Heavy-metal (HM) pollution is considered a leading source of environmental contamination. Heavy-metal pollution in ground water poses a serious threat to human health and the aquatic ecosystem. ...Conventional treatment technologies to remove the pollutants from wastewater are usually costly, time-consuming, environmentally destructive, and mostly inefficient. Phytoremediation is a cost-effective green emerging technology with long-lasting applicability. The selection of plant species is the most significant aspect for successful phytoremediation. Aquatic plants hold steep efficiency for the removal of organic and inorganic pollutants. Water hyacinth (Eichhornia crassipes), water lettuce (Pistia stratiotes) and Duck weed (Lemna minor) along with some other aquatic plants are prominent metal accumulator plants for the remediation of heavy-metal polluted water. The phytoremediation potential of the aquatic plant can be further enhanced by the application of innovative approaches in phytoremediation. A summarizing review regarding the use of aquatic plants in phytoremediation is gathered in order to present the broad applicability of phytoremediation.
With the rapid development of nanotechnology in the past decades, AgNPs are widely used in various fields and have become one of the most widely used nanomaterials, which leads to the inevitable ...release of AgNPs to the aquatic environment through various pathways. It is important to understand the effects of AgNPs on aquatic plants and zooplankton, which are widely distributed and diverse, and are important components of the aquatic biota. This paper reviews the effects of AgNPs on aquatic plants and zooplankton at the individual, cellular and molecular levels. In addition, the internal and external factors affecting the toxicity of AgNPs to aquatic plants and zooplankton are discussed. In general, AgNPs can inhibit growth and development, cause tissue damage, induce oxidative stress, and produce genotoxicity and reproductive toxicity. Moreover, the toxicity of AgNPs is influenced by the size, concentration, and surface coating of AgNPs, environmental factors including pH, salinity, temperature, light and co-contaminants such as NaOCl, glyphosate, As(V), Cu and Cd, sensitivity of test organisms, experimental conditions and so on. In order to investigate the toxicity of AgNPs in the natural environment, it is recommended to conduct toxicity evaluation studies of AgNPs under the coexistence of multiple environmental factors and pollutants, especially at natural environmental concentrations.
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•Toxicity of silver nanoparticles to aquatic plants and zooplankton was reviewed.•Cytotoxicity and genotoxicity explained the adverse effects at individual level.•Environmental factors and co-contaminants affect the toxicity of AgNPs.
Phytoremediation is a low-cost, environmentally friendly, and sustainable technology that can utilize vegetation and microorganisms to avoid eutrophication and purifying water environment. The ...ability of five different living aquatic plants of nitrogen (N), phosphorus (P), and chemical oxygen demand (CODcr) removal were investigated in pilot scale constructed wetlands (CWs). Aquatic plant mixes significantly improved CODcr removal and plant tissue uptake of nitrogen and phosphorus. The wetland performance of mixed plantings was also influenced by the specific species. The mixed planting of Phragmites australi, Nymphaea Colorado and Myriophyllum verticillatum (PNM)When assessing pollutant removal in CWs, PNM performed better within mixtures, a possible synergistic effect, while TNV Typha orientalis, Nymphaea Colorado, and Vallisneria natans (TNV) performed poorly, a possible antagonist effect. The nutrient uptake within plant tissues byunder mixed plants planting was always ahad synergistic effect. Mixed plantingAquatic plant mixes significantly increased the rhizosphere microbial diversity and promoted the growth of functional denitrifying flora.
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•Mixed planting significantly promoted CODcr removal, but had no effect on nitrogen and phosphorus removal.•Mixed planting of plants were always synergistic on plant uptake of nitrogen and phosphorus.•Mixed planting significantly increased the rhizosphere microbial diversity and promoted the growth of denitrifying flora.•Selecting the right mix of plants is an effective means to enhance the efficiency of CWs and improve eutrophication.
New arylpicolinate herbicide chemistry under development for rice, aquatic weed management, and other uses was evaluated using five aquatic plants. The herbicide ...4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoro-pyridine-2-benzyl ester—also identified as XDE-848 BE or SX-1552 (proposed International Organization for Standardization common name in review; active tradename RinskorTM)—and its acid form (XDE-848 acid or SX-1552A) were evaluated on three dicots: (1) Eurasian watermilfoil (EWM), (2) megalodonta, and (3) crested floating heart (CFH), and two monocots: (1) hydrilla and (2) elodea. A small-scale Organization for Economic Cooperation and Development (OECD) protocol developed using EWM for registration studies was utilized. EWM and megalodonta were also evaluated in larger-scale mesocosms for comparison. In-water concentrations between 0.01 and 243 μg ai L−1 as SX-1552 or SX-1552A were applied under static conditions for 14 (growth chamber) or 28 d (mesocosm). EWM was susceptible to both SX-1552 and SX-1552A, with dry-weight 50% effective concentration (EC50) values of 0.11 and 0.23 μg ai L−1 under growth chamber conditions. Megalodonta had EC50 values of 11.3 and 14.5 μg ai L−1 for the SX-1552 and SX-1552A. CFH was more sensitive to SX-1552 (EC50 = 5.6 μg ai L−1 ) than to SX-1552A (EC50 = 23.9 μg ai L−1). Hydrilla had EC50 values of 1.4 and 2.5 μg ai L−1, whereas elodea was more tolerant, with EC50 values of 6.9 and 13.1 μg ai L−1 for SX-1552 and SX-1552A, respectively. For EWM mesocosm trials, EC50 values for SX-1552 and 1552A were 0.12 μg ai L−1 and 0.58 μg ai L−1, whereas the megalodonta EC50 was 6.1 μg ai L−1. Activity of SX-1552 on EWM, hydrilla, and CFH merits continued investigation for selective aquatic weed control properties. Results suggest that the OECD protocol can be used to screen activity of herbicides for multiple aquatic plant species. Nomenclature: 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoro-pyridine-2-benzyl ester; crested floating heart, Nymphoides cristata (Roxb.) Kuntze; elodea, Elodea canadensis Michx.; Eurasian watermilfoil, Myriophyllum spicatum L.; hydrilla, Hydrilla verticillata L.f. Royle; megalodonta, Bidens beckii Torr. Ex Spreng.
Iron (Fe) is the fourth most abundant element in the earth’s crust and plays important roles in both biological and chemical processes. The redox reactivity of various Fe(II) forms has gained ...increasing attention over recent decades in the areas of (bio) geochemistry, environmental chemistry and engineering, and material sciences. The goal of this paper is to review these recent advances and the current state of knowledge of Fe(II) redox chemistry in the environment. Specifically, this comprehensive review focuses on the redox reactivity of four types of Fe(II) species including aqueous Fe(II), Fe(II) complexed with ligands, minerals bearing structural Fe(II), and sorbed Fe(II) on mineral oxide surfaces. The formation pathways, factors governing the reactivity, insights into potential mechanisms, reactivity comparison, and characterization techniques are discussed with reference to the most recent breakthroughs in this field where possible. We also cover the roles of these Fe(II) species in environmental applications of zerovalent iron, microbial processes, biogeochemical cycling of carbon and nutrients, and their abiotic oxidation related processes in natural and engineered systems.