Recent developments in optimization theory have extended some traditional algorithms for least-squares optimization of real-valued functions (Gauss–Newton, Levenberg–Marquardt, etc.) into the domain ...of complex functions of a complex variable. This employs a formalism called the Wirtinger derivative, and derives a full-complex Jacobian counterpart to the conventional real Jacobian. We apply these developments to the problem of radio interferometric gain calibration, and show how the general complex Jacobian formalism, when combined with conventional optimization approaches, yields a whole new family of calibration algorithms, including those for the polarized and direction-dependent gain regime. We further extend the Wirtinger calculus to an operator-based matrix calculus for describing the polarized calibration regime. Using approximate matrix inversion results in computationally efficient implementations; we show that some recently proposed calibration algorithms such as StefCal and peeling can be understood as special cases of this, and place them in the context of the general formalism. Finally, we present an implementation and some applied results of CohJones, another specialized direction-dependent calibration algorithm derived from the formalism.
Abstract
We describe a new multiscale deconvolution algorithm that can also be used in a multifrequency mode. The algorithm only affects the minor clean loop. In single-frequency mode, the minor loop ...of our improved multiscale algorithm is over an order of magnitude faster than the casa multiscale algorithm, and produces results of similar quality. For multifrequency deconvolution, a technique named joined-channel cleaning is used. In this mode, the minor loop of our algorithm is two to three orders of magnitude faster than casa msmfs. We extend the multiscale mode with automated scale-dependent masking, which allows structures to be cleaned below the noise. We describe a new scale-bias function for use in multiscale cleaning. We test a second deconvolution method that is a variant of the moresane deconvolution technique, and uses a convex optimization technique with isotropic undecimated wavelets as dictionary. On simple well-calibrated data, the convex optimization algorithm produces visually more representative models. On complex or imperfect data, the convex optimization algorithm has stability issues.
Neutrino geophysics, the study of the Earth’s interior by measuring the fluxes of geologically produced neutrino at its surface, is a new interdisciplinary field of science, rapidly developing as a ...synergy between geology, geophysics and particle physics. Geoneutrinos, antineutrinos from long-lived natural isotopes responsible for the radiogenic heat flux, provide valuable information for the chemical composition models of the Earth. The calculations of the expected geoneutrino signal are discussed, together with experimental aspects of geoneutrino detection, including the description of possible backgrounds and methods for their suppression. At present, only two detectors, Borexino and KamLAND, have reached sensitivity to the geoneutrino. The experiments accumulated a set of ∼190 geoneutrino events and continue the data acquisition. The detailed description of the experiments, their results on geoneutrino detection, and impact on geophysics are presented. The start of operation of other detectors sensitive to geoneutrinos is planned for the near future: the SNO+ detector is being filled with liquid scintillator, and the biggest ever 20 kt JUNO detector is under construction. A review of the physics potential of these experiments with respect to the geoneutrino studies, along with other proposals, is presented. New ideas and methods for geoneutrino detection are reviewed.
The new generation of radio interferometers is characterized by high sensitivity, wide fields of view and large fractional bandwidth. To synthesize the deepest images enabled by the high dynamic ...range of these instruments requires us to take into account the direction-dependent Jones matrices, while estimating the spectral properties of the sky in the imaging and deconvolution algorithms. In this paper we discuss and implement a wideband wide-field spectral deconvolution framework (ddfacet) based on image plane faceting, that takes into account generic direction-dependent effects. Specifically, we present a wide-field co-planar faceting scheme, and discuss the various effects that need to be taken into account to solve for the deconvolution problem (image plane normalization, position-dependent Point Spread Function, etc). We discuss two wideband spectral deconvolution algorithms based on hybrid matching pursuit and sub-space optimisation respectively. A few interesting technical features incorporated in our imager are discussed, including baseline dependent averaging, which has the effect of improving computing efficiency. The version of ddfacet presented here can account for any externally defined Jones matrices and/or beam patterns.
We present new 0.6-10 GHz observations of the binary neutron star merger GW170817 covering the period up to 300 days post-merger, taken with the upgraded Karl G. Jansky Very Large Array, the ...Australia Telescope Compact Array, the Giant Metrewave Radio Telescope and the MeerKAT telescope. We use these data to precisely characterize the decay phase of the late-time radio light curve. We find that the temporal decay is consistent with a power-law slope of t−2.2, and that the transition between the power-law rise and decay is relatively sharp. Such a slope cannot be produced by a quasi-isotropic (cocoon-dominated) outflow, but is instead the classic signature of a relativistic jet. This provides strong observational evidence that GW170817 produced a successful jet, and directly demonstrates the link between binary neutron star mergers and short-hard gamma-ray bursts. Using simple analytical arguments, we derive constraints on the geometry and the jet opening angle of GW170817. These results are consistent with those from our companion very long baseline interferometry paper, reporting superluminal motion in GW170817.
Trapping of Difluorocarbene by Frustrated Lewis Pairs Smirnov, Vladimir O.; Volodin, Alexander D.; Korlyukov, Alexander A. ...
Angewandte Chemie International Edition,
July 20, 2020, Letnik:
59, Številka:
30
Journal Article
Recenzirano
Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to ...release difluorocarbene at elevated temperatures.
Difluorocarbene is reversibly trapped by intramolecular frustrated Lewis pairs. The reaction proceeds stepwise via interaction of the carbene with the phosphorus atom followed by formation of the carbon‐boron bond.
Currently, in nonlinear optics, models associated with various types of the nonlinear Schrödinger equation (scalar (NLS), vector (VNLS), derivative (DNLS)), as well as with higher and mixed equations ...from the corresponding hierarchies are usually studied. Typical tools for solving the problem of propagation of optical nonlinear waves are the forward and inverse nonlinear Fourier transforms. One of the methods for reconstructing a periodic nonlinear signal is based on the use of spectral data in the form of spectral curves. In this paper, we study the properties of the spectral curves for all the derivatives NLS equations simultaneously. For all the main DNLS equations (DNLSI, DNLSII, DNLSIII), we have obtained unified Lax pairs, unified hierarchies of evolutionary and stationary equations, as well as unified equations of spectral curves of multiphase solutions. It is shown that stationary and evolutionary equations have symmetries, the presence of which leads to the existence of holomorphic involutions on spectral curves. Because of this symmetry, spectral curves of genus g are covers over other curves of genus M and N=g−M, where M is a number of phase of solutions. We also showed that the number of the genus g of the spectral curve is related to the number of phases M of the solution of one of the two formulas: g=2M or g=2M+1. The third section provides examples of the simplest solutions.
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