Anhand von sedimentologischen und
geländemorphologischen Untersuchungen wird die Abschmelzgeschichte des
südöstlichen Chiemsee-Gletschers beschrieben. Mit dem Trockenfallen
der Bad ...Adelholzen-Erlstätter Rinne im Verlaufe des Spätwürm
entwickelt sich aus dem Abschmelzen des Eislappens in der Grabenstätter
Bucht eine sich ständig tiefer legende konzentrische Abfolge von
zunächst peripheren Entwässerungsrinnen, wobei die ältesten
Rinnen dieser Phase bei Chieming, die jüngeren dann entsprechend weiter
im Süden, in die zentripetale Richtung umschwenken. Die Entstehung des Tüttensee-Komplexes ist im Kontext dieser Entwicklung
zu sehen. Er ist das Ergebnis der glazifluvialen und glazilakustrinen
Sedimentation im Einflussbereich des sukzessiven Eisabbaus in der
Grabenstätter Bucht in Kombination mit einer Toteisbildung im Bereich
des heutigen Tüttensees. Dafür sprechen die stufenartige Abfolge der
beschriebenen peripheren Abflussrinnen mit ihren immer tiefer liegenden
Abflussniveaus, die Höhengleichheit von drei dieser Rinnen mit den
Tüttensee-Terrassen sowie die für die jeweilige Terrassenentstehung
typische glazifluviale bzw. delta-artige Sedimentstruktur und -reife. Dieses
Ergebnis stellt ein Korrektiv zur Hypothese des Chiemgau-Impakts dar, wonach
der Tüttensee ein Impaktkrater sein soll. Da diese nun falsifizierte
Annahme vor allem im deutschsprachigen Raum von zahlreichen Medien
propagiert wird, ist der folgende Artikel auf Deutsch verfasst, um einer
breiten Leserschaft zugänglich zu sein.
Although large dams have been constructed and continue to be constructed on many rivers, the lack of long-term gauging data often makes it difficult to document either reservoir sedimentation or the ...dams' downstream impacts. More than 50years of water and sediment data from 20 gauging stations within the Yangtze River's basin provide us a unique opportunity to delineate the impacts from the Three Gorges Dam (TGD), the world's largest dam. During the first decade after TGD completion in 2003, 1.8Gt of sediments were trapped in the Three Gorges Reservoir (TGR). The TGR's sediment retention rate increased from ~65% during the first three years of operation to ~85% by 2008–2012, when the TGD was in normal operation; in the low-discharge drought years of 2006 and 2011, reservoir retention exceeded 90%. Sedimentation in the TGR has been discontinuous, the most prominent depocenters being at the broad section near the up-river entrance to the reservoir and just upstream of the dam, where sediment thickness locally exceeds 60m. Median size of the sediments trapped in the TGR is 11μm, whereas sediments discharged from the TGR are finer than 5μm. As a result of sediment retention in the TGR, the river downstream has been eroded at a rate of 65Mt/yr. Riverbed sediments have coarsened considerably in the first several hundred kilometers downstream of TGD. Sediment discharge into the Yangtze estuary, as measured at the Datong downstream gauging station, decreased by 130Mt/yr relative to the normal water years of 2001–2002, nearly 90% of which can be attributed to the TGD. With planned construction of large upstream Cascade Reservoirs, the amount of sediment entering the TGR will decline dramatically, thus reducing sedimentation in the TGR and thereby extending its lifespan; by the end of the 21st century, the TGR should have retained more than 80% of its original storage capacity. Sediment outflow from the TGR will likely be less than 15Mt/yr, compared to 50Mt/yr at present. Even with downstream channel erosion, the long-term average sediment discharge into the Yangtze estuary in future decades most likely will decrease to ca. 110Mt/yr, only 20% of its level in the 1960s, and further delta erosion is expected.
The presently active Yellow River (Huanghe) delta lobe has been formed since 1976 when the river was artificially diverted. The process and driving forces of morphological evolution of the present ...delta lobe still remain unclear. Here we examined the stepwise morphological evolution of the active Yellow River delta lobe including both the subaerial and the subaqueous components, and illustrated the critical roles of riverine discharge and sediment grain size in dominating the deltaic evolution. The critical sediment loads for maintaining the delta stability were also calculated from water discharge and sediment load measured at station Lijin, the last gauging station approximately 100km upstream from the river mouth. The results indicated that the development of active delta lobe including both subaerial and subaqueous components has experienced four sequential stages. During the first stage (1976–1981) after the channel migration, the unchannelized river flow enhanced deposition within the channel and floodplain between Lijin station and the river mouth. Therefore, the critical sediment supply calculated by the river inputs obtained from station Lijin was the highest. However, the actual sediment load at this stage (0.84 Gt/yr) was more than twice of the critical sediment load (~0.35 Gt/yr) for sustaining the active subaerial area, which favored a rapid seaward progradation of the Yellow River subaerial delta. During the second stage (1981–1996), the engineering-facilitated channelized river flow and the increase in median grain size of suspended sediment delivered to the sea resulted in the critical sediment load for keeping the delta stability deceasing to 0.29 Gt/yr. The active delta lobe still gradually prograded seaward at an accretion rate of 11.9km2/yr at this stage as the annual sediment load at Lijin station was 0.55 Gt/yr. From 1996 to 2002, the critical sediment load further decreased to 0.15 Gt/yr with the sediment grain size increased to 22.5μm; however, the delta suffered net erosion because of the insufficient sediment supply (0.11 Gt/yr). In the most recent stage (2002−2013), the intensive scouring of the lower river channel induced by the dam regulation provided relatively coarser sediment, which effectively reduced the critical sediment load to 0.06 Gt/yr, much lower than the corresponding sediment load at Lijin station (~0.16 Gt/yr). Consequently, the subaerial Yellow River delta transitioned to a slight accretion phase. Overall, the evolution of the active Yellow River delta is highly correlated to riverine water and sediment discharge. The sediment supply for keeping the subaerial delta stability is inconstant and varying with the river channel morphology and sediment grain size. We conclude that the human-impacted riverine sediment discharge and grain-size composition play dominant roles in the stepwise morphological evolution of the active delta lobe.
