Compositional data for >400 pumice clasts, organized according to eruptive sequence, crystal content, and texture, provide new perspectives on eruption and pre-eruptive evolution of the >600 km3 of ...zoned rhyolitic magma ejected as the Bishop Tuff during formation of Long Valley caldera. Proportions and compositions of different pumice types are given for each ignimbrite package and for the intercalated plinian pumice-fall layers that erupted synchronously. Although withdrawal of the zoned magma was less systematic than previously realized, the overall sequence displays trends toward greater proportions of less evolved pumice, more crystals (0·5-24 wt %), and higher FeTi-oxide temperatures (714-818°C). No significant hiatus took place during the 6 day eruption of the Bishop Tuff, nearly all of which issued from an integrated, zoned, unitary reservoir. Shortly before eruption, however, the zoned melt-dominant portion of the chamber was invaded by batches of disparate lower-silica rhyolite magma, poorer in crystals than most of the resident magma but slightly hotter and richer in Ba, Sr, and Ti. Interaction with resident magma at the deepest levels tapped promoted growth of Ti-rich rims on quartz, Ba-rich rims on sanidine, and entrapment of near-rim melt inclusions relatively enriched in Ba and CO2. Varied amounts of mingling, even in higher parts of the chamber, led to the dark gray and swirly crystal-poor pumices sparsely present in all ash-flow packages. As shown by FeTi-oxide geothermometry, the zoned rhyolitic chamber was hottest where crystal-richest, rendering any model of solidification fronts at the walls or roof unlikely. The main compositional gradient (75-195 ppm Rb; 0·8-2·2 ppm Ta; 71-154 ppm Zr; 0·40-1·73% FeO*) existed in the melt, prior to crystallization of the phenocryst suite observed, which included zircon as much as 100 kyr older than the eruption. The compositions of crystals, though themselves largely unzoned, generally reflect magma temperature and the bulk compositional gradient, implying both that few crystals settled or were transported far and that the observed crystals contributed little to establishing that gradient. Upward increases in aqueous gas and dissolved water, combined with the adiabatic gradient (for the ∼ 5 km depth range tapped) and the roofward decline in liquidus temperature of the zoned melt, prevented significant crystallization against the roof, consistent with dominance of crystal-poor magma early in the eruption and lack of any roof-rind fragments among the Bishop ejecta, before or after onset of caldera collapse. A model of secular incremental zoning is advanced wherein numerous batches of crystal-poor melt were released from a mush zone (many kilometers thick) that floored the accumulating rhyolitic melt-rich body. Each batch rose to its own appropriate level in the melt-buoyancy gradient, which was self-sustaining against wholesale convective re-homogenization, while the thick mush zone below buffered it against disruption by the deeper (non-rhyolitic) recharge that augmented the mush zone and thermally sustained the whole magma chamber. Crystal-melt fractionation was the dominant zoning process, but it took place not principally in the shallow melt-rich body but mostly in the pluton-scale mush zone before and during batchwise melt extraction.
We present two-feldspar thermometry and diffusion chronometry from sanidine, orthopyroxene and quartz from multiple samples of the Bishop Tuff, California, to constrain the temperature stratification ...within the pre-eruptive magma body and the timescales of magma mixing prior to its evacuation. Two-feldspar thermometry yields estimates that agree well with previous Fe–Ti oxide thermometry and gives a ~80 °C temperature difference between the earlier- and later-erupted regions of the magma chamber. Using the thermometry results, we model diffusion of Ti in quartz, and Ba and Sr in sanidine as well as Fe–Mg interdiffusion in orthopyroxene to yield timescales for the formation of overgrowth rims on these crystal phases. Diffusion profiles of Ti in quartz and Fe–Mg in orthopyroxene both yield timescales of <150 years for the formation of overgrowth rims. In contrast, both Ba and Sr diffusion in sanidine yield nominal timescales 1–2 orders of magnitude longer than these two methods. The main cause for this discrepancy is inferred to be an incorrect assumption for the initial profile shape for Ba and Sr diffusion modelling (i.e. growth zoning exists). Utilising the divergent diffusion behaviour of Ba and Sr, we place constraints on the initial width of the interface and can refine our initial conditions considerably, bringing Ba and Sr data into alignment, and yielding timescales closer to 500 years, the majority of which are then within uncertainty of timescales modelled from Ti diffusion in quartz. Care must be thus taken when using Ba in sanidine geospeedometry in evolved magmatic systems where no other phases or elements are available for comparative diffusion profiling. Our diffusion modelling reveals piecemeal rejuvenation of the lower parts of the Bishop Tuff magma chamber at least 500 years prior to eruption. Timescales from our mineral profiling imply either that diffusion coefficients currently used are uncertain by 1–2 orders of magnitude, or that the minerals concerned did not experience a common history, despite being extracted from the same single pumice clasts. Introduction of the magma initiating crystallisation of the contrasting rims on sanidine, quartz, orthopyroxene and zircon was prolonged, and may be a marker of other processes that initiated the Bishop Tuff eruption rather than the trigger itself.
