Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- Metasedimentne stijene Medvednice, koje se nalaze na prostoru Zagorje-Mid-Transdanubijske zone, zabilježile su nekoliko faza ...deformacija od kojih je najintenzivnija uzrokovala metamorfizam unutar facijesa zelenih škriljavaca. U radu su obrađene litostratigrafske jedinice Stari potok, Slani potok, Risnjak i Vila Rebar. Posebna pozornost je posvećena kloritoidnom škriljavcu iz jedinice Stari potok. Napravljene su petrografske i geokemijske analize (XRD, ICP-MS). Uvjeti metamorfizma određivani su pomoću geotermometara za klorit i parove klorit-kloritoid te geobarometara za muskovit (fengit). Konstruiran je dijagram pseudopresjeka za uzorak kloritoidnog škriljavca, izoplete udjela Mg u kloritu i kloritoidu te izoplete Si u muskovitu (fengit). Starost progradne faze metamorfizma izmjerena je na monacitima (EMP), pri čemu je dobivena starost srednje do gornje jure (153 ± 6,9 Ma). Mjerenje sadržaja izotopa U-Th-Pb napravljeno je na zajednici detritnih cirkona pomoću LA-ICP-MC-MS-a. Dobiveni starosni podaci cirkona dali su vrijednosti koje su grupirane u devet podgrupa, unutar šest starosnih grupa. Na temelju najmlađe starosne podgrupe cirkona procijenjena je maksimalna starost taloženja. Iz petrografskih analiza na uzorcima metasedimenata litostratigrafskih jedinica Stari potok, Risnjak, Vila Rebar i Slani potok, utvrđena je metamorfna mineralna asocijacija koju čine kvarc, bijeli tinjac, klorit, ± albit, ± biotit, ± kloritoid, ± turmalin, ± monacit, ± ksenotim, ± apatit. Sačuvani akcesorni detritarni minerali su cirkon i rutil. Mineralna asocijacija ukazuje na nizak stupanj metamorfizma unutar facijesa zelenih škriljavaca. Geokemijski podaci sugeriraju da su protoliti istraživanih metasedimentnih stijena uglavnom bili srednje do intenzivno trošeni zreli sedimenti, nastali taloženjem nakon trošenja stijena pretežito granitoidnog sastava, ugrađenih u vulkanski luk.- Metasedimentary rocks from Mt. Medvednica, located in Zagorje-Mid-Transdanubian zone, had undergone multiphase deformation history. The most intense deformation phase is manifested by the most intense metamorphic phase, which reached greenschist metamorphic facies. This thesis investigated Stari potok, Slani potok, Risnjak and Vila Rebar lithostratigraphic units, with special attention given to the occurrence of chloritoid schist in Stari potok unit. Petrographic and geochemical analysis were conducted (XRD, ICP-MS). Metamorphic conditions were investigated with geothermometers for chlorite and pairs of chlorite-chloritoid, while geobarometric conditions were calculated on muscovite (phengite). Pseudosection diagram, isopleths of XMg in chlorite and chloritoid, as well as XSi in muscovite (phengite) were modeled using software package PerpleX. Late Jurassic (153 ± 6.9 Ma) metamorphic age was determined based on sinmetamorphic monazite grains analysis. Ratios of U/Th/Pb from detrital zircon grains were measured on LA-ICP-MC-MS, resulting in recognition of nine subgroups within six detrital zircon age groups. Youngest subgroup of detrital zircons gave insight into deposition time of the protolith sediment. Petrographic analysis of metasediment samples of litostratigraphic units Stari potok, Slani potok, Risnjak and Vila Rebar indicated metamorphic mineral association of quartz, white micas, chlorite, ± albite, ± biotite, ± chloritoide, ± turmaline, ± monazite, ± xenotime, ± apatite. Accessory mineral phases are zircons and rutile. Mineral association is typical for low greenschist metamorphic facies. Geochemical data indicate that protolith sediments were mature, middle to intensively weathered sediments, produced by deposition after weathering of mainly volcanic arc granitoid rocks.- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain ...Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
Provider: - Institution: - Data provided by Europeana Collections- Rekristalizacija uzoraka allanita različitog stupnja metamiktnosti je inducirana žarenjem uzoraka na zraku, te u uvjetima inertne i ...reduktivne atmosfere na odabranim temperaturama. Do 800C metamiktni uzorci allanita djelomično rekristaliziraju u kristalnu strukturu allanita, no kod jače metamiktnih uzoraka već na ovoj temperaturi dolazi do pojavljivanja novih faza, cerijanita i hematita. Zbog oksidacije Fe2+ i Ce3+, te posljedično otpuštanja OHaniona, u danim uvjetima, nemoguće je ostvariti potpunu rekristalizaciju, a na višim temperaturama (> 900C) kristalna struktura allanita se u potpunosti raspada na jednostavnije okside (cerijanit, hematit), fosfate (britholit) i silikate (anortit). Iz tog razloga su odabrani uzorci hidrotermalno tretirani na nižim (150 -250C), te višim (400-800C) temperaturama na kojima dolazi do potpune rekristalizacije metamiknih uzoraka allanita, neovisno o stupnju metamiktnosti, bez pojave dodatnih faza. Jedan uzorak allanita je podvrgnut bombardiranju neutronima radi rušenja kristalne strukture, što je djelomično uspješno izvršeno. Svi procesi su praćeni difrakcijom rentgenskih zraka na prahu, visokorazlučujućom transimisijskom elektronskom mikroskopijom, te elektronskom difrakcijom, IR, Raman i Mössbauer spektroskopijom te termičkim metodama.- Recrystallization of allanite with different degrees of metamictization is induced by annealing of samples in air, inert and reductive atmosphere at chosen temperatures. Up to 800C metamict samples of allanite partially recrystallize to allanite crystal structure, but with heavily metamictized samples, already at these temperatures, new phases such as cerianite and hematite, occur. It is impossible to accomplish complete recrystallization in these conditions due to oxidation of Fe2+ and Ce3+, and escape of OHanion from the structure, and at higher temperatures (> 900C), allanite crystal structure breaks down to a mixture of simple oxides (cerianite an hematite), phosphate (britholite) and silicate (anorthite). Thus, chosen samples were hydrothermally treated at lower (150 -250C), and higher (400-800C) temperatures when complete recrystallization, without additional phases and regardless of the degree of metamictization, occurs. One allanite sample was bombarded with neutron flux, in order to destroy its crystal structure, what was partially accomplished. All processes were monitored by X-ray powder diffraction, high-resolution transmission electron microscopy coupled with electron diffraction, IR, Raman and Mössbauer spectroscopy, and thermal methods.- All metadata published by Europeana are available free of restriction under the Creative Commons CC0 1.0 Universal Public Domain Dedication. However, Europeana requests that you actively acknowledge and give attribution to all metadata sources including Europeana
