Molecular electronics Cuevas, Juan Carlos; Scheer, Elke
2010., 2010, 2010-06-23
eBook
This book provides a comprehensive overview of the rapidly developing field of molecular electronics. It focuses on our present understanding of the electrical conduction in single-molecule circuits ...and provides a thorough introduction to the experimental techniques and theoretical concepts. It will also constitute as the first textbook-like introduction to both the experiment and theory of electronic transport through single atoms and molecules. In this sense, this publication will prove invaluable to both researchers and students interested in the field of nanoelectronics and nanoscience in general.
Single layer graphite, known as graphene, is an important material because of its unique two-dimensional structure, high conductivity, excellent electron mobility and high surface area. To explore ...the more prospective properties of graphene, graphene hybrids have been synthesised, where graphene has been integrated with other important nanoparticles (NPs). These graphene-NP hybrid structures are particularly interesting because after hybridisation they not only display the individual properties of graphene and the NPs, but also they exhibit further synergistic properties. Reduced graphene oxide (rGO), a graphene-like material, can be easily prepared by reduction of graphene oxide (GO) and therefore offers the possibility to fabricate a large variety of graphene-transition metal oxide (TMO) NP hybrids. These hybrid materials are promising alternatives to reduce the drawbacks of using only TMO NPs in various applications, such as anode materials in lithium ion batteries (LIBs), sensors, photocatalysts, removal of organic pollutants, etc. Recent studies have shown that a single graphene sheet (GS) has extraordinary electronic transport properties. One possible route to connecting those properties for application in electronics would be to prepare graphene-wrapped TMO NPs. In this critical review, we discuss the development of graphene-TMO hybrids with the detailed account of their synthesis. In addition, attention is given to the wide range of applications. This review covers the details of graphene-TMO hybrid materials and ends with a summary where an outlook on future perspectives to improve the properties of the hybrid materials in view of applications are outlined.
More than a decade after the first report of single-molecule conductance, it remains a challenging goal to prove the exact nature of the transport through single molecules, including the number of ...transport channels and the origin of these channels from a molecular orbital point of view. We demonstrate for the archetypical organic molecule, benzenedithiol (BDT), incorporated into a mechanically controllable break junction at low temperature, how this information can be deduced from studies of the elastic and inelastic current contributions. We are able to tune the molecular conformation and thus the transport properties by displacing the nanogap electrodes. We observe stable contacts with low conductance in the order of 10–3 conductance quanta as well as with high conductance values above ∼0.5 quanta. Our observations show unambiguously that the conductance of BDT is carried by a single transport channel provided by the same molecular level, which is coupled to the metallic electrodes, through the whole conductance range. This makes BDT particularly interesting for applications as a broad range coherent molecular conductor with tunable conductance.
Organic radicals are promising building blocks for molecular spintronics. Little is known about the role of unpaired electrons for electron transport at the single-molecule level. Here, we examine ...the impact of magnetic fields on electron transport in single oligo(p-phenyleneethynylene) (OPE)-based radical molecular junctions, which are formed with a mechanically controllable break-junction technique at a low temperature of 4.2 K. Surprisingly huge positive magnetoresistances (MRs) of 16 to 287% are visible for a magnetic field of 4 T, and the values are at least 1 order of magnitude larger than those of the analogous pristine OPE (2–4%). Rigorous analysis of the MR and of current–voltage and inelastic electron-tunneling spectroscopy measurements reveal an effective reduction of the electronic coupling between the current-carrying molecular orbital and the electrodes with increasing magnetic field. We suggest that the large MR for the single-radical molecular junctions might be ascribed to a loss of phase coherence of the charge carriers induced by the magnetic field. Although further investigations are required to reveal the mechanism underlying the strong MR, our findings provide a potential approach for tuning charge transport in metal-molecule junctions with organic radicals.
A combined experimental and theoretical study is presented revealing the influence of metal–molecule coupling on electronic transport through single‐molecule junctions. Transport experiments through ...tolane molecules attached to gold electrodes via thiol, nitro, and cyano anchoring groups are performed. By fitting the experimental current–voltage characteristics to a single‐level tunneling model, we extract both the position of the molecular orbital closest to the Fermi energy and the strength of the metal–molecule coupling. The values found for these parameters are rationalized with the help of density‐functional‐theory‐based transport calculations. In particular, these calculations show that the anchoring groups determine the junction conductance by controlling not only the strength of the coupling to the metal but also the position of the relevant molecular energy levels.
Attaching molecules to metallic electrodes in order to establish a reliable electrical contact is still an open task in the field of molecular electronics. By inspection of the current–voltage characteristics and comparison to theoretical model descriptions, insight is gained into the role of the anchoring groups in the electrical properties of the molecules.
We present a novel method combining anodic aluminum oxide template synthesis and nanolithography to selectively deposit vertically patterned magnetic nanowires on a Si substrate. With this approach ...we fabricated three-dimensional nanowire-based spin valve devices without the need of complex etching processes or additional spacer coating. Through this method, we successfully obtained NiCu/Cu multilayered nanowire arrays with a controlled sequence along the long axis of the nanowires. Both magnetic switching and excitation phenomena driven by spin-polarized currents were clearly demonstrated in our NiCu/Cu multilayered nanowires. Moreover, the critical currents for switching and excitation were observed to be modulated in an oscillatory manner by the magnetic field in the nanowire-based devices. We present a toy model to qualitatively explain these observations.
We report on the experimental analysis of the charge transport through single-molecule junctions of the open and closed isomers of photoswitching molecules. Sulfur-free diarylethene molecules are ...developed and studied via electrical and optical measurements as well as density functional theory calculations. The single-molecule conductance and the current–voltage characteristics are measured in a mechanically controlled break-junction system at low temperatures. Comparing the results with the single-level transport model, we find an unexpected behavior of the current-dominating molecular orbital upon isomerization. We show that both the side chains and end groups of the molecules are crucial to understand the charge transport mechanism of photoswitching molecular junctions.
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