Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes

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Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes

He, Yu-Tao; Wang, Qiang; Zhao, Jiahui; Wang, Xiao-Zhen; Qiu, Yi-Feng; Yang, Yu-Chen; Hu, Jing-Yuan; Liu, Xue-Yuan; Liang, Yong-Min

Advanced synthesis & catalysis, October 12, 2015, Letnik: 357, Številka: 14-15

Journal Article

A method for the synthesis of trifluoromethyl CF3‐substituted spirocyclic compounds containing with a unique quaternary carbon center from readily available starting materials has been developed. The reaction provides a facile access to 2H‐azirines via cascade cyclization. These compounds constitute a new class of functionalized synthetic intermediates, which can be used for the synthesis of various nitrogen‐containing heterocycles and biologically active CF3‐containing compounds.

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Leto	Faktor vpliva		Izdaja		Kategorija		Razvrstitev
Leto	JCR	SNIP	JCR	SNIP	JCR	SNIP	JCR	SNIP

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