Rapid warming over the past 50 years on the Antarctic Peninsula is associated with the collapse of a number of ice shelves and accelerating glacier mass loss. In contrast, warming has been ...comparatively modest over West Antarctica and significant changes have not been observed over most of East Antarctica, suggesting that the ice-core palaeoclimate records available from these areas may not be representative of the climate history of the Antarctic Peninsula. Here we show that the Antarctic Peninsula experienced an early-Holocene warm period followed by stable temperatures, from about 9,200 to 2,500 years ago, that were similar to modern-day levels. Our temperature estimates are based on an ice-core record of deuterium variations from James Ross Island, off the northeastern tip of the Antarctic Peninsula. We find that the late-Holocene development of ice shelves near James Ross Island was coincident with pronounced cooling from 2,500 to 600 years ago. This cooling was part of a millennial-scale climate excursion with opposing anomalies on the eastern and western sides of the Antarctic Peninsula. Although warming of the northeastern Antarctic Peninsula began around 600 years ago, the high rate of warming over the past century is unusual (but not unprecedented) in the context of natural climate variability over the past two millennia. The connection shown here between past temperature and ice-shelf stability suggests that warming for several centuries rendered ice shelves on the northeastern Antarctic Peninsula vulnerable to collapse. Continued warming to temperatures that now exceed the stable conditions of most of the Holocene epoch is likely to cause ice-shelf instability to encroach farther southward along the Antarctic Peninsula.
•Real-time monitoring of CO2 release.•Measurements of water column pH and pCO2 via towed Video-CTD system.•Assessment of towed sensors capacity to detect potential CO2 leakage in the water ...column.•Estimation of thresholds for the detection of anomalous pCO2.
Within the framework of the STEMM-CCS project, a controlled CO2 release experiment was conducted under real-life conditions in the Goldeneye complex area, a depleted gas field located in the UK sector of the North Sea. Here, the viability of water column monitoring for the detection of the injected CO2 is evaluated. Real-time pH and pCO2 measurements were taken in the water column during the CO2 release experiment. Monitoring was carried out throughout the full water column, from the near-seafloor to the sea surface, in order to assess the spatial extent of the CO2 release. The dispersion of the CO2 plume was strongly influenced by tidal circulation in the area. The strongest signals were detected within 8 m of the bubble stream during low tide. The lowest pH and highest pCO2 values were 7.965 and 942.1 µatm, respectively, corresponding to variations of 16.4% H+ and 125.6% from baseline values. The pCO2 baseline dynamics of Goldeneye area were assessed by the evaluation of the natural pCO2-O2 covariance. The estimation of seasonal thresholds for anomalous pCO2 (pCO2:O2 ratio May= 1.63 ± 0.04) allowed us to assess with confidence the non-biological origin of the detected CO2 during the release experiment.
Abstract
Following on from the successful project to recover an ice core to bedrock on Berkner Island, similar drilling equipment and logistics were used on two further projects to recover ice cores ...to bedrock in the Antarctic Peninsula. At James Ross Island, a ship- and helicopter-supported project drilled to bedrock at 363 m depth in a single season, while a Twin Otter-supported project drilled to bedrock at 654m depth, again in a single season, from Fletcher Promontory. In both new projects, drilling was from the surface, with the infrastructure enclosed in a tent, using an uncased, partially fluid-filled, borehole.
The partial pressure of carbon dioxide (pCO2) in surface seawater is an important biogeochemical variable because, together with the pCO2 in the atmosphere, it determines the direction of air–sea ...carbon dioxide exchange. Large‐scale observations of pCO2 are facilitated by Ships‐of‐Opportunity (SOOP‐CO2) equipped with underway measuring instruments. The need for expanding the observation capacity and the challenges involving the sustainability and maintenance of traditional equilibrator systems led the community toward developing simpler and more autonomous systems. Here we performed a comparison between a membrane‐based sensor and a showerhead equilibration sensor installed on two SOOP‐CO2 between 2013 and 2018. We identified time‐ and space‐adequate crossovers in the Skagerrak Strait, where the two ship routes often crossed. We found a mean total difference of 1.5 ± 10.6 μatm and a root mean square error of 11 μatm. The pCO2 values recorded by the two instruments showed a strong linear correlation with a coefficient of 0.91 and a slope of 1.07 (± 0.14), despite the dynamic nature of the environment and the difficulty of comparing measurements from two different vessels. The membrane‐based sensor was integrated with a FerryBox system on a ship with a high sampling frequency in the study area. We showed the strength of having a sensor‐based network with a high spatial coverage that can be validated against conventional SOOP‐CO2 methods. Proving the validity of membrane‐based sensors in coastal and continental shelf seas and using the higher frequency measurements they provide can enable a thorough characterization of pCO2 variability in these dynamic environments.
Abstract
The partial pressure of carbon dioxide (
p
CO
2
) in surface seawater is an important biogeochemical variable because, together with the
p
CO
2
in the atmosphere, it determines the direction ...of air–sea carbon dioxide exchange. Large‐scale observations of
p
CO
2
are facilitated by Ships‐of‐Opportunity (SOOP‐CO
2
) equipped with underway measuring instruments. The need for expanding the observation capacity and the challenges involving the sustainability and maintenance of traditional equilibrator systems led the community toward developing simpler and more autonomous systems. Here we performed a comparison between a membrane‐based sensor and a showerhead equilibration sensor installed on two SOOP‐CO
2
between 2013 and 2018. We identified time‐ and space‐adequate crossovers in the Skagerrak Strait, where the two ship routes often crossed. We found a mean total difference of 1.5 ± 10.6
μ
atm and a root mean square error of 11
μ
atm. The
p
CO
2
values recorded by the two instruments showed a strong linear correlation with a coefficient of 0.91 and a slope of 1.07 (± 0.14), despite the dynamic nature of the environment and the difficulty of comparing measurements from two different vessels. The membrane‐based sensor was integrated with a FerryBox system on a ship with a high sampling frequency in the study area. We showed the strength of having a sensor‐based network with a high spatial coverage that can be validated against conventional SOOP‐CO
2
methods. Proving the validity of membrane‐based sensors in coastal and continental shelf seas and using the higher frequency measurements they provide can enable a thorough characterization of
p
CO
2
variability in these dynamic environments.
