Oil drilling fluids require additives to control and regulate their rheological properties. For water-based mud, many components such as polymers are introduced to respond to specific functions. In ...this work, starches extracted from potatoes and corn, were proposed as a filtration controller and their effects on the rheological properties of Algerian Na-Bentonite are examined. The potato and corn starches were fabricated by adopting an easy, eco-friendly, and cost-effective route (peeling, mixing, filtration and drying) for potatoes and (soaking, crushing, filtration and drying) for corn kernels. A comparative study of the rheological properties included apparent viscosity, plastic viscosity, yield point and gel strength. The measurements were performed in the presence of caustic soda and potassium chloride while varying the concentration for both starches (0.6, 1.2, and 2.0%) and potassium chloride (1.5, 3.0, and 4.5%). From the obtained results, both potato and corn starches enhanced the rheological properties meanwhile reduced the fluid loss and the filter cake thickness by an average of (20.66% and 26.66%) and (6.33% and 17.77%), respectively in basic/saline media drilling fluid formulations. This research demonstrates that bio-starches stand as a potential alternative additives for the enhancement of rheological and filtration properties in water-based drilling fluids.
Drilling fluid systems have seen the addition of new natural additives in recent years in order to replace traditional additives, improve their rheological properties, and ensure the functionality of ...the drilling fluid taking into account health and environmental factors. This paper aims to study and compare the effect of the addition of eggshell powder (ESP) as a native and local additive and calcium carbonate (CC) as a traditional and conventional additive on the rheological and filtration properties of the drilling fluid system based on Na-bentonite of the region of Meghnia (Algeria). The test results of 10, 20, and 30 g of CCwerecompared to the same concentrations of ESP.The findings showed that the CC with various concentrations (10, 20, and 30 g) increases the rheological properties and the mud density while it reduces the filter cake and the fluid loss values which are desirable, calcium carbonate had aslightly higher effect on the pH. The obtained results following the addition of ESP with different ratios revealed that the latter has a considerable impact on the plastic viscosity, the yield point, the gel strength, and the cake thickness. Additionally, the effect of the presence of eggshell as an additive in pH, fluid loss, and mud density was studied; we observed a slight increase in the pH, while the fluid loss values decreased. However, the mud density values increased. Beyond 20 g of eggshell, the properties of the mud becomeundesirable. Moreover, this study contributes tonewfindings and suggests that the utilization of waste food and local goods in drilling mud mixtures has a bright future respecting the percentages of use.
In this research, amphiphilic derivatives of kappa carrageenan (KC) were synthesized by hydrophobic modification with an alkyl halide (1-Octyl chloride). Three hydrophobic polymers with different ...degrees of substitution (DS) were obtained by the Williamson etherification reaction in an alkaline medium. The effect of the molar ratio (R = reagent/polymer) on the DS was investigated at different ratios (1, 2, and 3). The KC derivatives (KCRs) were characterized by different techniques such as FT-IR, 1H-NMR, X-ray Diffraction, Scanning electron microscopy, and a rheological assessment. The FT-IR and 1HNMR analyses confirmed the binding of the hydrophobic groups onto the KC molecule. The degrees of substitution calculated by 1H-NMR demonstrated that the derivative KCR3 (0.68) presented a higher degree of substitution compared to KCR1(0.45) and KCR2 (0.53). The XRD and SEM analyses revealed that the alkaline etherification conditions did not alter the morphological and crystallographic properties, as well as the rheological behavior of the obtained derivatives. The amphiphilic character of the KCRs was investigated using a conductivity method which revealed that the molecular aggregation occurred above the critical aggregation concentration (CAC). Decreasing CAC values of 0.15% (KCR1), 0.11% (KCR2) and 0.08% (KCR3)with the degree of substitution (DS) were found. Furthermore, KCR’s derivatives greatly improved the stability of oil/water emulsions as the droplet size decreased with increasing DS. The derivative (KCR3) with higher DS, showed a greater amphiphilic character, and improved emulsifying power.
