Context. Catalogue cross-correlation is essential to building large sets of multi-wavelength data, whether it be to study the properties of populations of astrophysical objects or to build reference ...catalogues (or timeseries) from survey observations. Nevertheless, resorting to automated processes with limited sets of information available on large numbers of sources detected at different epochs with various filters and instruments inevitably leads to spurious associations. We need both statistical criteria to select detections to be merged as unique sources, and statistical indicators helping in achieving compromises between completeness and reliability of selected associations. Aims. We lay the foundations of a statistical framework for multi-catalogue cross-correlation and cross-identification based on explicit simplified catalogue models. A proper identification process should rely on both astrometric and photometric data. Under some conditions, the astrometric part and the photometric part can be processed separately and merged a posteriori to provide a single global probability of identification. The present paper addresses almost exclusively the astrometrical part and specifies the proper probabilities to be merged with photometric likelihoods. Methods. To select matching candidates in n catalogues, we used the Chi (or, indifferently, the Chi-square) test with 2(n−1) degrees of freedom. We thus call this cross-match a χ-match. In order to use Bayes’ formula, we considered exhaustive sets of hypotheses based on combinatorial analysis. The volume of the χ-test domain of acceptance – a 2(n−1)-dimensional acceptance ellipsoid – is used to estimate the expected numbers of spurious associations. We derived priors for those numbers using a frequentist approach relying on simple geometrical considerations. Likelihoods are based on standard Rayleigh, χ and Poisson distributions that we normalized over the χ-test acceptance domain. We validated our theoretical results by generating and cross-matching synthetic catalogues. Results. The results we obtain do not depend on the order used to cross-correlate the catalogues. We applied the formalism described in the present paper to build the multi-wavelength catalogues used for the science cases of the Astronomical Resource Cross-matching for High Energy Studies (ARCHES) project. Our cross-matching engine is publicly available through a multi-purpose web interface. In a longer term, we plan to integrate this tool into the CDS XMatch Service.
Following World Health Assembly resolutions 50.36 in 1997 and 56.7 in 2003, the World Health Organization (WHO) committed itself to supporting human African trypanosomiasis (HAT)-endemic countries in ...their efforts to remove the disease as a public health problem. Mapping the distribution of HAT in time and space has a pivotal role to play if this objective is to be met. For this reason WHO launched the HAT Atlas initiative, jointly implemented with the Food and Agriculture Organization of the United Nations, in the framework of the Programme Against African Trypanosomosis.
The distribution of HAT is presented for 23 out of 25 sub-Saharan countries having reported on the status of sleeping sickness in the period 2000-2009. For the two remaining countries, i.e. Angola and the Democratic Republic of the Congo, data processing is ongoing. Reports by National Sleeping Sickness Control Programmes (NSSCPs), Non-Governmental Organizations (NGOs) and Research Institutes were collated and the relevant epidemiological data were entered in a database, thus incorporating (i) the results of active screening of over 2.2 million people, and (ii) cases detected in health care facilities engaged in passive surveillance. A total of over 42 000 cases of HAT and 6 000 different localities were included in the database. Various sources of geographic coordinates were used to locate the villages of epidemiological interest. The resulting average mapping accuracy is estimated at 900 m.
Full involvement of NSSCPs, NGOs and Research Institutes in building the Atlas of HAT contributes to the efficiency of the mapping process and it assures both the quality of the collated information and the accuracy of the outputs. Although efforts are still needed to reduce the number of undetected and unreported cases, the comprehensive, village-level mapping of HAT control activities over a ten-year period ensures a detailed and reliable representation of the known geographic distribution of the disease. Not only does the Atlas serve research and advocacy, but, more importantly, it provides crucial evidence and a valuable tool for making informed decisions to plan and monitor the control of sleeping sickness.
