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  • Three 1-thio-β- d-glucopyra...
    Ngane, Annie Ngono; Lavault, Marie; Séraphin, Denis; Landreau, Anne; Richomme, Pascal

    Carbohydrate research, 12/2006, Letnik: 341, Številka: 17
    Journal Article

    Three new 1-thioglycosides namely methylthiomethyl 1-thio-β- d-glucopyranoside (Afrostyraxthioside A), methylsulfonylmethyl 1-thio-β- d-glucopyranoside (Afrostyraxthioside B) and methylsulfonylmethylthiomethyl 1-thio-β- d-glucopyranoside (Afrostyraxthioside C) were isolated from the seeds of Afrostyrax lepidophyllus Mildbr. Their structures were mainly elucidated by using one- and two-dimensional NMR and mass spectroscopies and also by an efficient one-step synthesis. Moreover, Afrostyraxthiosides A, B and C constitute a new subclass of 1-thioglycosides isolated from natural sources.