In vivo fluorescent monitoring of physiological processes with high‐fidelity is essential in disease diagnosis and biological research, but faces extreme challenges due to aggregation‐caused ...quenching (ACQ) and short‐wavelength fluorescence. The development of high‐performance and long‐wavelength aggregation‐induced emission (AIE) fluorophores is in high demand for precise optical bioimaging. The chromophore quinoline‐malononitrile (QM) has recently emerged as a new class of AIE building block that possesses several notable features, such as red to near‐infrared (NIR) emission, high brightness, marked photostability, and good biocompatibility. In this minireview, we summarize some recent advances of our established AIE building block of QM, focusing on the AIE mechanism, regulation of emission wavelength and morphology, the facile scale‐up and fast preparation for AIE nanoparticles, as well as potential biomedical imaging applications.
In this Minireview, recent advances related to the aggregation‐induced emission (AIE) building block quinoline‐malononitrile are summarized. It focuses on the AIE mechanism, regulation of emission wavelength and morphology, the facile scale‐up and fast preparation for AIE nanoparticles, and potential biomedical imaging applications.
Covalent organic frameworks (COFs) are distinguished from other organic polymers by their crystallinity
, but it remains challenging to obtain robust, highly crystalline COFs because the ...framework-forming reactions are poorly reversible
. More reversible chemistry can improve crystallinity
, but this typically yields COFs with poor physicochemical stability and limited application scope
. Here we report a general and scalable protocol to prepare robust, highly crystalline imine COFs, based on an unexpected framework reconstruction. In contrast to standard approaches in which monomers are initially randomly aligned, our method involves the pre-organization of monomers using a reversible and removable covalent tether, followed by confined polymerization. This reconstruction route produces reconstructed COFs with greatly enhanced crystallinity and much higher porosity by means of a simple vacuum-free synthetic procedure. The increased crystallinity in the reconstructed COFs improves charge carrier transport, leading to sacrificial photocatalytic hydrogen evolution rates of up to 27.98 mmol h
g
. This nanoconfinement-assisted reconstruction strategy is a step towards programming function in organic materials through atomistic structural control.
Abstract
We report the observations of FRB 20220912A using the Five-hundred-meter Aperture Spherical radio Telescope. We conducted 17 observations totaling 8.67 hr and detected a total of 1076 bursts ...with an event rate up to 390 hr
−1
. The cumulative energy distribution can be well described using a broken power-law function with the lower- and higher-energy slopes of −0.38 ± 0.02 and −2.07 ± 0.07, respectively. We also report the
L
-band (1–1.5 GHz) spectral index of the synthetic spectrum of FRB 20220912A bursts, which is −2.6 ± 0.21. The average rotation measure value of the bursts from FRB 20220912A is −0.08 ± 5.39 rad m
−2
, close to 0 rad m
−2
and was relatively stable over 2 months. Most bursts have nearly 100% linear polarization. About 45% of the bursts have circular polarization with Signal-to-Noise ratio > 3, and the highest circular polarization degree can reach 70%. Our observations suggest that FRB 20220912A is located in a relatively clean local environment with complex circular polarization characteristics. These various behaviors imply that the mechanism of circular polarization of FRBs likely originates from an intrinsic radiation mechanism, such as coherent curvature radiation or inverse Compton scattering inside the magnetosphere of the FRB engine source (e.g., a magnetar).
In the past few years, significant advances have been made in understanding the distributions of exoplanet populations and the architecture of planetary systems. We review the recent progress of ...planet statistics, with a focus on the inner 1-AU region of planetary systems that has been fairly thoroughly surveyed by the
Kepler
mission. We also discuss the theoretical implications of these statistical results for planet formation and dynamical evolution.
Developing dopant‐free hole transporting materials (HTMs) is of vital importance for addressing the notorious stability issue of perovskite solar cells (PSCs). However, efficient dopant‐free HTMs are ...scarce. Herein, we improve the performance of dopant‐free HTMs featuring with a quinoxaline core via rational π‐extension. Upon incorporating rotatable or chemically fixed thienyl substitutes on the pyrazine ring, the resulting molecular HTMs TQ3 and TQ4 show completely different molecular arrangement as well as charge transporting capabilities. Comparing with TQ3, the coplanar π‐extended quinoxaline based TQ4 endows enriched intermolecular interactions and stronger π–π stacking, thus achieving a higher hole mobility of 2.08×10−4 cm2 V−1 s−1. It also shows matched energy levels and high thermal stability for application in PSCs. Planar n‐i‐p structured PSCs employing dopant‐free TQ4 as HTM exhibits power conversion efficiency (PCE) over 21 % with excellent long‐term stability.
Quinoxaline derivatives, featuring with rotatable and chemically fixed thienyl substitutes, are introduced as the core for constructing dopant‐free hole transporting materials (HTMs). The coplanar π‐extended quinoxaline‐based HTM TQ4 achieves the best photovoltaic performance (exceed 21 %) among planar n‐i‐p structured dopant‐free perovskite solar cells.