Nowadays, the use of eco-friendly additives in drilling fluids to improve rheological properties is widespread. This work aims to examine and assess the rheological characteristics and fluid loss of ...drilling fluid suspensions containing Algerian Na-Bentonite (NaB) and potato starch (PS) as viscosifier upon the addition of grass powder (GP). The obtained results indicate that the aging tests applied on different drilling fluid suspensions during 192 h at (20 °C) reduce the values of apparent viscosity by an average of (14.3%), plastic viscosity (22.2%), yield point (6.7%), and shear stress (47.3%) when varying the (PS) concentration in the suspensions (0.6, 1.2, 2%) as well as the values of fluid loss (9.5%); meanwhile, the values of initial and final gel strength are increased (32.6% and 19.6%, respectively). Subsequently, the possibility to further improve the rheological properties of drilling fluid suspensions using an environment eco-friendly additive (GP) has been studied. The introduction of (3, 6, 9 g) GP in the aged suspensions increases the values of rheological properties, i.e., the highest efficiency of 18.4% has been achieved by adding 9 g of GP to 2% (PS) aged suspension. The fluid loss test indicates that increasing the (GP) concentration in the (NaB+PS) suspension reduces the fluid loss volume by 36.42%. This study demonstrates the synergy of combining cost-effective GP to (NaB+PS) in aged drilling fluids by enhancing significantly its rheological properties besides a better environmental protection.
Monitoring stations have been established to combat water pollution, improve the ecosystem, promote human health, and facilitate drinking water production. However, continuous and extensive ...monitoring of water is costly and time-consuming, resulting in limited datasets and hindering water management research. This study focuses on developing an optimized K-nearest neighbor (KNN) model using the improved grey wolf optimization (I-GWO) algorithm to predict dry residue quantities. The model incorporates 20 physical and chemical parameters derived from a dataset of 400 samples. Cross-validation is employed to assess model performance, optimize parameters, and mitigate the risk of overfitting. Four folds are created, and each fold is optimized using 11 distance metrics and their corresponding weighting functions to determine the best model configuration. Among the evaluated models, the Jaccard distance metric with inverse squared weighting function consistently demonstrates the best performance in terms of statistical errors and coefficients for each fold. By averaging predictions from the models in the four folds, an estimation of the overall model performance is obtained. The resulting model exhibits high efficiency, with remarkably low errors reflected in the values of R, R2, R2ADJ, RMSE, and EPM, which are reported as 0.9979, 0.9958, 0.9956, 41.2639, and 3.1061, respectively. This study reveals a compelling non-linear correlation between physico-chemical water attributes and the content of dry tailings, indicating the ability to accurately predict dry tailing quantities. By employing the proposed methodology to enhance water quality models, it becomes possible to overcome limitations in water quality management and significantly improve the precision of predictions regarding critical water parameters.
Safeguarding drinking water is a major public health and environmental concern because it is essential to human life but may contain pollutants that can cause illness or harm the environment. ...Therefore, continuous research is necessary to improve water treatment methods and guarantee its quality. As part of this study, the effectiveness of coagulation–flocculation treatment using aluminum sulfate (Al2(SO4)3) was evaluated on a very polluted site. Samplings were taken almost every day for a month from the polluted site, and the samples were characterized by several physicochemical properties, such as hydrogen potential (pH), electrical conductivity, turbidity, organic matter, ammonium (NH+4), phosphate (PO43−), nitrate (NO3−), nitrite (NO2−), calcium (Ca2+), magnesium (Mg2+), total hardness (TH), chloride (Cl−), bicarbonate (HCO3−), sulfate (SO42−), iron (Fe3+), manganese (Mn2+), aluminum (Al3+), potassium (K+), sodium (Na+), complete alkalimetric titration (TAC), and dry residue (DR). Then, these samples were treated with Al2(SO4)3 using the jar test method, which is a common method to determine the optimal amount of coagulant to add to the water based on its physicochemical characteristics. A mathematical model had been previously created using the support vector machine method to predict the dose of coagulant according to the parameters of temperature, pH, TAC, conductivity, and turbidity. This Al2(SO4)3 treatment step was repeated at the end of each month for a year, and a second characterization of the physicochemical parameters was carried out in order to compare them with those of the raw water. The results showed a very effective elimination of the various pollutions, with a very high rate, thus demonstrating the effectiveness of the Al2(SO4)3. The physicochemical parameters measured after the treatment showed a significant reduction in the majority of the physicochemical parameters. These results demonstrated that the coagulation–flocculation treatment with Al2(SO4)3 was very effective in eliminating the various pollutions present in the raw water. They also stress the importance of continued research in the field of water treatment to improve the quality of drinking water and protect public health and the environment.
