Aims. We investigate the ortho-water abundance in outflows and shocks in order to improve our knowledge of shock chemistry and of the physics behind molecular outflows. Methods. We have used the Odin ...space observatory to observe the H2O(110-101) line. We obtain strip maps and single pointings of 13 outflows and two supernova remnants where we report detections for eight sources. We have used RADEX to compute the beam averaged abundances of o-H2O relative to H2. In the case of non-detection, we derive upper limits on the abundance. Results. Observations of CO emission from the literature show that the volume density of H2 can vary to a large extent, a parameter that puts severe uncertainties on the derived abundances. Our analysis shows a wide range of abundances reflecting the degree to which shock chemistry is affecting the formation and destruction of water. We also compare our results with recent results from the SWAS team. Conclusions. Elevated abundances of ortho-water are found in several sources. The abundance reaches values as high as what would be expected from a theoretical C-type shock where all oxygen, not in the form of CO, is converted to water. However, the high abundances we derive could also be due to the low densities (derived from CO observations) that we assume. The water emission may in reality stem from high density regions much smaller than the Odin beam. We do not find any relationship between the abundance and the mass loss rate. On the other hand, there is a relation between the derived water abundance and the observed maximum outflow velocity.
The Odin satellite has been used to search for the 118.75-GHz line of molecular oxygen (O2)in the Galactic centre. Odin observations were performed towards the Sgr A* circumnuclear disk (CND), and ...the Sgr A +20 km/s and +50 km/s molecular clouds using the position-switching mode. Supplementary ground-based observations were carried out in the 2-mm band using the ARO Kitt Peak 12-m telescope to examine suspected SiC features. A strong emission line was found at 118.27 GHz, attributable to the J=13-12 HC3N line. Upper limits are presented for the 118.75-GHz O2 (1,1-1,0) ground transition line and for the 118.11-GHz 3Pi2, J=3-2 ground state SiC line at the Galactic centre. Upper limits are also presented for the 487-GHz O2 line in the Sgr A +50 km/s cloud and for the 157-GHz, J=4-3, SiC line in the Sgr A +20 and +50 km/s clouds, as well as the CND. The CH3OH line complex at 157.2 - 157.3 GHz has been detected in the +20 and +50 km/s clouds but not towards Sgr A*/CND. A 3-sigma upper limit for the fractional abundance ratio of O2/H2 is found to be X(O2) < 1.2 x 10exp(-7) towards the Sgr A molecular belt region.
Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions ...SWAS and Odin found only very small amounts of water vapour and essentially no O2 in the dense star-forming interstellar medium. Only toward rho Oph A did Odin detect a weak line of O2 at 119 GHz in a beam size of 10 arcmin. A larger telescope aperture such as that of the Herschel Space Observatory is required to resolve the O2 emission and to pinpoint its origin. We use the Heterodyne Instrument for the Far Infrared aboard Herschel to obtain high resolution O2 spectra toward selected positions in rho Oph A. These data are analysed using standard techniques for O2 excitation and compared to recent PDR-like chemical cloud models. The 487.2GHz line was clearly detected toward all three observed positions in rho Oph A. In addition, an oversampled map of the 773.8GHz transition revealed the detection of the line in only half of the observed area. Based on their ratios, the temperature of the O2 emitting gas appears to vary quite substantially, with warm gas (> 50 K) adjacent to a much colder region, where temperatures are below 30 K. The exploited models predict O2 column densities to be sensitive to the prevailing dust temperatures, but rather insensitive to the temperatures of the gas. In agreement with these model, the observationally determined O2 column densities seem not to depend strongly on the derived gas temperatures, but fall into the range N(O2) = (3 to >6)e15/cm^2. Beam averaged O2 abundances are about 5e-8 relative to H2. Combining the HIFI data with earlier Odin observations yields a source size at 119 GHz of about 4 - 5 arcmin, encompassing the entire rho Oph A core.
Spectral line surveys are useful since they allow identification of new molecules and new lines in uniformly calibrated data sets. Nonetheless, large portions of the sub-millimetre spectral regime ...remain unexplored due to severe absorptions by H2O and O2 in the terrestrial atmosphere. The purpose of the measurements presented here is to cover wavelength regions at and around 0.55 mm -- regions largely unobservable from the ground. Using the Odin astronomy/aeronomy satellite, we performed the first spectral survey of the Orion KL molecular cloud core in the bands 486--492 and 541--576 GHz with rather uniform sensitivity (22--25 mK baseline noise). Odin's 1.1 m size telescope, equipped with four cryo-cooled tuneable mixers connected to broad band spectrometers, was used in a satellite position-switching mode. Two mixers simultaneously observed different 1.1 GHz bands using frequency steps of 0.5 GHz (25 hours each). An on-source integration time of 20 hours was achieved for most bands. The entire campaign consumed ~1100 orbits, each containing one hour of serviceable astro-observation. We identified 280 spectral lines from 38 known interstellar molecules (including isotopologues) having intensities in the range 80 to 0.05 K. An additional 64 weak lines remain unidentified. Apart from the ground state rotational 1(1,0)--1(0,1) transitions of ortho-H2O, H218O and H217O, the high energy 6(2,4)--7(1,7) line of para-H2O and the HDO(2,0,2--1,1,1) line have been observed, as well as the 1,0--0,1 lines from NH3 and its rare isotopologue 15NH3. We suggest assignments for some unidentified features, notably the new interstellar molecules ND and SH-. Severe blends have been detected in the line wings of the H218O, H217O and 13CO lines changing the true linewidths of the outflow emission.
