Progress in imaging and metrology depends on exquisite control over and comprehensive characterization of wave fields. As reflected in its name, coherent diffractive imaging relies on high coherence ...when reconstructing highly resolved images from diffraction intensities alone without the need for image-forming lenses. Fully coherent light can be described adequately by a single pure state. Yet partial coherence and imperfect detection often need to be accounted for, requiring statistical optics or the superposition of states. Furthermore, the dynamics of samples are increasingly the very objectives of experiments. Here we provide a general analytic approach to the characterization of diffractive imaging systems that can be described as low-rank mixed states. We use experimental data and simulations to show how the reconstruction technique compensates for and characterizes various sources of decoherence quantitatively. Based on ptychography, the procedure is closely related to quantum state tomography and is equally applicable to high-resolution microscopy, wave sensing and fluctuation measurements. As a result, some of the most stringent experimental conditions in ptychography can be relaxed, and susceptibility to imaging artefacts is reduced. Furthermore, the method yields high-resolution images of mixed states within the sample, which may include quantum mixtures or fast stationary stochastic processes such as vibrations, switching or steady flows.
Surface modulation of functional nanostructures is an efficient way of improving gas sensing properties in chemiresistive materials. However, synthesis methods employed so far in achieving desired ...performances are cumbersome and energy intensive. Moreover, nano-engineering-induced magnetic properties of these materials which are expected to enhance sensing responses have not been utilized until now in improving their interaction with target gases. In particular for gasses with paramagnetic nature such as NO or NO2, the inherent magnetic property of the chemiresistor might assist in enabling superior sensing performance. In this work, vanadium-doped NiO nano-clusters with ferromagnetic behavior at room temperature have been synthesized by a simple and effective combination of soft chemical routes and employed in efficient and selective detection of paramagnetic NO gas. While NiO is typically anti-ferromagnetic, the nanoscale engineering of NiO- and V-doped NiO samples have been found to tune the inherent anti-ferromagnetic behavior into room-temperature ferromagnetism. Surface modification in terms of formation of nano-clusters led to an increased Brunauer–Emmett–Teller surface area of ∼120 m2/g. The sample Ni0.636V0.364O has been observed to exhibit a selective and high response of ∼98% to 1 ppm NO at room temperature with fast response (14 s) and recovery (95 s). The improved sensing response of this sample compared to other doped NiO variants could be explained in terms of lower remnant magnetic moment of the sample accompanied with higher excess negative charge at the surface. The sensing response of this sample was increased by 30% in the presence of an external magnetic field of 280 gauss, highlighting the importance of magnetic ordering in chemiresistive gas sensing between the magnetic sensor material and target analyte. This material stands as a potential gas sensor with excellent NO detection properties.
Pd–Co x O y heteroaggregate-encapsulated hollow porous silica nanoreactors (Pd–Co x O y @HPSNs) were synthesized by a reverse microemulsion system. The key design of the developed reverse ...microemulsion system is to use poly(ethyleneimine) in the water droplets as the void templates for silica deposition and for anchoring the catalytic functionality inside the hollow silica nanospheres. The synthesized Pd–Co x O y @HPSNs contain ∼3 nm Pd–Co x O y hybrid nanostructures in ∼10 nm central cavities of silica nanospheres and illustrated a significantly promoted efficiency for hydrodechlorination of a series of chlorophenols into phenols under mild reaction conditions. The catalytic enhancement of Pd–Co x O y @HPSNs is ascribed to the synergistic effect between Pd and Co x O y and the protection of silica shells to the inner catalytic functionality.
We quantify the effects of the political development cycle—the fluctuations between the Left (Maoist) and the Right (pragmatist) development policies—on growth and structural transformation of China ...in 1953–1978. The left policies prioritized structural transformation toward nonagricultural production and consumption at the expense of agricultural development. The right policies prioritized agricultural consumption through slower structural transformation. The imperfect implementation of these policies led to large welfare costs of the political development cycle in a distorted economy undergoing a structural change. (JEL D72, N15, N45, N55, O21, P21, P24)
The concentration of nicotinamide adenine dinucleotide oxidized form (NAD+) changes during aging, and the production of NAD+ can significantly affect both health span and life span. However, it is ...still of great challenge to regenerate NAD+ from its precursors. Herein, we introduce a method to prepare multimetallic nanoparticles (including Au, Pt, Cu, and MgO) that can efficiently promote the conversion of NADH to NAD+. The nanoparticles are made by mixing reduced graphene oxide–polyethyleneimine–polyacrylic acid nano-films with metallic salts, where four different metal ions are reduced and grow at the surface of the nanolayers. The morphology, size, and growth rate of nanoparticles can be controlled by adding surfactants, applying an electric field, and so forth. Our multimetallic nanoparticles exhibit excellent catalytic performance that a complete conversion of NADH to NAD+ can be finished in 3 min without introducing additional oxygen. This work presents a way for the preparation of multimetallic nanoparticles to promote NAD+ regeneration, which shows great promise for the future design of high-performance materials for antiaging.
Using centuries of Nile flood data, I document that during deviant Nile floods, Egypt's highest-ranking religious authority was less likely to be replaced and relative allocations to religious ...structures increased. These findings are consistent with historical evidence that Nile shocks increased this authority's political influence by raising the probability he could coordinate a revolt. I find that the available data provide support for this interpretation and weigh against some of the most plausible alternatives. For example, I show that while Nile shocks increased historical references to social unrest, deviant floods did not increase a proxy for popular religiosity. Together, the results suggest an increase in the political power of religious leaders during periods of economic downturn.