The magmatic systems that give rise to voluminous crystal-poor rhyolite magma bodies can be considered to operate on two contrasting timescales: Those governed by longer-term processes by which a ...magma acquires its chemical and isotopic characteristics (e.g., fractional crystallisation and assimilation), and those operating at shorter timescales during the physical accumulation of the melt-dominant magma body that finally erupts. We explore the compositional and textural relationships between amphibole and orthopyroxene crystals from the 25.4 ka, 530 km
3
(magma) Oruanui eruption products (Taupo volcano, New Zealand) to investigate how processes related to the physical assembly of the pre-eruptive magma body are represented in the crystal record. Over 90 % of orthopyroxenes from the volumetrically dominant high-SiO
2
(>74 wt%) rhyolite pumices record textural evidence for a significant disequilibrium event (partial dissolution ± resorption of cores and interiors) prior to the growth of 40–500 μm thick rim zones. This dissolution/regrowth history of orthopyroxene is recorded in the chemistry of co-crystallising amphiboles as a prominent inflection in the concentrations of Mn and Zn, two elements notably enriched in orthopyroxene relative to amphibole. Textural and chemical features, linked with in situ thermobarometric estimates, indicate that a major decompression event preceded the formation of the melt-dominant body. The decompression event is inferred to represent the extraction of large volumes of melt plus crystals from the Oruanui crystal mush/source zone at pressures of 140–300 MPa (~6–12 km depth). Orthopyroxene underwent partial dissolution during ascent before reestablishing in the melt-dominant magma body at pressures of 90–140 MPa (~3.5–6 km). We model Fe–Mg diffusion across the core-rim boundaries along the crystallographic
a
or
b
-axes to constrain the timing of this decompression event, which marked establishment of the melt-dominant magma body. Maximum modelled ages indicate that this event did not begin until ~1,600 years before eruption, consistent with constraints from zircon model-age spectra. Once extraction began, it underwent runaway acceleration with a peak extraction age of ~230 years, followed by an apparent period of stasis of ~60 years prior to eruption. The rapidity of the extraction and accumulation processes implies the involvement of a dynamic driving force which, in the rifted continental arc setting of the Taupo Volcanic Zone, seems likely to be represented by magma-assisted extensional tectonic processes.
Important clues to the initiation and early behavior of large (super-) eruptions lie in the records of degassing during magma ascent. Here we investigate the timescales of magma ascent for three ...rhyolitic supereruptions that show field evidence for contrasting behavior at eruption onset: (1) 650 km3, 0.767 Ma Bishop Tuff, Long Valley; (2) 530 km3, 25.4 ka Oruanui eruption, Taupo; and (3) 2500 km3, 2.08 Ma Huckleberry Ridge Tuff, Yellowstone. During magma ascent, decompression causes volatile exsolution from the host melt into bubbles, leading to H2O and CO2 gradients in quartz-hosted re-entrants (REs; unsealed inclusions). These gradients are modeled to estimate ascent rates. We present best-fit modeled ascent rates for H2O and CO2 profiles for REs in early-erupted fall deposits from Bishop (n = 13), Oruanui (n = 9), and Huckleberry Ridge (n = 9). Using a Matlab script that includes an error minimization function, Bishop REs yield ascent rates of 0.6-13 m/s, overlapping with and extending beyond those of the Huckleberry Ridge (0.3-4.0 m/s). Re-entrants in Oruanui quartz crystals from the first two eruptive phases (of 10) yield the slowest ascent rates determined in this study (0.06-0.48 m/s), whereas those from phase three, which has clear field evidence for a marked increase in eruption intensity, are uniformly higher (1.4-2.6 m/s). For all three eruptions, the interiors of most REs appear to have re-equilibrated to lower H2O and CO2 concentrations when compared to co-erupted, enclosed melt inclusions in quartz. Such reequilibration implies the presence of an initial period of slower ascent, likely resulting from movement of magma from storage into a developing conduit system, prior to the faster (<1-2.5 h) final ascent of magma to the surface. This slower initial movement represents hours to several days of reequilibration, invalidating any assumption of constant decompression conditions from the storage region. However, the number of REs with deeper starting depths increases with stratigraphic height in all three deposits (particularly the Bishop Tuff), suggesting progressive elimination of the deep, sluggish ascent stage over time, which we interpret to be the result of maturing of the conduit system(s). Our results agree well with ascent rates estimated using theoretical approximations and numerical modeling for plinian rhyolitic eruptions (0.7-30 m/s), but overlap more with the slower estimates.