Wettability alteration can occur at different stages during the producing life of a reservoir. Oil recovery from oil-wet reservoirs can significantly be increased by altering its wettability from an ...oil-wet to a strongly water-wet condition. Chemical agents such as surfactants are known as wettability modifiers in oil-wet systems. More recently, nanofluids prepared by dispersing nanoparticles in several liquid agents have been considered as potential wettability modifiers. In this work, the effectiveness of alumina-based nanofluids in altering the wettability of sandstone cores with an induced oil-wet wettability was experimentally studied. Eight nanofluids with different nanoparticles concentration, ranging from 100 ppm to 10000 ppm, were prepared by dispersing alumina nanoparticles in an anionic commercial surfactant. The effect of nanofluids on wettability alteration was investigated by contact angle and imbibition tests, and it was shown that designed nanofluids could significantly change the wettability of the sandstone cores from a strongly oil-wet to a strongly water-wet condition. Imbibition tests also allowed identifying the effect of nanoparticles concentration on the suitability of the treatment for enhancing the imbibition process and restoring the original core wettability. Results showed that the effectiveness of the anionic surfactant as wettability modifier could be improved by adding nanoparticles in concentrations lower or equal than 500 ppm. The best performance was achieved when a concentration of 100 ppm was used. Additionally, a core displacement test was carried out by injecting in a sand pack a nanofluid prepared by dispersing alumina nanoparticles in distillated water. The treatment was effective in altering the sand pack wettability from an oil-wet to a strongly water-wet condition as indicated by a significant reduction in the residual water saturation and a displacement to the right of the oil relative permeability curve and the crossover point.
We describe herein the state of the art following the last 8 years of research into aromatic polyamides, wholly aromatic polyamides or aramids. These polymers belong to the family of high performance ...materials because of their exceptional thermal and mechanical behavior. Commercially, they have been transformed into fibers mainly for production of advanced composites, paper, and cut and fire protective garments. Huge research efforts have been carried out to take advantage of the mentioned characteristics in advanced fields related to transport applications, optically active materials, electroactive materials, smart materials, or materials with even better mechanical and thermal behavior.
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•Hydrothermal processing is a promising pretreatment for biomass fractionation.•Steam explosion and liquid hot water solubilize and depolymerize hemicellulose.•Hydrothermal ...pretreatment stage plays an important role in the biorefinery concept.•The severity factor correlates the operating conditions of temperature and time.
Hydrothermal processes are an attractive clean technology and cost-effective engineering platform for biorefineries based in the conversion of biomass to biofuels and high-value bioproducts under the basis of sustainability and circular bioeconomy. The deep and detailed knowledge of the structural changes by the severity of biomasses hydrothermal fractionation is scientifically and technological needed in order to improve processes effectiveness, reactors designs, and industrial application of the multi-scale target compounds obtained by steam explosion and liquid hot water systems. The concept of the severity factor log10 (Ro) established>30 years ago, continues to be a useful index that can provide a simple descriptor of the relationship between the operational conditions for biomass fractionation in second generation of biorefineries. This review develops a deep explanation of the hydrothermal severity factor based in lignocellulosic biomass fractionation with emphasis in research advances, pretreatment operations and the applications of severity factor kinetic model.
Atomically thin layers of two-dimensional materials can be assembled in vertical stacks that are held together by relatively weak van der Waals forces, enabling coupling between monolayer crystals ...with incommensurate lattices and arbitrary mutual rotation
. Consequently, an overarching periodicity emerges in the local atomic registry of the constituent crystal structures, which is known as a moiré superlattice
. In graphene/hexagonal boron nitride structures
, the presence of a moiré superlattice can lead to the observation of electronic minibands
, whereas in twisted graphene bilayers its effects are enhanced by interlayer resonant conditions, resulting in a superconductor-insulator transition at magic twist angles
. Here, using semiconducting heterostructures assembled from incommensurate molybdenum diselenide (MoSe
) and tungsten disulfide (WS
) monolayers, we demonstrate that excitonic bands can hybridize, resulting in a resonant enhancement of moiré superlattice effects. MoSe
and WS
were chosen for the near-degeneracy of their conduction-band edges, in order to promote the hybridization of intra- and interlayer excitons. Hybridization manifests through a pronounced exciton energy shift as a periodic function of the interlayer rotation angle, which occurs as hybridized excitons are formed by holes that reside in MoSe
binding to a twist-dependent superposition of electron states in the adjacent monolayers. For heterostructures in which the monolayer pairs are nearly aligned, resonant mixing of the electron states leads to pronounced effects of the geometrical moiré pattern of the heterostructure on the dispersion and optical spectra of the hybridized excitons. Our findings underpin strategies for band-structure engineering in semiconductor devices based on van der Waals heterostructures
.