Water-soluble polymers are becoming increasingly important in various applications, such as stabilizer fluids and drilling muds. These materials are used as viscosifiers and filtration control ...agents, flocculants, and deflocculants due to their superior properties in increasing viscosity and gelling ability in the presence of crosslinkers. In general, studying the rheological behavior of drilling fluids is of paramount importance to ensure successful well drilling operations. Partially hydrolyzed polyacrylamide is one of the polymers widely used in water-based muds. The main objective of this study is to optimize the rheological properties of drilling muds through a characterization study of various parameters, including rheological behavior, viscosity, temperature (23 °C, 40 °C, and 60 °C), salinity using KCl and NaCl contents, aging, pH, solubility, and structural analysis using infrared of partially hydrolyzed polyacrylamide. The study aims to demonstrate the importance of using polymers in drilling muds. The findings revealed that a rate of 3% of HPAM gave better rheological behavior, the influence of KCl (1.5%, 3%, and 4.5%) was greater than that of NaCl (1.5%, 3%, and 4.5%) on polymers, and the aging test showed that the different formulations are stable and maintain their behavior up to 110 °C. The solubility test results confirmed the maximum amount absorbed by polyacrylamide (CHPAM = 66.42 g/L) in order to avoid aggregation, gelification, and enhance the drilling mud by utilizing the prescribed contents.
Environmental protection is becoming a primary objective when choosing processes and technologies for treating oily waters resulting from hydrocarbon production. The focus of treating oily waters is ...to eliminate contaminants from effluents before discharging them into the receiving environment while adhering to discharge standards. Our work aims to analyze the treatment process for oily waters in the API unit of the North Industrial Center (CINA), which involves a physical–chemical treatment using activated silica and Kurifix. The study aims to improve the treatment process used for oily water treatment to ensure water conservation for reuse. To enhance the CINA-HMD oily water treatment process, we created coagulants with different doses (C1–C6) using sodium silicate, activated silicate (sodium silicate + sulfuric acid), distilled water, Kurifix, and an oxygen scavenger while measuring pH, HC (hydrocarbon), and SS (suspended solids) levels. Coagulation and flocculation processes were used to remove suspended solids and hydrocarbons from the water. The results show that the coagulant used reduces suspended matter and hydrocarbon content and increases pH. The best treatment is achieved with a coagulant prepared with distilled water, 5% sodium silicate, and 2% sulfuric acid. The optimal dose of coagulant is 16 ppm. Automatic dosing provides better efficiency than manual dosing. The study recommends continuous verification of chemical preparation and injection, periodic cleaning of settling tanks, and monitoring of oily water entering the station.
The “excess salt replication process” is a new simple method of fabrication of open-cell metal foam based on the commonly known salt replication method. Porous materials with porosity between 46% and ...66% result when the employed alloy is 25% antimonial lead alloy and when it is 58% to 65% zamak 5. These foams are proposed as structured catalysts instead of packed beds in the treatment of wastewater. The local regimes influencing macroscopic air flow behaviour through these foams are delimited and boundaries are analysed in terms of sample length. Most of the experimental tests in this work exhibited a general trend of air flow in ESR foams dominated by the “strong inertia regime”. It was established that the law governing the unidirectional air flow through these foams was the full cubic law. The permeability and inertia coefficient of five samples with a cell diameter between 2.5 and 4.5 mm were calculated, and an empirical correlation was fitted. The irregular cuboid shape of salt grains used in the ESR foam was the origin of the special cell form of ESR foams leading to an anisotropic ordered porous media. This can explain the macroscopic turbulence of air flow because there were many dead zones present in the corner of each cubic cell, thus causing kinetic energy loss starting at earlier regimes.
Four distinct types of multiple emulsions were synthesized using xanthan gum and pectin through two distinct manufacturing processes. The assessment encompassed the examination of morphology, ...stability, and rheological properties for the resulting water-in-oil-in-water (W/O/W) double emulsions. Formulations were meticulously crafted with emulsifiers that were compatible with varying compositions. Remarkably stable multiple emulsions were achieved with a 0.5 wt% xanthan concentration, demonstrating resilience for nearly two months across diverse storage temperatures. In contrast, multiple emulsions formulated with a higher pectin concentration (2.75 wt%) exhibited instability within a mere three days. All multiple emulsions displayed shear-thinning behavior, characterized by a decline in apparent viscosity with escalating shear rates. Comparatively, multiple emulsions incorporating xanthan gum showcased elevated viscosity at low shear rates in contrast to those formulated with pectin. These results underscore the pivotal role of the stepwise process over the direct approach and emphasize the direct correlation between biopolymer concentration and emulsion stability. This present investigation demonstrated the potential use of pectin and xanthan gum as stabilizers of multiple emulsions with potential application in the pharmaceutical industry for the formulation of topical dosage forms.