Background
Kidney transplantation is the optimal treatment for end‐stage kidney disease. Retrieval, transport and transplant of kidney grafts causes ischaemia reperfusion injury. The current accepted ...standard is static cold storage (SCS) whereby the kidney is stored on ice after removal from the donor and then removed from the ice box at the time of implantation. However, technology is now available to perfuse or "pump" the kidney during the transport phase or at the recipient centre. This can be done at a variety of temperatures and using different perfusates. The effectiveness of treatment is manifest clinically as delayed graft function (DGF), whereby the kidney fails to produce urine immediately after transplant.
Objectives
To compare hypothermic machine perfusion (HMP) and (sub)normothermic machine perfusion (NMP) with standard SCS.
Search methods
We searched the Cochrane Kidney and Transplant Register of Studies to 18 October 2018 through contact with the Information Specialist using search terms relevant to this review. Studies in the Register are identified through searches of CENTRAL, MEDLINE, and EMBASE, conference proceedings, the International Clinical Trials Register (ICTRP) Search Portal and ClinicalTrials.gov.
Selection criteria
All randomised controlled trials (RCTs) and quasi‐RCTs comparing HMP/NMP versus SCS for deceased donor kidney transplantation were eligible for inclusion. All donor types were included (donor after circulatory (DCD) and brainstem death (DBD), standard and extended/expanded criteria donors). Both paired and unpaired studies were eligible for inclusion.
Data collection and analysis
The results of the literature search were screened and a standard data extraction form was used to collect data. Both of these steps were performed by two independent authors. Dichotomous outcome results were expressed as risk ratio (RR) with 95% confidence intervals (CI). Continuous scales of measurement were expressed as a mean difference (MD). Random effects models were used for data analysis. The primary outcome was incidence of DGF. Secondary outcomes included: one‐year graft survival, incidence of primary non‐function (PNF), DGF duration, long term graft survival, economic implications, graft function, patient survival and incidence of acute rejection.
Main results
No studies reported on NMP, however one ongoing study was identified.
Sixteen studies (2266 participants) comparing HMP with SCS were included; 15 studies could be meta‐analysed. Fourteen studies reported on requirement for dialysis in the first week post‐transplant (DGF incidence); there is high‐certainty evidence that HMP reduces the risk of DGF when compared to SCS (RR 0.77; 95% CI 0.67 to 0.90; P = 0.0006). HMP reduces the risk of DGF in kidneys from DCD donors (7 studies, 772 participants: RR 0.75; 95% CI 0.64 to 0.87; P = 0.0002; high certainty evidence), as well as kidneys from DBD donors (4 studies, 971 participants: RR 0.78, 95% CI 0.65 to 0.93; P = 0.006; high certainty evidence). The number of perfusions required to prevent one episode of DGF (number needed to treat, NNT) was 7.26 and 13.60 in DCD and DBD kidneys respectively. Studies performed in the last decade all used the LifePort machine and confirmed that HMP reduces the incidence of DGF in the modern era (5 studies, 1355 participants: RR 0.77, 95% CI 0.66 to 0.91; P = 0.002; high certainty evidence). Reports of economic analysis suggest that HMP can lead to cost savings in both the North American and European settings.
