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Ristic, Predrag; Rodic, Marko; Filipovic, Nenad; Mitic, Dragana; Andjelkovic, Katarina; Todorovic, Tamara
Journal of the Serbian Chemical Society, 2021, Letnik: 86, Številka: 4Journal Article
Two square?planar complexes, PtLCl (1) and PdLCl (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.
