The rapid development of plastic industrials has created a variety of plastic products, causing revolutionary progress in chemistry, physics, biology, and medicine. Large-scale production and ...applications of plastics increase their possibility of entering the environment. Previous environmental impact studies typically focused on the toxicity, behavior and fate; limited attention was paid on greenhouse gas emissions and climate change. With the increase of plastic waste, the threat of plastic pollution to the earth’s climate has been gradually taken seriously. Evidence showed that greenhouse gas emissions occur at every stage of the plastic life cycle, including extraction and transportation of plastic raw materials, plastic manufacturing, waste treatment and entering the environment. The oil and gas industries used to make plastics are the main sources of greenhouse gas emissions (from the extraction of raw materials to the manufacture of plastics). Emissions of greenhouse gases during manufacture are mainly controlled by the production facilities themselves, usually depending on the efficiency, configuration and service life of equipment. Additionally, there are some unintended impacts, including transport requirements, pipeline leakage, land use, as well as impeding forests as natural carbons sinks. Recycling of plastic waste energy seems to be a good way to deal with waste plastics, but this process will release a lot of greenhouse gases. With this energy conversion occurring, the incineration of plastic packing waste will become one of the main sources of greenhouse gas emissions. Furthermore, plastics released into the environment also slowly release greenhouse gases, and the presence of (micro)plastics in the ocean will seriously interfere with the carbon fixation capacity of the ocean. In its current form, greenhouse gas emissions from cradle to grave of plastics will reach 1.34 gigatons per year by 2030 and 2.8 gigatons per year by 2050. This will seriously consume the global remaining carbon budgets, thereby threatening the ability of the global community to keep global temperatures rising by below 1.5 °C even 2 °C by 2100. In order to achieve this goal, the total global greenhouse gas emissions must be kept within the remaining carbon budget of 420–570 gigatons. The accumulative greenhouse gas emissions from cradle to grave of plastics may exceed 56 gigatons by 2050 (approximately accounting for 10%–13% of the total remaining carbon budget). As the plastic industry plans to expand production on a large scale, the problem will worsen further. The World Economic Forum forecasted that by 2030, the production and use of plastics will grow at an annual rate of 3.8%, and this growth rate will fall to 3.5% per year from 2030 to 2050. However, there are significant challenges and uncertainties in this estimation, and challenge and uncertainty factors come from all aspects. Recently, several organizations and researchers have started to discern the relationship between greenhouse gas emissions and plastic industrials, but relevant research on these impacts is still in its infancy. Consequently, the contribution of plastic pollution to greenhouse gas emissions and climate change should be given immediate attention and it needs to further explore the impact of plastic pollution on greenhouse gas emission and climate change. The implementation of measures to solve or alleviate the (micro)plastic crisis was critical necessary and proposed: (1) production control of global plastics; (2) improving the treatment and disposal of plastic waste; and (3) assessment of the impact of global environmental (micro)plastics on climate.
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•A crisis that plastic life cycle affects GHG emission and climate change is raised.•GHG emissions from cradle to grave of plastics will reach 1.34 Gt per year by 2030.•Accumulative GHG emission from cradle to grave of plastics may exceed 56 Gt by 2050.•GHG emissions from plastic life cycle seriously threaten remaining carbon budget.•Perspectives and challenges on plastic industry and policy are put forward.
•Municipal sewage sludge was pyrolyzed at various temperature.•Pyrolysis temperature influences the properties of biochar strongly.•Biochars perform better than commercial activated carbon on heavy ...metal adsorption.•The purpose of both energy recovery and heavy metal removal can achieve at 900°C.
To investigate systematically the influence of pyrolysis temperature on properties and heavy metal adsorption potential of municipal sludge biochar, biophysical dried sludge was pyrolyzed under temperature varying from 500°C to 900°C. The biochar yield decreased with the increase in pyrolysis temperature, while the ash content retained mostly, thus transforming the biochars into alkaline. The structure became porous as the temperature increased, and the concentrations of surface functional group elements remained low. Despite the comparatively high content of heavy metal in the biochar, the leaching toxicity of biochars was no more than 20% of the Chinese standard. In the batch experiments of cadmium(II) adsorption, the removal capacity of biochars improved under higher temperature, especially at 800°C and 900°C even one order of magnitude higher than that of the commercial activated carbon. For both energy recovery and heavy metal removal, the optimal pyrolysis temperature is 900°C.
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•Impact of surfactant on adsorption performance of Pb2+ on MPs was studied.•Surfactant caused a higher hydrophilicity of MPs and improved the adsorption ability of MPs for Pb2+.•SDBS ...significantly enhanced adsorption of Pb2+ on MPs compared with other two surfactants.•The presence of Cu2+ affected the adsorption behavior of PP for Pb2+.•Surfactant could promote the migration and stabilization of Pb2+ in the environment.