We investigate the physical and chemical conditions in a typical star forming region, including an unbiased search for new molecules in a spectral region previously unobserved. Due to its proximity, ...the Orion KL region offers a unique laboratory of molecular astrophysics in a chemically rich, massive star forming region. Several ground-based spectral line surveys have been made, but due to the absorption by water and oxygen, the terrestrial atmosphere is completely opaque at frequencies around 487 and 557 GHz. To cover these frequencies we used the Odin satellite to perform a spectral line survey in the frequency ranges 486-492 GHz and 541-577 GHz, filling the gaps between previous spectral scans. Odin's high main beam efficiency and observations performed outside the atmosphere make our intensity scale very well determined. We observed 280 spectral lines from 38 molecules including isotopologues, and, in addition, 64 unidentified lines. The beam-averaged emission is dominated by CO, H2O, SO2, SO, 13CO and CH3OH. Species with the largest number of lines are CH3OH, (CH33)2O, SO2, 13CH3OH, CH3CN and NO. Six water lines are detected including the ground state rotational transition o-H2O, its isotopologues o-H218O and o-H217O, the Hot Core tracing p-H2O transition 6(2,4)-7(1,7), and the 2(0, 2)-1(1,1) transition of HDO. Other lines of special interest are the 1_0-0_0 transition of NH3 and its isotopologue 15NH3. Isotopologue abundance ratios of D/H, 12C/13C, 32S/34S, 34S/33S, and 18O/17O are estimated. The temperatures, column densities and abundances in the various subregions are estimated, and we find very high gas-phase abundances of H2O, NH3, SO2, SO, NO, and CH3OH. A comparison with the ice inventory of ISO sheds new light on the origin of the abundant gas-phase molecules.
Planet.Space Sci.55:1058-1068,2007 The Odin satellite, launched in Feb. 2001, is equipped with a 1.1-m
submillimetre telescope. Odin was used to observe the 557 GHz line of water
with high spectral ...resolution in 12 comets between 2001 and 2005. Line shapes
and spatial mapping provide information on the anisotropy of the outgassing and
constraints on water excitation, enabling accurate measurements of the water
production rate. Five comets were regularly observed over periods of more than
one month to monitor the variation of their water outgassing rate with
heliocentric distance. Observing campaigns have been generally coordinated with
ground-based observations of molecular lines at Nan\c{c}ay, CSO or IRAM 30-m
telescopes to obtain molecular abundances relative to water.
Thanks to Odin's frequency coverage, it was also possible to detect the
H_2^18O 548GHz line, first in comet 153P/Ikeya-Zhang in April 2002 (Lecacheux
et al., 2003) and then in comets C/2002 T7 (LINEAR), C/2001 Q4 (NEAT) and
C/2004 Q2 (Machholz). The ^16O/^18O isotopic ratio (\approx450) is consistent
with the terrestrial value. Ammonia has been searched for in three comets
through its J_K = 1_0-0_0 line at 572 GHz and was tentatively detected in
C/2001 Q4 and C/2002 T7. The derived abundances of NH_3 relative to water are
0.5 % and 0.3 %, respectively, similar to values obtained in other comets with
different techniques.
We present a 39 h integration with the Odin satellite on the ground-state
118.75 GHz line of O2 towards the region of strongest molecular emission in the
Small Magellanic Cloud. Our 3sigma upper ...limit to the O2 integrated intensity
of <0.049 K km/s in a 9'(160 pc) diameter beam corresponds to an upper limit on
the O2/H2 abundance ratio of <1.3E-6. Although a factor of 20 above the best
limit on the O2 abundance obtained for a Galactic source, our result has
interesting implications for understanding oxygen chemistry at sub-solar metal
abundances. We compare our abundance limit to a variety of astrochemical models
and find that, at low metallicities, the low O2 abundance is most likely
produced by the effects of photo-dissociation on molecular cloud structure.
Freeze-out of molecules onto dust grains may also be consistent with the
observed abundance limit, although such models have not yet been run at
sub-solar initial metallicities.
We have searched for emission from the 557 GHz ortho-water line in the
interstellar medium of six nearby starburst galaxies. We used the Odin
satellite to observe the 1_10-1_01 transition of o-H2O in ...the galaxies NGC253,
IC342, M82, NGC4258, CenA, and M51. None of the galaxies in our sample was
detected. We derive three sigma upper limits to the H2O abundance relative to
H2 ranging from 2e-9 to 1e-8. The best of these upper limits are comparable to
the measured abundance of H$_2$O in the Galactic star forming region W3.
However, if only 10% of the molecular gas is in very dense cores, then the
water abundance limits in the cores themselves would be larger by a factor of
10 i.e. 2e-8 to 1e-7. These observations suggest that detections of H2O
emission in galaxies with the upcoming Herschel Space Observatory are likely to
require on-source integration times of an hour or more except in the very
brightest extragalactic targets such as M82 and NGC253.