Recent models support the view that the Pyrenees were formed after the inversion of a previously highly extended continental crust that included exhumed upper mantle rocks. Mantle rocks remain near ...to the surface after compression and mountain building, covered by the latest Cretaceous to Paleogene sequences. 3‐D lithospheric‐scale gravity inversion demands the presence of a high‐density mantle body placed within the crust in order to justify the observed anomalies. Exhumed mantle, having ~50 km of maximum width, continuously extends beneath the Basque‐Cantabrian Basin and along the northern side of the Pyrenees. The association of this body with rift, postrift, and inversion structural geometries is tested in a balanced cross section across the Basque‐Cantabrian Basin that incorporates a major south‐dipping ramp‐flat‐ramp extensional detachment active between Valanginian and early Cenomanian times. Results indicate that horizontal extension progressed ~48 km at variable strain rates that increased from 1 to ~4 mm/yr in middle Albian times. Low‐strength Triassic Keuper evaporites and mudstones above the basement favor the decoupling of the cover with formation of minibasins, expulsion rollovers, and diapirs. The inversion of the extensional system is accommodated by doubly verging basement thrusts due to the reactivation of the former basin bounding faults in Eocene‐Oligocene times. Total shortening is estimated in ~34 km and produced the partial subduction of the continental lithosphere beneath the two sides of the exhumed mantle. Obtained results help to pinpoint the original architecture of the North Iberian Margin and the evolution of the hyperextended aborted intracontinental basins.
Key Points
3‐D lithospheric‐scale gravity inversion demands the presence of a high‐density mantle body placed within the crust
Exhumed mantle extends beneath the Basque‐Cantabrian Basin and along the northern side of the Pyrenees
A major south‐dipping ramp‐flat‐ramp extensional detachment active between Valanginian and early Cenomanian times controlled rifting and mantle exhumation
Polyphosphate (polyP) is a pro-inflammatory agent and a potent modulator of the human blood-clotting system. The presence of polyP of 60 phosphate units was identified in rat basophilic leukemia ...(RBL-2H3) mast cells using specific enzymatic assays, urea-polyacrylamide gel electrophoresis of cell extracts, and staining of cells with 4,6-diamidino-2-phenylindole (DAPI), and the polyP-binding domain of Escherichia coli exopolyphosphatase. PolyP co-localizes with serotonin- but not with histamine-containing granules. PolyP levels greatly decreased in mast cells stimulated to degranulate by IgE. Mast cell granules were isolated and found to be acidic and decrease their polyP content upon alkalinization. In agreement with these results, when RBL-2H3 mast cells were loaded with the fluorescent calcium indicator fura-2 acetoxymethyl ester to measure their intracellular Ca2+ concentration (Ca2+i), they were shown to possess a significant amount of Ca2+ stored in an acidic compartment different from lysosomes. PolyP derived from RBL-2H3 mast cells stimulated bradykinin formation, and it was also detected in human basophils. All of these characteristics of mast cell granules, together with their known elemental composition, and high density, are similar to those of acidocalcisomes. The results suggest that mast cells polyP could be an important mediator of their pro-inflammatory and pro-coagulant activities.
Background: Polyphosphate has pro-coagulant and pro-inflammatory activities.
Results: Mast cell polyphosphate was found in their acidocalcisome-like granules and stimulated bradykinin formation.
Conclusion: Polyphosphate is a novel component of mast cell granules.
Significance: Results suggest that the pro-coagulant and pro-inflammatory activities of mast cells could in part be attributed to polyphosphate.
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