The impact of surfactant addition on the adsorption performance of lead ion (Pb2+) as a typical heavy metal ion on three microplastics was investigated. The types of microplastics (polyethylene (PE), polypropylene (PP) and polymethylmethacrylate (PMMA)) and surfactants (triton X-100 (TX-100), 1-hexadecylpyridinium bromide (HDPB), and sodium dodecyl benzenesulfonate (SDBS)), adsorption time, concentration of Pb2+, and coexisting ions was systematically investigated, and the characteristics of adsorption of Pb2+ by microplastics were analyzed. The experimental results showed that the adsorption capacity of Pb2+ on three micropalstics was different. The adsorption capacity of Pb2+ on the three microplastics without surfactants was: 4.21 (PMMA) > 2.01 (PE) > 1.57 mg g−1 (PP). The addition of surfactants resulted in a higher hydrophilicity of microplastics, and obviously improved the adsorption ability of microplastics for lead ions. SDBS can significantly enhance the adsorption of Pb2+ on three microplastics compared with other two surfactants (TX100 and HDPB). The highest adsorption capacity of Pb2+ on the three microplastics with addition of SDBS solution was: 7.87 (PMMA) > 7.20 (PE) > 7.02 mg g−1 (PP). With the increase of adsorption time and Pb2+ concentration, the adsorption efficiency of microplastics for Pb2+ first increased and then decreased. The pH of solution had a great influence on the adsorption of Pb2+ by microplastics. The results of coexisting ion experiments demonstrated that when lead ion and copper ion coexist, the two ions have competitive adsorption phenomenon on PP. This research explored the adsorption characteristics of lead ions by microplastics with addition of surfactants, which can provide theoretical basis for further study of heavy metal enrichment and environmental behavior of microplastics in the environment.
For the lack of precise monitoring and accurate assessment models for air quality, this paper fully considers such constraints and establishes an evaluation model of air pollution emission level to ...evaluate the air pollution emission level of Wuhan-a city in central China. The model uses entropy weight method including important indicators of air pollution into the integrated optimization of air quality assessment, laying the basis for sources of pollution and the reasonable and effective city development. The total emissions of air pollution for Wuhan shows a gradual upward trend over time, mainly coming from industrial pollution. The government can reduce air pollution by focusing on detecting major polluting industries, promoting industrial technological progress and innovation, and strengthening the effective implementation of emission trading system.
Biologics play a positive and effective role in the treatment of immune-related dermatoses. However, many other immune-related diseases have also manifested along with biologics treatment. ...Paradoxical reaction through immune-related dermatoses refer to the new onset or exacerbation of other immune-mediated dermatoses (mainly psoriasis and atopic dermatitis) after biologics treatment of inflammatory dermatoses (mainly psoriasis and atopic dermatitis), such as new atopic dermatitis (AD) in psoriasis (PsO) treatment and new PsO in AD treatment. A common genetic background and Inflammatory pathway are possible pathogenesis. Faced with paradoxical reactions, the choice of therapy needs to be directed toward therapies effective for both diseases, such as Janus kinase (JAK) inhibitors. The Janus kinase and signal transducer and activator of transcription (JAK-STAT) pathway plays an important role in the inflammatory pathway, and has been widely used in the treatment of AD and PsO in recent years. This article focuses on JAK inhibitors such as tofacitinib, baricitinib, ruxolitinib, Abrocitinib, upadacitinib, and deucravacitinib, to explore the possible application in treatment of paradoxical reactions. Common side effects, baseline risk factors and safety use of JAK inhibitors were discussed.
A survey on terahertz communications Chen, Zhi; Ma, Xinying; Zhang, Bo ...
China communications,
02/2019, Letnik:
16, Številka:
2
Journal Article
Recenzirano
With the exponential growth of the data traffic in wireless communication systems, terahertz (THz) frequency band is envisioned as a promising candidate to support ultra-broadband for future beyond ...fifth generation (5G), bridging the gap between millimeter wave (mmWave) and optical frequency ranges. The purpose of this paper is to provide a comprehensive literature review on the development towards THz communications and presents some key technologies faced in THz wireless communication systems. Firstly, despite the substantial hardware problems that have to be developed in terms of the THz solid state superheterodyne receiver, high speed THz modulators and THz antennas, the practical THz channel model and the efficient THz beamforming are also described to compensate for the severe path attenuation. Moreover, two different kinds of lab-level THz communication systems are introduced minutely, named a solid state THz communication system and a spatial direct modulation THz communication system, respectively. The solid state THz system converts intermediate frequency (IF) modulated signal to THz frequency while the direct modulation THz system allows the high power THz sources to input for approving the relatively long distance communications. Finally, we discuss several potential application scenarios as well as some vital technical challenges that will be encountered in the future THz communications.