Sensing of metal ions and anions is of great importance because of their widespread distribution in environmental systems and biological processes. Colorimetric and fluorescent chemosensors based on ...organic molecular species have been demonstrated to be effective for the detection of various ions and possess the significant advantages of low cost, high sensitivity, and convenient implementation. Of the available classes of organic molecules, porphyrin analogues possess inherently many advantageous features, making them suitable for the design of ion chemosensors, with the targeted sensing behavior achieved and easily modulated based on their following characteristics: (1) NH moieties properly disposed for binding of anions through cooperative hydrogen-bonding interactions; (2) multiple pyrrolic N atoms or other heteroatoms for selectively chelating metal ions; (3) variability of macrocycle size and peripheral substitution for modulation of ion selectivity and sensitivity; and (4) tunable near-infrared emission and good biocompatibility. In this Review, design strategies, sensing mechanisms, and sensing performance of ion chemosensors based on porphyrin analogues are described by use of extensive examples. Ion chemosensors based on normal porphyrins and linear oligopyrroles are also briefly described. This Review provides valuable information for researchers of related areas and thus may inspire the development of more practical and effective approaches for designing high-performance ion chemosensors based on porphyrin analogues and other relevant compounds.
Unprecedented dual aggregation‐induced emission (AIE) behavior based on a steric‐hindrance photochromic system is presented, with incorporation one or two bulky aryl groups, resulting in different ...flexibleness. The dual AIE behavior of open and closed isomers can be explained by restriction of intramolecular rotation (RIR), restriction of intramolecular vibration (RIV), and intermolecular stacking. The large bulky benzothiophene causes restricted rotation, enhancing the emission of open form in solution and weak π–π molecular packing, thereby efficiently enhancing the luminescence performance in the solid state. With incorporation of two large bulky benzothiophene groups, BBTE possesses the most outstanding AIE activity, undergoing highly efficient and reversible off‐to‐on fluorescence in film upon alternating UV and visible light irradiation along with excellent fatigue resistance. The off‐to‐on fluorescent photoswitch is successfully established in super resolution imaging.
Dual AIE behavior: The steric‐hindrance photochromic system efficiently regulates the intramolecular rotational/vibrational magnitude and intermolecular stacking to tune aggregation‐induced emission (AIE) activity. The off‐to‐on fluorescent photoswitch is successfully established in super resolution imaging.
Biosensing is of vital importance for advancing public health through monitoring abnormalities in biological systems, which may be potentially associated with certain body dysfunctions. A wide range ...of luminescent materials have been actively pursued in the fabrication of biosensing platforms, particularly ones that can function in complex biological fluids with high selectivity and sensitivity. Recently, metal-organic frameworks (MOFs) have experienced rapid growth due to their tunable structures, large surface area, and being prone to surface engineering,
etc.
These virtues endow MOF materials with immense feasibility in the target-oriented construction of sensing platforms for specific applications. In this review, we extrapolated six sensing mechanisms for MOF-based photoluminescent biosensing platforms, including photoelectron transfer (PET), resonance energy transfer (RET), competition absorption (CA), structural transformation (ST), chemical conversion (CC), and quencher detachment (QD). Accordingly, recent progress of MOF-based materials in photoluminescence sensing of biomolecules, biomarkers, drugs, and toxins was highlighted. The objective of this review is to provide readers with an extensive overview of the design and synthesis of MOF materials for photoluminescence biosensing. The challenges and outlook are briefly discussed at the end.
Recent progress of MOF-based photoluminescent platforms: a comprehensive overview of their applications in biosensing and underlying mechanisms.
This paper investigates the physical layer security of a satellite network, whose downlink spectral resource is shared with a terrestrial cellular network. We propose to employ a multi-antenna base ...station (BS) as a source of green interference to enhance secure transmission in the satellite network. By taking the mutual interference between these two networks into account, we first formulate a constrained optimization problem to maximize the instantaneous rate of the terrestrial user while satisfying the interference probability constraint of the satellite user. Then, with the assumption that imperfect channel state information (CSI) and statistical CSI of the link between the BS and satellite user are available at the BS, we present two beamforming (BF) schemes, namely, hybrid zero-forcing and partial zero-forcing to solve the optimization problem and obtain the BF weight vectors in a closed form. Moreover, we analyze the secrecy performance of primary satellite network by considering two practical scenarios, namely: Scenario I, the eavesdroppers CSI is unknown at the satellite and Scenario II, the eavesdroppers CSI is known at the satellite. Specifically, we derive the analytical expressions for the secrecy outage probability for Scenario I and the average secrecy rate for Scenario II. Finally, numerical results are provided to confirm the superiority of the proposed BF schemes and the validity of the performance analysis, as well as demonstrate the impacts of various parameters on the secrecy performance of the satellite network.
Improved Bethe-Heitler formula Zhu, Wei
Nuclear physics. B,
April 2020, 2020-04-00, 2020-04-01, Letnik:
953
Journal Article
Recenzirano
Odprti dostop
The Bethe-Heitler formula describes bremsstrahlung and it's a typical and important example in quantum electromagnetic dynamics (QED). This formula is widely applied in many branches of physics and ...astrophysics. We find that the integrated bremsstrahlung cross section at the static approximation and high energy limit has an unexpected big increment, which is missed by previous bremsstrahlung theory. This anomalous effect also exists in electron-positron pair creation. We derive the relating formulas and point out that electromagnetic cascades at the top of atmosphere can test this effect.
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