We present a novel instrument, the Sub-Ocean probe, allowing in situ and continuous measurements of dissolved methane in seawater. It relies on an optical feedback cavity enhanced absorption ...technique designed for trace gas measurements and coupled to a patent-pending sample extraction method. The considerable advantage of the instrument compared with existing ones lies in its fast response time of the order of 30 s, that makes this probe ideal for fast and continuous 3D-mapping of dissolved methane in water. It could work up to 40 MPa of external pressure, and it provides a large dynamic range, from subnmol of CH4 per liter of seawater to mmol L–1. In this work, we present laboratory calibration of the instrument, intercomparison with standard method and field results on methane detection. The good agreement with the headspace equilibration technique followed by gas-chromatography analysis supports the utility and accuracy of the instrument. A continuous 620-m depth vertical profile in the Mediterranean Sea was obtained within only 10 min, and it indicates background dissolved CH4 values between 1 and 2 nmol L–1 below the pycnocline, similar to previous observations conducted in different ocean settings. It also reveals a methane maximum at around 6 m of depth, that may reflect local production from bacterial transformation of dissolved organic matter.
Abstract
The British Antarctic Survey, in collaboration with Laboratoire de Glaciologie et Géophysique de l’Environnement, has in recent years successfully drilled to bedrock on three remote sites ...around the Antarctic Peninsula. Based on the experience from the multi-season project at Berkner Island (948m depth, 2002–05) we optimized the drill set-up to better suit two subsequent single-season projects at James Ross Island (363m depth, 2008) and Fletcher Promontory (654m depth, 2012). The adaptations, as well as the reasons for them, are discussed in detail and include a drill tent set-up without a trench; drilling without a borehole casing with a relatively low fluid column height; and using a shorter drill. These optimizations were aimed at reducing cargo loads and installation time while maintaining good core quality, productivity and a safe working environment. In addition, we introduce a number of innovations, ranging from a new lightweight cable tensioning device and drill-head design to core storage and protection trays. To minimize the environmental impact, all the drill fluid was successfully recovered at both sites and we describe and evaluate this operation.
According to many prognostic scenarios by the Intergovernmental Panel on Climate Change (IPCC), a scaling-up of carbon dioxide (CO2) capture and storage (CCS) by several orders-of-magnitude is ...necessary to meet the target of ≤2 °C global warming by 2100 relative to preindustrial levels. Since a large fraction of the predicted CO2 storage capacity lies offshore, there is a pressing need to develop field-tested methods to detect and quantify potential leaks in the marine environment. Here, we combine field measurements with numerical models to determine the flow rate of a controlled release of CO2 in a shallow marine setting at about 119 m water depth in the North Sea. In this experiment, CO2 was injected into the sediment at 3 m depth at 143 kg d-1. The new leakage monitoring tool predicts that 91 kg d-1 of CO2 escaped across the seafloor, and that 51 kg d-1 of CO2 were retained in the sediment, in agreement with independent field estimates. The new approach relies mostly on field data collected from ship-deployed technology (towed sensors, Acoustic Doppler current profiler—ADCP), which makes it a promising tool to monitor existing and upcoming offshore CO2 storage sites and to detect and quantify potential CO2 leakage.
•Combination of towed sensors and numerical simulations quantified the CO2 leakage.•64% of CO2 injected at 3-m depth in the sediment leaked into bottom water.•Gas-phase measurements of chemical tracers validated the bubble dissolution model.
Methane (CH4) in marine sediments has the potential to contribute to changes in the ocean and climate system. Physical and biochemical processes that are difficult to quantify with current standard ...methods such as acoustic surveys and discrete sampling govern the distribution of dissolved CH4 in oceans and lakes. Detailed observations of aquatic CH4 concentrations are required for a better understanding of CH4 dynamics in the water column, how it can affect lake and ocean acidification, the chemosynthetic ecosystem, and mixing ratios of atmospheric climate gases. Here we present pioneering high-resolution in situ measurements of dissolved CH4 throughout the water column over a 400 m deep CH4 seepage area at the continental slope west of Svalbard. A new fast-response underwater membrane-inlet laser spectrometer sensor demonstrates technological advances and breakthroughs for ocean measurements. We reveal decametre-scale variations in dissolved CH4 concentrations over the CH4 seepage zone. Previous studies could not resolve such heterogeneity in the area, assumed a smoother distribution, and therefore lacked both details on and insights into ongoing processes. We show good repeatability of the instrument measurements, which are also in agreement with discrete sampling. New numerical models, based on acoustically evidenced free gas emissions from the seafloor, support the observed heterogeneity and CH4 inventory. We identified sources of CH4, undetectable with echo sounder, and rapid diffusion of dissolved CH4 away from the sources. Results from the continuous ocean laser-spectrometer measurements, supported by modelling, improve our understanding of CH4 fluxes and related physical processes over Arctic CH4 degassing regions.
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