With inherent orthogonality, both the spin angular momentum (SAM) and orbital angular momentum (OAM) of photons have been utilized to expand the dimensions of quantum information, optical ...communications, and information processing, wherein simultaneous detection of SAMs and OAMs with a single element and a single-shot measurement is highly anticipated. Here, a single azimuthal-quadratic phase metasurface-based photonic momentum transformation (PMT) is illustrated and utilized for vortex recognition. Since different vortices are converted into focusing patterns with distinct azimuthal coordinates on a transverse plane through PMT, OAMs within a large mode space can be determined through a single-shot measurement. Moreover, spin-controlled dual-functional PMTs are proposed for simultaneous SAM and OAM sorting, which is implemented by a single spin-decoupled metasurface that merges both the geometric phase and dynamic phase. Interestingly, our proposed method can detect vectorial vortices with both phase and polarization singularities, as well as superimposed vortices with a certain interval step. Experimental results obtained at several wavelengths in the visible band exhibit good agreement with the numerical modeling. With the merits of ultracompact device size, simple optical configuration, and prominent vortex recognition ability, our approach may underpin the development of integrated and high-dimensional optical and quantum systems.
Micro(nano)plastics, as emerging contaminants, have attracted worldwide attention. Nowadays, the environmental distribution, sources, and analysis methods and technologies of micro(nano)plastics have ...been well studied and recognized. Nevertheless, the role of micro(nano)plastic particles as vectors for attaching organisms is not fully understood. In this paper, the role of micro(nano)plastics as vectors, and their potential effects on the ecology are introduced. Micro(nano)plastics could 1) accelerate the diffusion of organisms in the environment, which may result in biological invasion; 2) increase the gene exchange between attached biofilm communities, causing the transfer of pathogenic and antibiotic resistance genes; 3) enhance the rate of energy, material and information flow in the environment. Accordingly, the role of microplastics as vectors for organisms should be further evaluated in the future research.
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•Questions of micro(nano)plastics as organism vectors have been raised.•Ecological effects of micro(nano)plastics as organism vectors are discussed.•Role of micro(nano)plastics as organism vectors need to be studied in future.
In recent years, solar photovoltaic power generation has emerged as an essential means of energy supply. The prediction of its active power is not only conducive to cost saving but can also promote ...the development of solar power generation industry. However, it is challenging to obtain an accurate and high-quality interval prediction of active power. Based on the data set of desert knowledge in the Australia solar center in Australia, firstly, we have compared twelve interval prediction methods based on machine learning. Secondly, six ensemble methods, namely Ensemble-Mean, Ensemble-Median (Ensemble-Med), Ensemble-Envelop (Ensemble-En), Ensemble-Probability averaging of endpoints and simple averaging of midpoints (Ensemble-PM), Ensemble-Exterior trimming (Ensemble-TE), and Ensemble-Interior trimming (Ensemble-TI) are used to combine forecast intervals. The result indicates that Ensemble-TE is the best method. Additionally, compared to other methods, Ensemble-TE ensures the prediction interval coverage probability for confidence levels of 95%, 90%, 85%, and 80% as 0.960, 0.920, 0.873, and 0.824, respectively, using 15-min level data. Meanwhile, the narrower prediction interval normalized averaged width is calculated for the same confidence levels as 0.066, 0.045, 0.035, and 0.028, respectively. In addition, higher Winkler score and smaller coverage width-based criterion are obtained, representing high-quality intervals. We have calculated smaller mean prediction interval center deviation, which is approximately 0.044. Thus, the above demonstrates that this study obtains the prediction interval with better performance compared to other existing methods.
Utilizing terahertz (THz) waves to transmit data for communication and imaging places high demands on phase modulation. However, until now, it is difficult to realize a more than 100° phase shift in ...the transmission mode with one-layer structure. In this paper, a ring-dumbbell composite resonator nested with VO2 nanostructures is proposed to achieve the large phase shift. It is found that in this structure a hybrid mode with an enhanced resonant intensity, which is coupled by the L-C resonance and dipole resonance has been observed. Applying the photoinduced phase transition characteristics of VO2, the resonant intensity of the mode can be dynamically controlled, which leads to a large phase shift in the incident THz wave. The dynamic experimental results show that controlling the power of the external laser can achieve a phase shift of up to 138° near 0.6 THz using this one-layer VO2 nested composite structure. Moreover, within a 55 GHz (575–630 GHz) bandwidth, the phase shift exceeds 130°. This attractive phase shift modulation may provide prospective applications in THz imaging, communications, and so on.
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