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  • Synthesis, Characterization...
    Liu, Cheng

    Acta chimica Slovenica, 2022-Mar-15, Letnik: 69, Številka: 1
    Journal Article

    Three new zinc(II) and one vanadium(V) complexes, Zn2Cl2L2 (1), Zn2I2L2 (2), ZnCl2(HL) (3), and V2O2(μ-O)2L2 (4), where L is 5-bromo-2-((2-(methylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by elemental analyses, IR and UV-Vis spectra, as well as molar conductivity. Structures of the complexes were confirmed by single crystal X-ray diffraction. Complexes 1 and 2 are isostructural dinuclear zinc compounds, with the Zn atoms in square pyramidal coordination. The Zn atoms in the mononuclear complex 3 are in tetrahedral coordination. Complex 4 is a dinuclear vanadium(V) compound, with the V atoms in octahedral coordination. The complexes were assayed for antibacterial activities by MTT method.