•A universal strategy is proposed to improve the environmental resistance of air filters.•An ultrathin alumina layer is conformally deposited on a porous membrane via ALD.•An alumina shell effectively protects a polymer core from various external stimuli.•The resulting composite membrane shows excellent PM filtration efficiency (∼99%).•PM filtration efficiency does not deteriorate even after water spraying. In this study, a composite membrane was developed by conformally coating an ultrathin Al2O3 layer through low-temperature (90 °C) atomic layer deposition (ALD) on a hydrophilic mixed cellulose ester (MCE) membrane with a 3D networked microporous structure. The thickness of the deposited Al2O3 layer, without clogging the pores of the membrane, was precisely controlled by varying the number of ALD cycles from 100 to 300. The ultrathin (∼33 nm) Al2O3 layer greatly enhanced the resistance to various environmental stimuli and contributed to the improved removal efficiency of airborne particulate matter (PM), owing to the reduced pore size. The resulting composite membrane installed on an insect screen exhibited excellent removal efficiency (>99%) for PM of various sizes (PM1.0, PM2.5, and PM10) at a controlled flow rate of 1 L/min. In particular, unlike polypropylene-based commercial PM filters that strongly rely on electrostatic adsorption for PM filtration, the reduction in the PM removal efficiency caused by water or ethanol was negligible in the developed composite membrane, enabling long-term use even in extreme environments.