Two studies reported HMP also improves graft survival however we were not able to meta‐analyse these results. A reduction in incidence of PNF could not be demonstrated. The effect of HMP on our other outcomes (incidence of acute rejection, patient survival, hospital stay, long‐term graft function, duration of DGF) remains uncertain.
Authors' conclusions
HMP is superior to SCS in deceased donor kidney transplantation. This is true for both DBD and DCD kidneys, and remains true in the modern era (studies performed in the last decade). As kidneys from DCD donors have a higher overall DGF rate, fewer perfusions are needed to prevent one episode of DGF (7.26 versus 13.60 in DBD kidneys).
Further studies looking solely at the impact of HMP on DGF incidence are not required. Follow‐up reports detailing long‐term graft survival from participants of the studies already included in this review would be an efficient way to generate further long‐term graft survival data.
Economic analysis, based on the results of this review, would help cement HMP as the standard preservation method in deceased donor kidney transplantation.
RCTs investigating (sub)NMP are required.
Supereruptions (>10
15
kg ≈ 450 km
3
of ejected magma) have received much attention because of the challenges in explaining how and over what time intervals such large volumes of magma are ...accumulated, stored and erupted. However, the processes that follow supereruptions, particularly those focused around magmatic recovery, are less fully documented. We present major and trace-element data from whole-rock, glass and mineral samples from eruptive products from Taupo volcano, New Zealand, to investigate how the host magmatic system reestablished and evolved following the Oruanui supereruption at 25.4 ka. Taupo’s young eruptive units are precisely constrained chronostratigraphically, providing uniquely fine-scale temporal snapshots of a post-supereruption magmatic system. After only ~5 kyr of quiescence following the Oruanui eruption, Taupo erupted three small volume (~0.1 km
3
) dacitic pyroclastic units from 20.5 to 17 ka, followed by another ~5-kyr-year time break, and then eruption of 25 rhyolitic units starting at ~12 ka. The dacites show strongly zoned minerals and wide variations in melt-inclusion compositions, consistent with early magma mixing followed by periods of cooling and crystallisation at depths of >8 km, overlapping spatially with the inferred basal parts of the older Oruanui silicic mush system. The dacites reflect the first products of a new silicic system, as most of the Oruanui magmatic root zone was significantly modified in composition or effectively destroyed by influxes of hot mafic magmas following caldera collapse. The first rhyolites erupted between 12 and 10 ka formed through shallow (4–5 km depth) cooling and fractionation of melts from a source similar in composition to that generating the earlier dacites, with overlapping compositions for melt inclusions and crystal cores between the two magma types. For the successively younger rhyolite units, temporal changes in melt chemistry and mineral phase stability are observed, which reflect the development, stabilisation and maturation of a new, probably unitary, silicic mush system. This new mush system was closely linked to, and sometimes physically interacted with, underlying mafic melts of similar composition to those involved in the Oruanui supereruption. From the inferred depths of magma storage and geographical extent of vent sites, we consider that a large silicic mush system (>200 km
3
and possibly up to 1000 km
3
in volume) is now established at Taupo and is capable of feeding a new episode or cycle of volcanism at any stage in the future.
•We document the earliest fall deposits in the Huckleberry Ridge Supereruption.•Six crystallizing bodies amalgamated into three discrete melt bodies prior to eruption.•Melt inclusions partially ...reequilibrated during slow ascent, matching field evidence.•Slow ascent rates imply the magmatic body was not strongly overpressurized at onset.•The three cupolas were vented sequentially, modulated by external forces.
