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Padmanaban, Mohan; Müller, Philipp; Lieder, Christian; Gedrich, Kristina; Grünker, Ronny; Bon, Volodymyr; Senkovska, Irena; Baumgärtner, Sandra; Opelt, Sabine; Paasch, Silvia; Brunner, Eike; Glorius, Frank; Klemm, Elias; Kaskel, Stefan
Chemical communications, 01/2011, Letnik: 47, Številka: 44Journal Article
A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.
