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A SIFSIX-MOF constructed from a metalloligand yields enhanced stability for selective CO2 adsorptionTous-Granados, Alberto M; Hernandez-Maldonado, Arturo J
Chemical communications (Cambridge, England), 08/2023, Letnik: 59, Številka: 66Journal Article
The first example of a metalloligand(ML)-based non-interpenetrated SIFSIX MOF Cu(ML)2(SiF6)n (ML = Cu(pyac)2 = bis3-(4-pyridyl)pentane-2,4-dionatocopper(ii)) exhibits one-dimensional pore channels decorated with accessible Cu2+ sites that provide superior water vapor stability and CO2 selectivity over CH4vs. similar materials constructed from non-metal containing organic ligands.