How exceedingly large, volcanic supereruptions begin provides crucial information on the storage, ascent and release of silica-rich magma in catastrophic events. Initial fall deposits of the 2.08 Ma, 2500 km3 Huckleberry Ridge eruption are multiply bedded and in several places contain reworked intervals, indicating time breaks in the opening phases of the eruption. A 2.5 m section of these fall deposits was sampled at nine levels below the earliest ignimbrite (member A) at Mount Everts (Mammoth, Wyoming). We analyzed major and trace elements and volatiles in quartz-hosted melt inclusions (MIs), reentrants (REs; unsealed melt inclusions) and associated obsidian pyroclasts (thick-walled shards) to establish quartz crystallization and storage depths and melt compositional groupings. Systematic relationships between Rb and other incompatible elements (U, Cl, B) indicate ∼55% fractional crystallization between the least and most evolved glass compositions. In contrast, H2O concentrations in MIs show scattered relationships with trace elements and are interpreted to reflect variable loss of H2O by diffusion through the quartz host during magma ascent. The wide H2O variations (1.0–4.7 wt.%) in MIs from individual fall horizons imply as much as ∼14 days of diffusive loss, reflecting highly variable and surprisingly slow decompression conditions. Water and CO2 gradients in reentrants, however, are consistent with final ascent times of <1 to 4 h (ascent rates of ∼0.3–1.5 m/s), similar to those represented by MIs that we infer to have experienced little to no diffusive H2O loss. The wide range of ascent rates for co-erupted crystals mirrors that of intermittent explosive activity at Mount St. Helens in summer 1980, and implies that the Huckleberry Ridge magma body was not strongly overpressured at eruption onset. Restored entrapment pressures and geochemical data for MIs provide evidence for six distinct populations of quartz that originally crystallized in geochemically distinct magma domains. The compositions of REs and obsidian pyroclasts, by comparison, show that by the onset of eruption, the quartz had been brought together into three discrete magma bodies, which we interpret to have been cupolas on the roof of the main magma body. These cupolas were erupted sequentially and episodically from separate vents to generate the fall deposits before escalating activity led to generation of voluminous pyroclastic flows, and this pattern of activity suggests that tectonic triggering may have destabilized multiple magma bodies. Supereruptions as large as the Huckleberry Ridge event may start hesitatingly if the parental magma bodies are not strongly overpressured, with small-scale episodic activity that is modulated by external controls that may leave no other geological evidence for their presence.
The study of phonotactics is a central topic in phonology. We propose a theory of phonotactic grammars and a learning algorithm that constructs such grammars from positive evidence. Our grammars ...consist of constraints that are assigned numerical weights according to the principle of maximum entropy. The grammars assess possible words on the basis of the weighted sum of their constraint violations. The learning algorithm yields grammars that can capture both categorical and gradient phonotactic patterns. The algorithm is not provided with constraints in advance, but uses its own resources to form constraints and weight them. A baseline model, in which Universal Grammar is reduced to a feature set and an SPE-style constraint format, suffices to learn many phonotactic phenomena. In order for the model to learn nonlocal phenomena such as stress and vowel harmony, it must be augmented with autosegmental tiers and metrical grids. Our results thus offer novel, learning-theoretic support for such representations. We apply the model in a variety of learning simulations, showing that the learned grammars capture the distributional generalizations of these languages and accurately predict the findings of a phonotactic experiment.
Clouds and Hazes of Venus Titov, Dmitrij V.; Ignatiev, Nikolay I.; McGouldrick, Kevin ...
Space science reviews,
12/2018, Letnik:
214, Številka:
8
Journal Article
Recenzirano
Odprti dostop
More than three decades have passed since the publication of the last review of the Venus clouds and hazes. The paper published in 1983 in the Venus book summarized the discoveries and findings of ...the US Pioneer Venus and a series of Soviet Venera spacecraft (Esposito et al. in Venus, p. 484,
1983
). Due to the emphasis on in-situ investigations from descent probes, those missions established the basic features of the Venus cloud system, its vertical structure, composition and microphysical properties. Since then, significant progress in understanding of the Venus clouds has been achieved due to exploitation of new observation techniques onboard Galileo and Messenger flyby spacecraft and Venus Express and Akatsuki orbiters. They included detailed investigation of the mesospheric hazes in solar and stellar occultation geometry applied in the broad spectral range from UV to thermal IR. Imaging spectroscopy in the near-IR transparency “windows” on the night side opened a new and very effective way of sounding the deep atmosphere. This technique together with near-simultaneous UV imaging enabled comprehensive study of the cloud morphology from the cloud top to its deep layers. Venus Express operated from April 2006 until December 2014 and provided a continuous data set characterizing Venus clouds and hazes over a time span of almost 14 Venus years thus enabling a detailed study of temporal and spatial variability. The polar orbit of Venus Express allowed complete latitudinal coverage. These studies are being complemented by JAXA Akatsuki orbiter that began observations in May 2016. This paper reviews the current status of our knowledge of the Venus cloud system focusing mainly on the results acquired after the Venera, Pioneer Venus and Vega missions.
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