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Liu, Jing-Yuan; Wang, Zhen-Ying; Li, Qiang; Li, Dacheng; Dou, Jianmin
New journal of chemistry, 03/2023, Letnik: 47, Številka: 11Journal Article
An I 2 -mediated 3+2+1 aerobic cyclization reaction of anilines with alkynes and tertiary amines without any peroxides has been reported. This protocol employed tertiary amines as a C1 building block for the direct synthesis of 2-non, 2-alkyl, and even 2-aryl substituted quinolines via C–N bond cleavage. Differing from the traditional methods, both terminal and internal alkynes were compatible in this metal-free three-component system. It is possible that the 2-vinylbenzenamine species might be produced as one of the active intermediates in this process.
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JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
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in: SICRIS
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