Salinization and nitrate pollution are generally ascertained as the main issues affecting coastal aquifers worldwide. In arid zones, where agricultural activities also result in soil salinization, ...both phenomena tend to co-exist and synergically contribute to alter groundwater quality, with severe negative impacts on human populations and natural ecosystems’ wellbeing. It becomes therefore necessary to understand if and to what extent integrated hydrogeochemical tools can help in distinguishing among possible different salinization and nitrate contamination origins, in order to provide adequate science-based support to local development and environmental protection. The alluvial plain of Bou-Areg (North Morocco) extends over about 190 km
2
and is separated from the Mediterranean Sea by the coastal Lagoon of Nador. Its surface is covered for more than 60% by agricultural activities, although the region has been recently concerned by urban population increase and tourism expansion. All these activities mainly rely on groundwater exploitation and at the same time are the main causes of both aquifer and lagoon water quality degradation. For this reason, it was chosen as a case study representative of the typical situation of coastal aquifers in arid zones worldwide, where a clear identification of salinization and pollution sources is fundamental for the implementation of locally oriented remedies and long-term management strategies. Results of a hydrogeochemical investigation performed between 2009 and 2011 show that the Bou-Areg aquifer presents high salinity (often exceeding 100 mg/L in TDS) due to both natural and anthropogenic processes. The area is also impacted by nitrate contamination, with concentrations generally exceeding the WHO statutory limits for drinking water (50 mg/L) and reaching up to about 300 mg/L, in both the rural and urban/peri-urban areas. The isotopic composition of dissolved nitrates (δ
15
N
NO3
and δ
18
O
NO
) was used to constrain pollution drivers. The results indicate two main origins for human-induced pollution: (i) manure and septic effluents, especially in urban areas, and (ii) synthetic fertilizers in agricultural areas. In the latter, δ
15
N-enriched values highlight a mixture of those sources, possibly related to unbalanced fertilization and agricultural return flow. Boron isotopes (δ
11
B) were hence studied to further distinguish the nitrate origin in the presence of multiple sources and mixing processes. The results indicate that in the study area, the high geochemical background for B and Cl, associated to the complex water-rock interaction processes, limit the application of the coupled δ
11
B and δ
15
N isotopic systematics to the detection of sources of groundwater pollution. In fact, despite the exceedingly high nitrate contents, the depleted δ
11
B values that characterize synthetic fertilizers and sewage leakages could not be detected. Therefore, even if in saline groundwater the anthropogenic contribution has a negligible effect in terms of salinity input, with both sewage and irrigation water not very charged, the associated nitrate content fuels up water-rock interaction processes, eventually leading to a mineralization increase.
The most spread groundwater-dependent ecosystems in the River Po valley are semi-natural lowland springs called “fontanili”. They provide specific habitats and support high biodiversity, but are ...often strongly impaired by agricultural pollution. In the present study we seasonally monitored the discharge and nitrogen concentration of 48 fontanili from the Adda and the Ticino river basins. We observed a wide spatial variability of both NO3-N concentrations and flows. The annual NO3-N loads ranged from <1 to 75 t y−1 and < 1 to 29 t y−1 in the Adda and Ticino basins respectively. In the springs characterized by variable discharge the N loads were exported mostly during the summer season when water table level was elevated mainly due to irrigation. Upscaling the mean NO3-N load to each river catchment based on the total number of springs, we obtained an aerial export of 33.2 ± 6.0 and 12.5 ± 3.2 kg y−1 ha−1. Such loads accounted for the 30.4 and 21.5% of the N surplus estimated for the Adda and Ticino basins respectively.
Random Forest analysis was performed to identify the most important environmental variables influencing the nitrate contamination in the spring waters. A total of 22 explanatory variables related to N sources, land uses, intrinsic hydrogeologic and soil proprieties, in “situ” and remotely sensed variables were considered. The percent of soil cultivated with maize in a 500 m radius buffer area surrounding the sampling site, the N from manure and the distance of each spring from the main river were the most effective factors in controlling the NO3-N concentration in the fontanili water.
The outcomes of this work open up to achievable management prospects for the protection and recovery of fontanili waters, and can be particularly useful for water managers in identifying areas and sites where restoration plans should be a priority.
