NGC6910 and eleven in ...Chi Persei. We compare pulsational properties, in particular the frequency spectra, of Beta Cep stars in both clusters and explain the differences in terms of the global parameters of the clusters. We also indicate that the more complicated pattern of the variability among B type stars in Chi Persei is very likely caused by higher rotational velocities of stars in this cluster. We conclude that the sample of pulsating stars in the two open clusters constitutes a very good starting point for the ensemble asteroseismology of Beta Cep-type stars and maybe also for other B-type pulsators.
CONTEXT: Recent progress in the seismic interpretation of field beta Cep stars has resulted in improvements of the physics in the stellar structure and evolution models of massive stars. Further ...asteroseismic constraints can be obtained from studying ensembles of stars in a young open cluster, which all have similar age, distance and chemical composition. AIMS: To improve our comprehension of the beta Cep stars, we studied the young open cluster NGC 884 to discover new B-type pulsators, besides the two known beta Cep stars, and other variable stars. METHODS: An extensive multi-site campaign was set up to gather accurate CCD photometry time series in four filters (U, B, V, I) of a field of NGC884. Fifteen different instruments collected almost 77500 CCD images in 1286 hours. The images were calibrated and reduced to transform the CCD frames into interpretable differential light curves. Various variability indicators and frequency analyses were applied to detect variable stars in the field. Absolute photometry was taken to deduce some general cluster and stellar properties. RESULTS: We achieved an accuracy for the brightest stars of 5.7 mmag in V, 6.9 mmag in B, 5.0 mmag in I and 5.3 mmag in U. The noise level in the amplitude spectra is 50 micromag in the V band. Our campaign confirms the previously known pulsators, and we report more than one hundred new multi- and mono-periodic B-, A- and F-type stars. Their interpretation in terms of classical instability domains is not straightforward, pointing to imperfections in theoretical instability computations. In addition, we have discovered six new eclipsing binaries and four candidates as well as other irregular variable stars in the observed field.
Charge carrier mobilities in molecular condensates are usually small, as the coherent transport, which is highly effective in conventional semiconductors, is impeded by disorder and the small ...intermolecular coupling. A significant band dispersion can usually only be observed in exceptional cases such as for π-stacking of aromatic molecules in organic single crystals. Here based on angular resolved photoemission, we demonstrate on the example of planar π-conjugated molecules that the hybridization with a metal substrate can substantially increase the delocalization of the molecular states in selective directions along the surface. Supported by ab initio calculations we show how this mechanism couples the individual molecules within the organic layer resulting in an enhancement of the in-plane charge carrier mobility.
Photoemission spectroscopy is commonly applied to study the band structure of solids by measuring the kinetic energy versus angular distribution of the photoemitted electrons. Here, we apply this ...experimental technique to characterize discrete orbitals of large π-conjugated molecules. By measuring the photoemission intensity from a constant initial-state energy over a hemispherical region, we generate reciprocal space maps of the emitting orbital density. We demonstrate that the real-space electron distribution of molecular orbitals in both a crystalline pentacene film and a chemisorbed p-sexiphenyl monolayer can be obtained from a simple Fourier transform of the measurement data. The results are in good agreement with density functional calculations.
The lower esophageal sphincter (LES), surrounded by diaphragmatic muscle, prevents gastroesophageal reflux. When these structures become incompetent, gastric contents may cause gastroesophageal ...reflux disease (GERD). For treatment, lifestyle interventions are always recommended. We hypothesized that by actively training the crura of the diaphragm as part of the LES using breathing training exercises, GERD can be positively influenced.
A prospective randomized controlled study was performed. Patients with non-erosive GERD or healed esophagitis without large hernia and/or previous surgery were included. Patients were randomized and allocated either to active breathing training program or to a control group. Quality of life (QoL), pH-metry, and on-demand proton pump inhibitor (PPI) usage were assessed at baseline and after 4 weeks of training. For long-term follow-up, all patients were invited to continue active breathing training and were further assessed regarding QoL and PPI usage after 9 months. Paired and unpaired t-test was used for statistical analysis.
Nineteen patients with non-erosive GERD or healed esophagitis were randomized into two groups (10 training group and 9 control group). There was no difference in baseline patient characteristics between the groups and all patients finished the study. There was a significant decrease in time with a pH<4.0 in the training group (9.1±1.3 vs. 4.7±0.9%; P<0.05), but there was no change in the control group. QoL scores improved significantly in the training group (13.4±1.98 before and 10.8±1.86 after training; P<0.01), but no changes in QoL were seen in the control group. At long-term follow-up at 9 months, patients who continued breathing exercise (11/19) showed a significant decrease in QoL scores and PPI usage (15.1±2.2 vs. 9.7±1.6; 98±34 vs. 25±12 mg/week, respectively; P<0.05), whereas patients who did not train had no long-term effect.
We show that actively training the diaphragm by breathing exercise can improve GERD as assessed by pH-metry, QoL scores and PPI usage. This non-pharmacological lifestyle intervention could help to reduce the disease burden of GERD.
The intramolecular enamine-Mizoroki–Heck reaction allows for the construction of nitrogen-containing heterocycles, although the related intermolecular version is less known. The reactions of enamines ...derived from Cyrene were investigated under Mizoroki–Heck conditions. An optimization study was used to identify that 1.5 mol % Pd(dba)2 with PCy3 in xylene at reflux temperature gave the highest yield with electron-rich aryl iodides. Arylation occurred predominantly at the C–N center of the enamine, while the diastereoselectivity was dependent on the nitrogen substitution in the enamine.
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