Exploring highly active and inexpensive bifunctional electrocatalysts for water‐splitting is considered to be one of the prerequisites for developing hydrogen energy technology. Here, an efficient ...simultaneous etching‐doping sedimentation equilibrium (EDSE) strategy is proposed to design and prepare hollow Rh‐doped CoFe‐layered double hydroxides for overall water splitting. The elaborate electrocatalyst with optimized composition and typical hollow structure accelerates the electrochemical reactions, which can achieve a current density of 10 mA cm−2 at an overpotential of 28 mV (600 mA cm−2 at 188 mV) for hydrogen evolution reaction (HER) and 100 mA cm−2 at 245 mV for oxygen evolution reaction (OER). The cell voltage for overall water splitting of the electrolyzer assembled by this electrocatalyst is only 1.46 V, a value far lower than that of commercial electrolyzer constructed by Pt/C and RuO2 and most reported bifunctional electrocatalysts. Furthermore, the existence of Fe vacancies introduced by Rh doping and the typical hollow structure are demonstrated to optimize the entire HER and OER processes. EDSE associates doping with template‐directed hollow structures and paves a new avenue for developing bifunctional electrocatalysts for overall water splitting. It is also believed to be practical in other catalysis fields as well.
Etching‐doping sedimentation equilibrium induces the conversion of zeolitic imidazolate framework‐67 nanotriangles into template‐directed hollow Rh‐doped CoFe‐layered double hydroxides, which can combine the effects of doping and the synthesis method of etching precursor to accelerate the kinetics for water splitting. These findings provide a new avenue for the combination of doping and template‐directed hollow structures.
Proglacial lakes are ubiquitous within the Quaternary record and can provide exceptional breadth and depth of palaeoenvironmental information. Present deglaciation is increasing the number and size ...of proglacial lakes around the world. This study provides a synthesis of knowledge on proglacial lake character and behaviour and critically evaluates the importance of proglacial lakes from a geological perspective. We show how ‘ice-marginal’ or ‘ice-contact’ lakes and other distal proglacial lakes can be distinguished from each other by geomorphological, sedimentological, chemical and biological characteristics. The key controls on proglacial lake geomorphology and sedimentology are outlined and discussed. Proglacial lakes can exacerbate mountain glacier and ice sheet margin ablation via mechanical and thermal stresses, but very large lakes can moderate summer air temperatures and relatively retard summer ice ablation. Proglacial lakes interrupt meltwater flux and are very efficient sediment traps. Hydrological routing and consequent geomorphological activity can be radically modified by sudden drainage of proglacial lakes and resultant glacial lake outburst floods; exceptionally large proglacial lake drainages affected global ocean circulation and global climate during the Quaternary. Overall, analyses of proglacial lakes can provide a valuable insight into (i) patterns, character and behaviour of mountain glaciers, ice sheets and glaciations, and (ii) the impacts of past, present and future deglaciation.
•Synthesis of knowledge on proglacial lake formation, evolution and physical properties.•Criteria for distinguishing proglacial lakes in the Quaternary record.•Effects of proglacial lakes on glacier ice dynamics, meltwater and sediment fluxes and weather and climate.
The sulfur biogeochemical cycle plays a key role in regulating Earth’s surface redox through diverse abiotic and biological reactions that have distinctive stable isotopic fractionations. As such, ...variations in the sulfur isotopic composition (δ34S) of sedimentary sulfate and sulfide phases over Earth history can be used to infer substantive changes to the Earth’s surface environment, including the rise of atmospheric oxygen. Such inferences assume that individual δ34S records reflect temporal changes in the global sulfur cycle; this assumption may be well grounded for sulfate-bearing minerals but is less well established for pyrite-based records. Here, we investigate alternative controls on the sedimentary sulfur isotopic composition of marine pyrite by examining a 300-m drill core of Mediterranean sediments deposited over the past 500,000 y and spanning the last five glacial–interglacial periods. Because this interval is far shorter than the residence time of marine sulfate, any change in the sulfur isotopic record preserved in pyrite (δ34Spyr) necessarily corresponds to local environmental changes. The stratigraphic variations (>76‰) in the isotopic data reported here are among the largest ever observed in pyrite, and are in phase with glacial–interglacial sea level and temperature changes. In this case, the dominant control appears to be glacial–interglacial variations in sedimentation rates. These results suggest that there exist important but previously overlooked depositional controls on sedimentary sulfur isotope records, especially associated with intervals of substantial sea level change. This work provides an important perspective on the origin of variability in such records and suggests meaningful paleoenvironmental information can be derived from pyrite δ34S records.