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•Maize cultivated adjacent lands control NO3 content in the main GDEs of the Po plain.•A severe pollution of fontanili is likely when N from manure exceeds 300 kg N ha−1 y−1.•The areal nitrate export of springs represents a consistent fraction of the N surplus.•Spring N loads were greater in summer when the water table was high due to irrigation.
Nitrate contamination still remains one of the main groundwater quality issues in several aquifers worldwide, despite the perduring efforts of the international scientific community to effectively ...tackle this problem. The classical hydrogeological and isotopic investigations are obviously of paramount importance for the characterization of contaminant sources, but are clearly not sufficient for the correct and long-term protection of groundwater resources. This paper aims at demonstrating the effectiveness of the socio-hydrogeological approach as the best tool to tackle groundwater quality issues, while contributing bridging the gap between science and society. An integrated survey, including land use, hydrochemical (physicochemical parameters and major ions) and isotopic (δ15NNO3 and δ18ONO3) analyses, coupled to capacity building and participatory activities was carried out to correctly attribute the nitrate origin in groundwater from the Grombalia Basin (North Tunisia), a region where only synthetic fertilizers have been generally identified as the main source of such pollution. Results demonstrates that the basin is characterized by high nitrate concentrations, often exceeding the statutory limits for drinking water, in both the shallow and deep aquifers, whereas sources are associated to both agricultural and urban activities.
The public participation of local actors proved to be a fundamental element for the development of the hydrogeological investigation, as it permitted to obtain relevant information to support data interpretation, and eventually guaranteed the correct assessment of contaminant sources in the studied area. In addition, such activity, if adequately transferred to regulators, will ensure the effective adoption of management practices based on the research outcomes and tailored on the real needs of the local population, proving the added value to include it in any integrated investigation.
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•Effectiveness of socio-hydrogeology in groundwater quality assessment is proven.•Dual origin of nitrate contamination: fertilizers and anthropogenic organic matter.•High nitrates in the deep aquifer suggest hydraulic connections with the shallow.•Dissolution of evaporites is triggered by nitrate contamination.•Public participation provides essential information for correct data interpretation.
The knowledge of the regional variability, the background values and the anthropic vs. natural origin for potentially harmful elements in soils is of critical importance to assess human impact and to ...fix guide values and quality standards. The present study was undertaken as a preliminary survey on soil contamination on a regional scale in Piemonte (NW Italy). The aims of the study were: (1) to determine average regional concentrations of some heavy metals (Cr, Co, Ni, Cu, Zn, Pb); (2) to find out their large-scale variability; (3) to define their natural or artificial origin; and (4) to identify possible non-point sources of contamination. Multivariate statistic approaches (Principal Component Analysis and Cluster Analysis) were adopted for data treatment, allowing the identification of three main factors controlling the heavy metal variability in cultivated soils. Geostatistics were used to construct regional distribution maps, to be compared with the geographical, geologic and land use regional database using GIS software. This approach, evidencing spatial relationships, proved very useful to the confirmation and refinement of geochemical interpretations of the statistical output. Cr, Co and Ni were associated with and controlled by parent rocks, whereas Cu together with Zn, and Pb alone were controlled by anthropic activities. The study indicates that background values and realistic mandatory guidelines are impossible to fix without an extensive data collection and without a correct geochemical interpretation of the data.
ABSTRACT
We present the star formation history (SFH) of the extremely metal-poor dwarf galaxy DDO 68, based on our photometry with the Advanced Camera for Surveys. With a metallicity of only
and a ...very isolated location, DDO 68 is one of the most metal-poor galaxies known. It has been argued that DDO 68 is a young system that started forming stars only ∼0.15 Gyr ago. Our data provide a deep and uncontaminated optical color–magnitude diagram (CMD) that allows us to disprove this hypothesis since we find a population of at least ∼1 Gyr old stars. The star formation activity has been fairly continuous over all the look-back time. The current rate is quite low, and the highest activity occurred between 10 and 100 Myr ago. The average star formation rate over the whole Hubble time is ≃0.01
M
⊙
yr
−1
, corresponding to a total astrated mass of ≃1.3 × 10
8
M
⊙
. Our photometry allows us to infer the distance from the tip of the red giant branch,
D
= 12.08 ± 0.67 Mpc; however, to let our synthetic CMD reproduce the observed ones, we need a slightly higher distance,
D
= 12.65 Mpc, or (
m
−
M
)
0
= 30.51, still inside the errors of the previous determination, and we adopt the latter. DDO 68 shows a very interesting and complex history, with its quite disturbed shape and a long tail, probably due to tidal interactions. The SFH of the tail differs from that of the main body mainly for enhanced activity at recent epochs likely triggered by the interaction.