The properties of quantum states have led to the development of new technologies, ranging from quantum information to quantum metrology. A recent field of research to emerge is quantum imaging, which ...aims to overcome the limits of classical imaging by making use of the spatial properties of quantum states of light . In particular, quantum correlations between twin beams represent a fundamental resource for these studies. One of the most interesting proposed schemes takes advantage of the spatial quantum correlations between parametric down-conversion light beams to realize sub-shot-noise imaging of weak absorbing objects, leading ideally to noise-free imaging. Here, we present the first experimental realization of this scheme, showing its potential to achieve a larger signal-to-noise ratio than classical imaging methods. This work represents the starting point for this quantum technology, which we anticipate will have applications when there is a requirement for low-photon-flux illumination (for example for use with biological samples).
Graphene oxide (GO), single-walled carbon nanohorn (CNHox), and nitrogen-doped CNH (N-CNH) were functionalized with fluorinated poly(ethylene glycol) (F-PEG) and/or with a fluorinated dendrimer ...(F-DEN) to prepare a series of assembled nanocomposites (GO/F-PEG, CNHox/F-PEG, N-CNH/F-PEG, N-CNH/F-DEN, and N-CNH/F-DEN/F-PEG) that provide effective multisite O2 reservoirs. In all cases, the O2 uptake increased with time and saturated after 10–20 min. When graphitic carbons (GO and CNHox) were coated with F-PEG, the O2 uptake doubled. The O2 loading was slightly higher in N-CNH compared to CNHox. Notably, coating N-CNH with F-DEN or F-PEG, or with both F-DEN and F-PEG, was more effective. The best performance was obtained with the N-CNH/F-DEN/F-PEG nanocomposite. The O2 uptake kinetics and mechanisms were analyzed in terms of the Langmuir adsorption equation based on a multibinding site assumption. This allowed the precise determination of multiple oxygen binding sites, including on the graphitic structure and in the dendrimer, F-DEN, and F-PEG. After an initial rapid, relatively limited release, the amount of O2 trapped in the nanomaterials remained high (>95%). This amount was marginally lower for the functionalized composites, but the oxygen stored was reserved for longer times. Finally, it is shown that these systems can generate singlet oxygen after irradiation by a light-emitting diode, and this production correlates with the amount of O2 loaded. Thus, it was anticipated that the present nanocomposites hierarchically assembled from components with different characters and complementary affinities for oxygen can be useful as O2 reservoirs for singlet oxygen generation to kill bacteria and viruses and to perform photodynamic therapy.
Nanocellulose-mediated MXene composites have attracted widespread attention in the fields of sustainable energy, wearable sensors, and electromagnetic interference (EMI) shielding. However, the ...effects of different nanocelluloses on the multifunctional properties of nanocellulose/Ti3C2T x composites still need further exploration. Herein, we use three types of nanocelluloses, including bacterial cellulose (BC), cellulose nanocrystals (CNCs), and 2,2,6,6-tetramethylpiperidin-1-yloxy (TEMPO)-oxidized cellulose nanofibers (TOCNs), as intercalation to link Ti3C2T x nanosheets via a self-assembly process, improving the dispersibility, film-forming ability, mechanical properties, and multifunctional performances of nanocelluloses/Ti3C2T x hybrids through electrostatic forces and hydrogen bonding. The optimized ultrathin (∼40 μm) TOCN/Ti3C2T x film integrates excellent tensile strength (∼98.89 MPa), long-term stability (during deformation and water erosion), favorable photoelectric response (photosensitivity up to 2620%), and temperature response (reaching 163 °C in only 12 s). Laser-cutting patterned TOCN/Ti3C2T x films are assembled into flexible multifunctional electronics, exhibiting splendid photoresponse performances and tunable electromagnetic energy shielding capability (>96.4%) related to the variation of water content at the film–gel electrolyte interface. Multifunctional patterned devices based on TOCN/Ti3C2T x composite films provide a novel pathway to rationally design wearable EMI devices with photoelectric response and photothermal conversion.
The design and development of radar-–infrared compatible stealth materials are challenging in the field of broadband absorption due to the contradiction of stealth requirements and mechanisms in ...different frequency bands. However, hollow structures show great promise for multispectral stealth because they can lengthen the attenuation path of electromagnetic waves (EMWs) for microwave absorption, interrupt the continuity of heat-transport channels, and lower the thermal conductivity to realize infrared stealth. Here, a new morphological fabrication strategy has been developed to efficiently prepare compatible stealth nanomaterials. In a specific hydrothermal process, the confined growth of flake α-Fe2O3 (f-Fe2O3) outside of hollow mesoporous carbon spheres (HMCS) is achieved using NH3·H2O as a shape-controlled reagent. The introduction of f-Fe2O3 helps to lower infrared emissivity and improve high-frequency impedance matching, which depends on the stable dielectric property of the specific flake shape. Moreover, the size of f-Fe2O3 can be regulated by changing the constituent proportion in the hydrothermal suspension to obtain excellent performance. The minimum reflection loss (RL) of the HMCS@f-Fe2O3-6 composite is −34.16 dB at 2.4 mm, and the effective absorption bandwidth (EAB) reaches 4.8 GHz. Furthermore, the lowest emissivities of the HMCS@f-Fe2O3-6-20 wt %/polyetherimide (PEI) film in the 3–5 and 8–14 μm infrared wavebands are 0.212 and 0.508, respectively. These discoveries may pave the way for the development of radar–infrared compatible stealth materials from the perspective of microstructural design.
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