We present two cases about projects in different maturity levels regarding infrastructure as code. The intent is to expose experiences and problems that may arise on new or already existing projects. ...Each case is exposed in a separate session.
Abstract
We report the large effort that is producing comprehensive high-level young star cluster (YSC) catalogs for a significant fraction of galaxies observed with the Legacy ExtraGalactic UV ...Survey (LEGUS)
Hubble
treasury program. We present the methodology developed to extract cluster positions, verify their genuine nature, produce multiband photometry (from NUV to NIR), and derive their physical properties via spectral energy distribution fitting analyses. We use the nearby spiral galaxy NGC 628 as a test case for demonstrating the impact that LEGUS will have on our understanding of the formation and evolution of YSCs and compact stellar associations within their host galaxy. Our analysis of the cluster luminosity function from the UV to the NIR finds a steepening at the bright end and at all wavelengths suggesting a dearth of luminous clusters. The cluster mass function of NGC 628 is consistent with a power-law distribution of slopes
and a truncation of a few times 10
5
. After their formation, YSCs and compact associations follow different evolutionary paths. YSCs survive for a longer time frame, confirming their being potentially bound systems. Associations disappear on timescales comparable to hierarchically organized star-forming regions, suggesting that they are expanding systems. We find mass-independent cluster disruption in the inner region of NGC 628, while in the outer part of the galaxy there is little or no disruption. We observe faster disruption rates for low mass (≤10
4
) clusters, suggesting that a mass-dependent component is necessary to fully describe the YSC disruption process in NGC 628.
We present an investigation of the relationship between giant molecular cloud (GMC) properties and the associated stellar clusters in the nearby flocculent galaxy NGC 7793. We combine the star ...cluster catalogue from the HST LEGUS (Legacy ExtraGalactic UV Survey) programme with the 15 pc resolution ALMA CO(2-1) observations. We find a strong spatial correlation between young star clusters and GMCs such that all clusters still associated with a GMC are younger than 11 Myr and display a median age of 2 Myr. The age distribution increases gradually as the cluster-GMC distance increases, with star clusters that are spatially unassociated with molecular gas exhibiting a median age of 7 Myr. Thus, star clusters are able to emerge from their natal clouds long before the time-scale required for clouds to disperse. To investigate if the hierarchy observed in the stellar components is inherited from the GMCs, we quantify the amount of clustering in the spatial distributions of the components and find that the star clusters have a fractal dimension slope of -0.35 +/- 0.03, significantly more clustered than the molecular cloud hierarchy with slope of -0.18 +/- 0.04 over the range 40-800 pc. We find, however, that the spatial clustering becomes comparable in strength for GMCs and star clusters with slopes of -0.44 +/- 0.03 and -0.45 +/- 0.06, respectively, when we compare massive (> 10(5) M-circle dot) GMCs to massive and young star clusters. This shows that massive star clusters trace the same hierarchy as their parent GMCs, under the assumption that the star formation efficiency is a few per cent.
The assessment of nitrate pollution origin using stable isotope techniques is a fundamental prerequisite for the application of sustainable groundwater management plans. Although nitrate pollution is ...a worldwide groundwater quality problem, existing knowledge on the origin of nitrate pollution in arid and semi-arid regions is still scarce. Using the example of the Grombalia aquifer (NE Tunisia), this work summarizes the main strengths and constraints of multi-isotope techniques targeting at nitrate source identification and apportionment The results highlighted that, even in the case of well-established methodologies, like those of isotope hydrogeochemistry (δ15NNO3, δ 18ONO3 and δ 11B) and mixing modelling for source apportionment, it is fundamental to take into account regional and local end-members to avoid biased data interpretation and to fully exploit the potential of such accurate tools.
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•Current knowledge of nitrate pollution origin in (semi)arid regions is still scarce.•New frontiers for nitrate source apportionment in (semi)arid regions are discussed.•δ15N/δ11B systematics: not effective for groundwater with high B natural background.•SIAR outcomes are highly dependent on the values attributed to the sources.•Unbiased source apportionment is fundamental to support groundwater management.
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